Gasworks
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Gasworks
A gasworks or gas house is an industrial plant for the production of flammable gas. Many of these have been made redundant in the developed world by the use of natural gas, though they are still used for storage space. Early gasworks Coal gas was introduced to Great Britain in the 1790s as an illuminating gas by the Scottish inventor William Murdoch. Early gasworks were usually located beside a river or canal so that coal could be brought in by barge. Transport was later shifted to railways and many gasworks had internal railway systems with their own locomotives. Early gasworks were built for factories in the Industrial Revolution from about 1805 as a light source and for industrial processes requiring gas, and for lighting in country houses from about 1845. Country house gas works are extant at Culzean Castle in Scotland and Owlpen in Gloucestershire. Equipment A gasworks was divided into several sections for the production, purification and storage of gas. Retort ho ...
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Launceston Gas Works
The Launceston Gasworks is a former industrial site located in the CBD of Launceston, Tasmania. The site was the principal supplier of gas to the City of Launceston before the importation of LPG in the 1970s. The gasworks produced gas by heating coal and siphoning off the gas that it released before refining and storing it on site in a set of 3, steel frame gasometers. The first buildings on site were the horizontal retort buildings built in 1860 from sandstone and local brick. The site was later used by Origin Energy as their Launceston LPG outlet. The site is instantly recognizable by its 1930s, steel braced, vertical retort building with the words "COOK WITH GAS" in the brickwork. History Starting in 1826, Launceston was lit with lamps running on sperm whale oil. These lamps were unpopular and local butchers soon replaced these with "slush" lamps that burned animal fat. These lamps were still disliked by many so in 1844 a local man, Doctor William Russ Pugh (a statue of ...
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Illuminating Gas
The history of gaseous fuel, important for lighting, heating, and cooking purposes throughout most of the 19th century and the first half of the 20th century, began with the development of analytical and pneumatic chemistry in the 18th century. The manufacturing process for "synthetic fuel gases" (also known as "manufactured fuel gas", "manufactured gas" or simply "gas") typically consisted of the gasification of combustible materials, usually coal, but also wood and oil. The coal was gasified by heating the coal in enclosed ovens with an oxygen-poor atmosphere. The fuel gases generated were mixtures of many chemical substances, including hydrogen, methane, carbon monoxide and ethylene, and could be burnt for heating and lighting purposes. Coal gas, for example, also contains significant quantities of unwanted sulfur and ammonia compounds, as well as heavy hydrocarbons, and so the manufactured fuel gases needed to be purified before they could be used. The first attempts to manufa ...
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Coal Gas
Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities. The original coal gas was produced by the coal gasification reaction, and thus the burnable component consisted of a roughly equal molecular mixture of carbon monoxide and hydrogen. Thus, coal gas was highly toxic. Other compositions contain additional calorific gases such as methane, produced by the Fischer-Tropsch process, and volatile hydrocarbons together with small quantities of non-calorific gases such as carbon dioxide and nitrogen. Prior to the development of natural gas supply and transmission—during the 1940s and 1950s in the United States and during the late 1960s and 1970s in the United Kingdom and Australia—almost all gas for fuel and lighting was manufactured fro ...
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William Murdoch
William Murdoch (sometimes spelled Murdock) (21 August 1754 – 15 November 1839) was a Scottish engineer and inventor. Murdoch was employed by the firm of Boulton & Watt and worked for them in Cornwall, as a steam engine erector for ten years, spending most of the rest of his life in Birmingham, England. Murdoch was the inventor of the oscillating cylinder steam engine, and gas lighting is attributed to him in the early 1790s, as well as the term "gasometer". However the Dutch-Belgian Academic Jean-Pierre Minckelers had already published on coal gasification and gas lighting in 1784, and had used gas to light his auditorium at the University of Leuven from 1785. Archibald Cochrane, 9th Earl of Dundonald, had also used gas for lighting his family estate from 1789 onwards. Murdoch also made innovations to the steam engine, including the sun and planet gear and D slide valve. He invented the steam gun and the pneumatic tube message system, and worked on one of the first Brit ...
