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Marine Grade Stainless
Marine grade stainless alloys typically contain molybdenum to resist the corrosive effects of NaCl or salt in seawater. Concentrations of salt in seawater can vary, and splash zones can cause concentrations to increase dramatically from the spray and evaporation. SAE 316 stainless steel is a molybdenum-alloyed steel and the second most common austenitic stainless steel (after grade 304). It is the preferred steel for use in marine environments because of its greater resistance to pitting corrosion than most other grades of steel without molybdenum. The fact that it is negligibly responsive to magnetic fields means that it can be used in applications where a non-magnetic metal is required. 316 alloys While 316 is not completely rust-proof, the alloy is more corrosion resistant than other common stainless steels. For example, surgical steel is made from subtypes of 316 stainless steel. In addition to molybdenum, 316 also contains a number of other elements in varying conc ...
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Molybdenum
Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals have been known throughout history, but the element was discovered (in the sense of differentiating it as a new entity from the mineral salts of other metals) in 1778 by Carl Wilhelm Scheele. The metal was first isolated in 1781 by Peter Jacob Hjelm. Molybdenum does not occur naturally as a free metal on Earth; it is found only in various oxidation states in minerals. The free element, a silvery metal with a grey cast, has the sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of the world production of the element (about 80%) is used in steel alloys, including high-strength alloys and superalloys. Most molybdenum compounds have low solubility ...
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Silicon
Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic table: carbon is above it; and germanium, tin, lead, and flerovium are below it. It is relatively unreactive. Because of its high chemical affinity for oxygen, it was not until 1823 that Jöns Jakob Berzelius was first able to prepare it and characterize it in pure form. Its oxides form a family of anions known as silicates. Its melting and boiling points of 1414 °C and 3265 °C, respectively, are the second highest among all the metalloids and nonmetals, being surpassed only by boron. Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure element in the Earth's crust. It is widely distributed in space in cosmic dusts, planetoids, and planets as various forms of silicon ...
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Crevice Corrosion
Crevice corrosion refers to corrosion occurring in occluded spaces such as interstices in which a stagnant solution is trapped and not renewed. These spaces are generally called crevices. Examples of crevices are gaps and contact areas between parts, under gaskets or seals, inside cracks and seams, spaces filled with deposits and under sludge piles. Mechanism The corrosion resistance of a stainless steel is dependent on the presence of an ultra-thin protective oxide film (passive film) on its surface, but it is possible under certain conditions for this oxide film to break down, for example in halide solutions or reducing acids. Areas where the oxide film can break down can also sometimes be the result of the way components are designed, for example under gaskets, in sharp re-entrant corners or associated with incomplete weld penetration or overlapping surfaces. These can all form crevices which can promote corrosion. To function as a corrosion site, a crevice has to be of suffi ...
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Pitting Corrosion
Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic (oxidation reaction) while an unknown but potentially vast area becomes cathodic (reduction reaction), leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions. Another term arises, pitting factor, which is defined as the ratio of the depth of the deepest pit (resulting due to corrosion) to the average penetration, which can be calculated based on the weight loss. Development and kinetics of pitting According to Frankel (1998) who performed a review on pitting corrosion, it develops in three successive steps: (or nucleation) by breakdown of the passive film protecting the metal surface from oxidation, (2) growth of metastable pits (growing up to the micron scale and then repassi ...
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Chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride salts such as sodium chloride are often very soluble in water.Green, John, and Sadru Damji. "Chapter 3." ''Chemistry''. Camberwell, Vic.: IBID, 2001. Print. It is an essential electrolyte located in all body fluids responsible for maintaining acid/base balance, transmitting nerve impulses and regulating liquid flow in and out of cells. Less frequently, the word ''chloride'' may also form part of the "common" name of chemical compounds in which one or more chlorine atoms are covalently bonded. For example, methyl chloride, with the standard name chloromethane (see IUPAC books) is an organic compound with a covalent C−Cl bond in which the chlorine is not an anion. Electronic properties A chloride ion (diameter 167  pm) is much lar ...
