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Mass Spectrograph
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated according ...
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Mass-to-charge Ratio
The mass-to-charge ratio (''m''/''Q'') is a physical quantity relating the ''mass'' (quantity of matter) and the ''electric charge'' of a given particle, expressed in units of kilograms per coulomb (kg/C). It is most widely used in the electrodynamics of charged particles, e.g. in electron optics and ion optics. It appears in the scientific fields of electron microscopy, cathode ray tubes, accelerator physics, nuclear physics, Auger electron spectroscopy, cosmology and mass spectrometry. The importance of the mass-to-charge ratio, according to classical electrodynamics, is that two particles with the same mass-to-charge ratio move in the same path in a vacuum, when subjected to the same electric and magnetic fields. On rare occasions, the thomson has been used as its unit in the field of mass spectrometry. Some disciplines use the charge-to-mass ratio (''Q''/''m'') instead, which is the multiplicative inverse of the mass-to-charge ratio. The CODATA recommended value for an ...
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Alpha Calutron Tank
Alpha (uppercase , lowercase ; grc, ἄλφα, ''álpha'', or ell, άλφα, álfa) is the first letter of the Greek alphabet. In the system of Greek numerals, it has a value of one. Alpha is derived from the Phoenician letter aleph , which is the West Semitic word for " ox". Letters that arose from alpha include the Latin letter A and the Cyrillic letter А. Uses Greek In Ancient Greek, alpha was pronounced and could be either phonemically long ( ː or short ( . Where there is ambiguity, long and short alpha are sometimes written with a macron and breve today: Ᾱᾱ, Ᾰᾰ. * ὥρα = ὥρᾱ ''hōrā'' "a time" * γλῶσσα = γλῶσσᾰ ''glôssa'' "tongue" In Modern Greek, vowel length has been lost, and all instances of alpha simply represent the open front unrounded vowel . In the polytonic orthography of Greek, alpha, like other vowel letters, can occur with several diacritic marks: any of three accent symbols (), and either of two breathing marks ...
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Isotopes Of Uranium
Uranium (92U) is a naturally occurring radioactive element that has no stable isotope. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in the Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from 214U to 242U (with the exceptions of 220U and 241U). The standard atomic weight of natural uranium is . Naturally occurring uranium is composed of three major isotopes, uranium-238 (99.2739–99.2752% natural abundance), uranium-235 (0.7198–0.7202%), and uranium-234 (0.0050–0.0059%). All three isotopes are radioactive (i.e., they are radioisotopes), and the most abundant and stable is uranium-238, with a half-life of (close to the age of the Earth). Uranium-238 is an alpha emitter, decayi ...
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Ernest O
Ernest is a given name derived from Germanic word ''ernst'', meaning "serious". Notable people and fictional characters with the name include: People *Archduke Ernest of Austria (1553–1595), son of Maximilian II, Holy Roman Emperor * Ernest, Margrave of Austria (1027–1075) *Ernest, Duke of Bavaria (1373–1438) * Ernest, Duke of Opava (c. 1415–1464) *Ernest, Margrave of Baden-Durlach (1482–1553) *Ernest, Landgrave of Hesse-Rheinfels (1623–1693) *Ernest Augustus, Elector of Brunswick-Lüneburg (1629–1698) *Ernest, Count of Stolberg-Ilsenburg (1650–1710) * Ernest Augustus, King of Hanover (1771–1851), son of King George III of Great Britain *Ernest II, Duke of Saxe-Coburg and Gotha (1818–1893), sovereign duke of the Duchy of Saxe-Coburg and Gotha *Ernest Augustus, Crown Prince of Hanover (1845–1923) *Ernest, Landgrave of Hesse-Philippsthal (1846–1925) *Ernest Augustus, Prince of Hanover (1914–1987) *Prince Ernst August of Hanover (born 1954) * Prince Ernst ...
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Calutron
A calutron is a mass spectrometer originally designed and used for separating the isotopes of uranium. It was developed by Ernest Lawrence during the Manhattan Project and was based on his earlier invention, the cyclotron. Its name was derived from California University Cyclotron, in tribute to Lawrence's institution, the University of California, where it was invented. Calutrons were used in the industrial-scale Y-12 uranium enrichment plant at the Clinton Engineer Works in Oak Ridge, Tennessee. The enriched uranium produced was used in the Little Boy atomic bomb that was detonated over Hiroshima on 6 August 1945. The calutron is a type of sector mass spectrometer, an instrument in which a sample is ionized and then accelerated by electric fields and deflected by magnetic fields. The ions ultimately collide with a plate and produce a measurable electric current. Since the ions of the different isotopes have the same electric charge but different masses, the heavier isotopes ...
