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Group 10
Group 10, numbered by current IUPAC style, is the group of chemical elements in the periodic table that consists of nickel (Ni), palladium (Pd), platinum (Pt), and darmstadtium (Ds). All are d-block transition metals. All known isotopes of darmstadtium are radioactive with short half-lives, and are not known to occur in nature; only minute quantities have been synthesized in laboratories. Characteristics Chemical properties The ground state electronic configurations of palladium and platinum are exceptions to Madelung's rule. According to Madelung's rule, the electronic configuration of palladium and platinum are expected to be r5s2 4d8 and e4f14 6d2 5d8 respectively. However, the 5s orbital of palladium is empty, and the 6s orbital of platinum is only partially filled. The relativistic stabilization of the 7s orbital is the explanation to the predicted electron configuration of darmstadtium, which, unusually for this group, conforms to that predicted by the Aufbau princ ...
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IUPAC
The International Union of Pure and Applied Chemistry (IUPAC ) is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. This administrative office is headed by IUPAC's executive director, currently Lynn Soby. IUPAC was established in 1919 as the successor of the International Congress of Applied Chemistry for the advancement of chemistry. Its members, the National Adhering Organizations, can be national chemistry societies, national academies of sciences, or other bodies representing chemists. There are fifty-four National Adhering Organizations and three Associate National Adhering Organizations. IUPAC's Inter-divisional Committee on ...
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Lustre (mineralogy)
Lustre (British English) or luster (American English; see spelling differences) is the way light interacts with the surface of a crystal, rock, or mineral. The word traces its origins back to the Latin ''lux'', meaning "light", and generally implies radiance, gloss, or brilliance. A range of terms are used to describe lustre, such as ''earthy'', ''metallic'', ''greasy'', and ''silky''. Similarly, the term ''vitreous'' (derived from the Latin for glass, ''vitrum'') refers to a glassy lustre. A list of these terms is given below. Lustre varies over a wide continuum, and so there are no rigid boundaries between the different types of lustre. (For this reason, different sources can often describe the same mineral differently. This ambiguity is further complicated by lustre's ability to vary widely within a particular mineral species). The terms are frequently combined to describe intermediate types of lustre (for example, a "vitreous greasy" lustre). Some minerals exhibit unus ...
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Pierre-François Chabaneau
Pierre-François Chabaneau (27 June 1754 – 18 February 1842) was a French chemist who spent much of his life working in Spain. He was one of the first chemists to succeed in producing malleable platinum. Chabaneau was born in Dordogne, France, and died near his home village at the age of 88 years. Early life Chabaneau was born in 1754 in Nontron, a village in the Dordogne department of France. His uncle, a member of the order of Saint Anthony, encouraged him to study theology. While Chabaneau excelled in his studies, his distaste for metaphysical speculation led him to antagonize his teachers, which in turn caused him to be expelled from school. Sympathetic towards Chabaneau's state of poverty, the director of a Jesuit college in Passy offered him a position as a mathematics professor, despite Chabaneau having only a basic understanding of arithmetic. In studying the material for the next day's lessons, Chabaneau taught himself algebra and geometry. His academic interest s ...
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Charles Wood (ironmaster)
Charles Wood (1702 – October 1774) was an English ironmaster and one of the inventors of the potting and stamping method of making wrought iron from pig iron. Parents Charles Wood was the 7th of 15 children of William Wood of Wolverhampton and his wife Margaret, daughter of Richard Molyneux, an ironmonger in that area. William Wood followed his father-in-law's trade until 1715, when he became an ironmaster too and later entered into a contract to provide copper coinage for Ireland. He was also a projector, floating his business as an ironmaster as a joint stock company at the time of the South Sea Bubble (1720). Later, he sought to develop a new process of ironmaking and to obtain a charter for a "Company of Ironmasters of Great Britain". However the process (carried on at Frizington, Cumberland) produced little iron and he probably died in debt. Career Charles Wood was a partner in some of the businesses, and certainly in the final one. His father's will left him a l ...
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Antonio De Ulloa
Antonio de Ulloa y de la Torre-Giralt, FRS, FRSA, KOS (12 January 1716 – 3 July 1795) was a Spanish naval officer, scientist, and administrator. At the age of nineteen, he joined the French Geodesic Mission to what is now the country of Ecuador. That mission took more than eight years to complete its work, during which time Ulloa made many astronomical, natural, and social observations in South America. The reports of Ulloa's findings earned him an international reputation as a leading savant. Those reports include the first published observations of the metal platinum, later identified as a new chemical element. Ulloa was elected as a Fellow of the Royal Society of London in 1746, and as a foreign member of the Royal Swedish Academy of Sciences in 1751. Ulloa served the Spanish Crown as governor of Huancavelica (1758–64), in Perú, and superintendent of the quicksilver mines in the region. Following the defeat of France in the Seven Years' War, Ulloa was appoin ...
