Metatorbernite
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Metatorbernite (or meta-torbernite) is a
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
phosphate mineral Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluoride (F−), and hydroxide (OH−) anions that also fit ...
, and is a
dehydration In physiology, dehydration is a lack of total body water, with an accompanying disruption of metabolic processes. It occurs when free water loss exceeds free water intake, usually due to exercise, disease, or high environmental temperature. Mil ...
pseudomorph In mineralogy, a pseudomorph is a mineral or mineral compound that appears in an atypical form (crystal system), resulting from a substitution process in which the appearance and dimensions remain constant, but the original mineral is replaced b ...
of
torbernite Torbernite is a radioactive, hydrated green copper uranyl phosphate mineral, found in granites and other uranium-bearing deposits as a secondary mineral. Its name derives from the Swedish chemist Torbern Bergman (1735–1784), It is also known ...
. Chemically, it is a
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
uranyl The uranyl ion is an oxycation of uranium in the oxidation state +6, with the chemical formula . It has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands may ...
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...
and usually occurs in the form of green platy deposits. It can form by direct deposition from a supersaturated solution, which produces true crystalline metatorbernite, with a dark green colour, translucent
diaphaneity In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions a ...
, and vitreous lustre. However, more commonly, it is formed by the dehydration of torbernite, which causes internal stress and breakage within the crystal lattice, resulting in crystals composed of microscopic powder held together using
electrostatic Electrostatics is a branch of physics that studies electric charges at rest ( static electricity). Since classical times, it has been known that some materials, such as amber, attract lightweight particles after rubbing. The Greek word for amb ...
force, and having a lighter green colour, opaque diaphaneity, and a relatively dull lustre. As with torbernite, it is named after the
Swedish Swedish or ' may refer to: Anything from or related to Sweden, a country in Northern Europe. Or, specifically: * Swedish language, a North Germanic language spoken primarily in Sweden and Finland ** Swedish alphabet, the official alphabet used by ...
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
Torbern Bergman Torbern Olaf (Olof) Bergman (''KVO'') (20 March 17358 July 1784) was a Swedish chemist and mineralogist noted for his 1775 ''Dissertation on Elective Attractions'', containing the largest chemical affinity tables ever published. Bergman was the ...
. It is especially closely associated with torbernite, but is also found amongside
autunite Autunite (hydrated calcium uranyl phosphate), with formula Ca(UO2)2(PO4)2·10–12H2O, is a yellow-greenish fluorescent phosphate mineral with a hardness of 2–. Autunite crystallizes in the orthorhombic system and often occurs as tabular square ...
, meta-autunite and
uraninite Uraninite, formerly pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium causes ...
.


References


Uranium minerals
Uranyl compounds Copper(II) minerals Phosphate minerals Radioactive minerals Tetragonal minerals Minerals in space group 85 Uranium(VI) minerals {{phosphate-mineral-stub