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Sector Instrument
A sector instrument is a general term for a class of mass spectrometer that uses a static electric (E) or magnetic (B) sector or some combination of the two (separately in space) as a mass analyzer. Popular combinations of these sectors have been the EB, BE (of so-called reverse geometry), three-sector BEB and four-sector EBEB (electric-magnetic-electric-magnetic) instruments. Most modern sector instruments are double-focusing instruments (first developed by Francis William Aston, Arthur Jeffrey Dempster, Kenneth Bainbridge and Josef Mattauch in 1936) in that they focus the ion beams both in direction and velocity. Theory The behavior of ions in a homogeneous, linear, static electric or magnetic field (separately) as is found in a sector instrument is simple. The physics are described by a single equation called the Lorentz force law. This equation is the fundamental equation of all mass spectrometric techniques and applies in non-linear, non-homogeneous cases too and is an impor ...
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Arthur Jeffrey Dempster
Arthur Jeffrey Dempster (August 14, 1886 – March 11, 1950) was a Canadian-American physicist best known for his work in mass spectrometry and his discovery in 1935 of the uranium isotope 235U. Early life and education Dempster was born in Toronto, Ontario, Canada. He received his bachelor's and master's degrees at the University of Toronto in 1909 and 1910, respectively. He travelled to study in Germany, and then left at the outset of World War I for the United States; there he received his Ph.D. in physics at the University of Chicago. Academic career Dempster joined the physics faculty at the University of Chicago in 1916 and remained there until his death in 1950. During World War II he worked on the secret Manhattan Project to develop the world's first nuclear weapons. From 1943 to 1946, Dempster was chief physicist of the University of Chicago's Metallurgical Laboratory or "Met Lab" which integrally related to the Manhattan Project and founded to study the materials ...
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Spectroscopy
Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. Matter waves and acoustic waves can also be considered forms of radiative energy, and recently gravitational waves have been associated with a spectral signature in the context of the Laser Interferometer Gravitational-Wave Observatory (LIGO) In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum. Historically, spectroscopy originated as the study of the wavelength dependence of the absorption by gas phase matter of visible light dispersed by a prism. Spectroscopy, primarily in the electromagnetic spectrum, is a fundamental exploratory tool in the fields of astronomy, chemistry, materials science, and physics, allowing the composition, physical structure and e ...
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Oscilloscope
An oscilloscope (informally a scope) is a type of electronic test instrument that graphically displays varying electrical voltages as a two-dimensional plot of one or more signals as a function of time. The main purposes are to display repetitive or single waveforms on the screen that would otherwise occur too briefly to be perceived by the human eye. The displayed waveform can then be analyzed for properties such as amplitude, frequency, rise time, time interval, distortion, and others. Originally, calculation of these values required manually measuring the waveform against the scales built into the screen of the instrument. Modern digital instruments may calculate and display these properties directly. Oscilloscopes are used in the sciences, medicine, engineering, automotive and the telecommunications industry. General-purpose instruments are used for maintenance of electronic equipment and laboratory work. Special-purpose oscilloscopes may be used to analyze an automotive ign ...
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Phosphor
A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam (cathode rays) in a cathode-ray tube. When a phosphor is exposed to radiation, the orbital electrons in its molecules are excited to a higher energy level; when they return to their former level they emit the energy as light of a certain color. Phosphors can be classified into two categories: fluorescent substances which emit the energy immediately and stop glowing when the exciting radiation is turned off, and phosphorescent substances which emit the energy after a delay, so they keep glowing after the radiation is turned off, decaying in brightness over a period of milliseconds to days. Fluorescent materials are used in applications in which the ...
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Dalton Transactions
''Dalton Transactions'' is a peer-reviewed scientific journal publishing original (primary) research and review articles on all aspects of the chemistry of inorganic, bioinorganic, and organometallic compounds. It is published weekly by the Royal Society of Chemistry. The journal was named after the English chemist, John Dalton, best known for his work on modern atomic theory. Authors can elect to have accepted articles published as open access. The editor is Andrew Shore. ''Dalton Transactions'' was named a "rising star" by ''In-cites'' from Thomson Scientific in 2006. Publication history The journal was established as the ''Journal of the Chemical Society A: Inorganic, Physical, Theoretical'' in 1966. In 1972, the journal was divided into three separate journals: ''Journal of the Chemical Society, Dalton Transactions'' (covering inorganic and organometallic chemistry), '' Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases'', and '' ...
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Photographic Plate
Photographic plates preceded photographic film as a capture medium in photography, and were still used in some communities up until the late 20th century. The light-sensitive emulsion of silver salts was coated on a glass plate, typically thinner than common window glass. History Glass plates were far superior to film for research-quality imaging because they were stable and less likely to bend or distort, especially in large-format frames for wide-field imaging. Early plates used the wet collodion process. The wet plate process was replaced late in the 19th century by gelatin dry plates. A view camera nicknamed "The Mammoth" weighing was built by George R. Lawrence in 1899, specifically to photograph "The Alton Limited" train owned by the Chicago & Alton Railway. It took photographs on glass plates measuring × . Glass plate photographic material largely faded from the consumer market in the early years of the 20th century, as more convenient and less fragile fil ...
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