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Iron Sulfide
Iron sulfide or Iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals By increasing order of stability: * Iron(II) sulfide, FeS * Greigite, Fe3S4 (cubic) * Pyrrhotite, Fe1−xS (where x = 0 to 0.2) (monoclinic or hexagonal) * Troilite, FeS, the endmember of pyrrhotite (hexagonal) * Mackinawite, Fe1+xS (where x = 0 to 0.1) (tetragonal) * Marcasite, orthorhombic FeS2 * Pyrite, cubic FeS2 (fool's gold) * Arsenopyrite (''mispickel''), FeAsS, or Fe(As-S), Fe(III) mixed arseno-sulfide (monoclinic) Synthetic * Iron(III) sulfide, Fe2S3 * Iron-sulfur clusters, includes both synthetic and biological Biological * Iron–sulfur protein Iron–sulfur proteins (or iron–sulphur proteins in British spelling) are proteins characterized by the presence of iron–sulfur clusters containing sulfide-linked di-, tri-, and tetrairon centers in variable oxidation states. Iron–sulfur cl ... {{DEFAULTSORT:Iron Sulfide Iron compounds Iron minerals Sulfur ...
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Ferric Oxide
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally as the mineral magnetite. As the mineral known as hematite, Fe2O3 is the main source of iron for the steel industry. Fe2O3 is readily attacked by acids. Iron(III) oxide is often called rust, and to some extent this label is useful, because rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as Hydrous ferric oxide. Structure Fe2O3 can be obtained in various polymorphs. In the main one, α, iron adopts octahedral coordination geometry. That is, each Fe center is bound to six oxygen ligands. In the γ polymorph, some of the Fe sit on tetrahedral sites, with four oxygen ligands. Alpha phase α-Fe2O3 has the rhombohedral, corundum (α-Al2O3) structure and i ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the ...
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Ammonium
The ammonium cation is a positively-charged polyatomic ion with the chemical formula or . It is formed by the protonation of ammonia (). Ammonium is also a general name for positively charged or protonated substituted amines and quaternary ammonium cations (), where one or more hydrogen atoms are replaced by organic groups (indicated by R). Acid–base properties The ammonium ion is generated when ammonia, a weak base, reacts with Brønsted acids (proton donors): :H+ + NH3 -> H4 The ammonium ion is mildly acidic, reacting with Brønsted bases to return to the uncharged ammonia molecule: : H4 + B- -> HB + NH3 Thus, treatment of concentrated solutions of ammonium salts with strong base gives ammonia. When ammonia is dissolved in water, a tiny amount of it converts to ammonium ions: :H2O + NH3 OH- + H4 The degree to which ammonia forms the ammonium ion depends on the pH of the solution. If the pH is low, the equilibrium shifts to the right: more ammonia molecules are co ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Gloucestershire
Gloucestershire ( abbreviated Glos) is a county in South West England. The county comprises part of the Cotswold Hills, part of the flat fertile valley of the River Severn and the entire Forest of Dean. The county town is the city of Gloucester and other principal towns and villages include Cheltenham, Cirencester, Kingswood, Bradley Stoke, Stroud, Thornbury, Yate, Tewkesbury, Bishop's Cleeve, Churchdown, Brockworth, Winchcombe, Dursley, Cam, Berkeley, Wotton-under-Edge, Tetbury, Moreton-in-Marsh, Fairford, Lechlade, Northleach, Stow-on-the-Wold, Chipping Campden, Bourton-on-the-Water, Stonehouse, Nailsworth, Minchinhampton, Painswick, Winterbourne, Frampton Cotterell, Coleford, Cinderford, Lydney and Rodborough and Cainscross that are within Stroud's urban area. Gloucestershire borders Herefordshire to the north-west, Worcestershire to the north, Warwickshire to the north-east, Oxfordshire to the east, Wiltshire to the south, Bristol and Somerset ...
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Ammonium Hydroxide
Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests an alkali with chemical formula, composition , it is actually impossible to isolate samples of NH4OH. The ions and OH− do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions. Basicity of ammonia in water In aqueous solution, ammonia deprotonation, deprotonates a small fraction of the water to give ammonium and hydroxide according to the following chemical equilibrium, equilibrium: : NH3 + H2O NH4+ + OH−. In a 1 Molar concentration, M ammonia solution, about 0.42% of the ammonia is converted to ammonium, equivalent to pH = 11.63 because [NH4+] = 0.0042 M, [OH−] = 0.0042 M, [NH3] = 0.9958 M, and pH = 14 + log10[OHâ ...
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Condensation
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition. Initiation Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules. Reversibility scenarios A few distinct reversibility scenarios emerge here with respect to the n ...
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