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316 Wire Rope For Marine Industry
__NOTOC__ Year 316 ( CCCXVI) was a leap year starting on Sunday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Sabinus and Rufinus (or, less frequently, year 1069 '' Ab urbe condita''). The denomination 316 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Emperor Constantine the Great issues an edict, prohibiting the punishment of slaves by crucifixion and facial branding. * Constantine I sends his half-brother Julius Constantius to Licinius at Sirmium ( Pannonia), with the proposal to accept Bassianus as ''Caesar'' and give him power over Italy. Licinius refuses, and forces a conspiracy against Constantine. * Licinius elevates Valerius Valens to ''Augustus'', and mobilises an army against Constantine. Bassianus is accused of conspiracy and executed. * October 8 ...
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Niobium
Niobium is a chemical element with chemical symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite, hence the former name "columbium". Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish. English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. German chemist Heinrich Rose dete ...
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Titanium
Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Kingdom of Great Britain, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titan (mythology), Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll process, Kroll and Hunter process, Hunter processes. The most common compound, titanium dioxide, is a popular photocatalysis, photocatalyst and is used in the manufacture of white pigments ...
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Free Machining Steel
Free machining steel is steel that forms small chips when machined. This increases the machinability of the material by breaking the chips into small pieces, thus avoiding entanglement in the machinery. This enables automatic equipment to run without human interaction. Free machining steel with lead also allow for higher machining rates. Free machining steel costs 15 to 20% more than standard steel, but this higher cost is offset by increased machining speeds, larger cuts, and longer tool life.Degarmo, p. 117. The disadvantages of free machining steel are: ductility is decreased; impact resistance is reduced; copper-based brazed joints suffer from embrittlement with bismuth free machining grades; shrink fits are not as strong.Degarmo, p. 118. Types There are four main types of free machining steel: ''leaded'', ''resulfurized'', ''rephosphorized'' and ''super''. Super free-machining steels are alloyed with tellurium, selenium, and bismuth. Mechanics Free machining steels are ca ...
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Intergranular Corrosion
In materials science, intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides. (''Cf.'' transgranular corrosion.) Description This situation can happen in otherwise corrosion-resistant alloys, when the grain boundaries are depleted, known as ', of the corrosion-inhibiting elements such as chromium by some mechanism. In nickel alloys and austenitic stainless steels, where chromium is added for corrosion resistance, the mechanism involved is precipitation of chromium carbide at the grain boundaries, resulting in the formation of chromium-depleted zones adjacent to the grain boundaries (this process is called sensitization). Around 12% chromium is minimally required to ensure passivation, a mechanism by which an ultra thin invisible film, known as passive film, forms on the surface of stainless steels. This passive film protects the ...
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SAE 316L Stainless Steel
SAE 316L grade stainless steel, sometimes referred to as A4 stainless steel or marine grade stainless steel, is the second most common austenitic stainless steel after 304/A2 stainless steel. Its primary alloying constituents after iron, are chromium (between 16–18%), nickel (10–12%) and molybdenum (2–3%), with small (<1%) quantities of silicon, phosphorus & sulfur also present. The addition of molybdenum provides greater corrosion resistance than 304, with respect to localized corrosive attack by s and to general corrosion by reducing acids, such as sulfuric acid. 316L grade is the low carbon version of 316 stainless steel. When cold worked, 316 can produce high yield and tensile strengths similar to
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Molybdenum
Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lead ores. Molybdenum minerals have been known throughout history, but the element was discovered (in the sense of differentiating it as a new entity from the mineral salts of other metals) in 1778 by Carl Wilhelm Scheele. The metal was first isolated in 1781 by Peter Jacob Hjelm. Molybdenum does not occur naturally as a free metal on Earth; it is found only in various oxidation states in minerals. The free element, a silvery metal with a grey cast, has the sixth-highest melting point of any element. It readily forms hard, stable carbides in alloys, and for this reason most of the world production of the element (about 80%) is used in steel alloys, including high-strength alloys and superalloys. Most molybdenum compounds have low solubility ...
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