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2 Pallas
Pallas (minor-planet designation: 2 Pallas) is the second asteroid to have been discovered, after Ceres. It is believed to have a mineral composition similar to carbonaceous chondrite meteorites, like Ceres, though significantly less hydrated than Ceres. It is the third-largest asteroid in the Solar System by both volume and mass, and is a likely remnant protoplanet. It is 79% the mass of Vesta and 22% the mass of Ceres, constituting an estimated 7% of the mass of the asteroid belt. Its estimated volume is equivalent to a sphere in diameter, 90–95% the volume of Vesta. During the planetary formation era of the Solar System, objects grew in size through an accretion process to approximately the size of Pallas. Most of these protoplanets were incorporated into the growth of larger bodies, which became the planets, whereas others were ejected by the planets or destroyed in collisions with each other. Pallas, Vesta and Ceres appear to be the only intact bodies from this ...
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William Hyde Wollaston
William Hyde Wollaston (; 6 August 1766 – 22 December 1828) was an English chemist and physicist who is famous for discovering the chemical elements palladium and rhodium. He also developed a way to process platinum ore into malleable ingots.Melvyn C. UsselmanWilliam Hyde WollastonEncyclopædia Britannica, retrieved 31 March 2013 Life He was born in East Dereham in Norfolk, the son of the Francis Wollaston (1737–1815), a noted amateur astronomer, and his wife Althea Hyde. He was one of 17 children, but the family was financially well-off and he enjoyed an intellectually stimulating environment. He was educated privately (and remotely) at Charterhouse School from 1774 to 1778 then studied Sciences at Gonville and Caius College, Cambridge. In 1793 he obtained his doctorate (MD) in medicine from Cambridge University, and was a Fellow of his college from 1787 to 1828. He worked as a physician in Huntingdon from 1789 then moved to Bury St Edmunds before moving to London ...
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Bactria
Bactria (; Bactrian: , ), or Bactriana, was an ancient region in Central Asia in Amu Darya's middle stream, stretching north of the Hindu Kush, west of the Pamirs and south of the Gissar range, covering the northern part of Afghanistan, southwestern Tajikistan and southeastern Uzbekistan. Called "beautiful Bactria, crowned with flags" by the Avesta, the region is one of the sixteen perfect Iranian lands that the supreme deity Ahura Mazda had created. One of the early centres of Zoroastrianism and capital of the legendary Kayanian kings of Iran, Bactria is mentioned in the Behistun Inscription of Darius the Great as one of the satrapies of the Achaemenid Empire; it was a special satrapy and was ruled by a crown prince or an intended heir. Bactria was the centre of Iranian resistance against the Macedonian invaders after the fall of the Achaemenid Empire in the 4th century BC, but eventually fell to Alexander the Great. After the death of Alexander, Bactria was annexed by ...
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Indonesia
Indonesia, officially the Republic of Indonesia, is a country in Southeast Asia and Oceania between the Indian and Pacific oceans. It consists of over 17,000 islands, including Sumatra, Java, Sulawesi, and parts of Borneo and New Guinea. Indonesia is the world's largest archipelagic state and the 14th-largest country by area, at . With over 275 million people, Indonesia is the world's fourth-most populous country and the most populous Muslim-majority country. Java, the world's most populous island, is home to more than half of the country's population. Indonesia is a presidential republic with an elected legislature. It has 38 provinces, of which nine have special status. The country's capital, Jakarta, is the world's second-most populous urban area. Indonesia shares land borders with Papua New Guinea, East Timor, and the eastern part of Malaysia, as well as maritime borders with Singapore, Vietnam, Thailand, the Philippines, Australia, Palau, and India ...
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Sulfide Ore
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH−) are the conjugate acids of sulfide. Chemical properties The sulfide ion, S2−, does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8 MgI ...
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Laterite
Laterite is both a soil and a rock type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by intensive and prolonged weathering of the underlying parent rock, usually when there are conditions of high temperatures and heavy rainfall with alternate wet and dry periods. Tropical weathering (''laterization'') is a prolonged process of chemical weathering which produces a wide variety in the thickness, grade, chemistry and ore mineralogy of the resulting soils. The majority of the land area containing laterites is between the tropics of Cancer and Capricorn. Laterite has commonly been referred to as a soil type as well as being a rock type. This and further variation in the modes of conceptualizing about laterite (e.g. also as a complete weathering profile or theory about weathering) has led to calls for the term to be abandoned alto ...
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Refractory
In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, inorganic, non-metallic, porous, and heterogeneous. They are typically composed of oxides or carbides, nitrides etc. of the following materials: silicon, aluminium, magnesium, calcium, boron, chromium and zirconium. ASTM C71 defines refractories as "...non-metallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above ." Refractory materials are used in furnaces, kilns, incinerators, and reactors. Refractories are also used to make crucibles and moulds for casting glass and metals and for surfacing flame deflector systems for rocket launch structures. Today, the iron- and steel-industry and metal casting sectors use appr ...
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