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Flame Treatment
Flame treatment is the application of a gas flame to the surface of a material to improve adhesion. Polyolefins, especially polyethylene and polypropylene bond poorly, because they consist of long non-polar molecules. Without special treatment, adhesives, ink, and other coatings cannot be applied to these materials. By rapidly applying intense heat to a surface, molecular chains are broken and polar functional groups are added. Flame treatment also burns off dust, fibers, oils, and other surface contaminants. Flame treatment is faster than corona treatment, but requires more complicated and expensive equipment. Process Fuel gas is pre-mixed with air, and the resulting flame is directed at the surface to be treated. The flame has a light blue inner cone, called primary, and a dull blue outer cone, called secondary. The hottest part of the flame is the primary, which may be up The tip of the inner cone (primary) contains an assortment of highly reactive chemicals, including u ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adhesion
Adhesion is the tendency of dissimilar particles or surfaces to cling to one another ( cohesion refers to the tendency of similar or identical particles/surfaces to cling to one another). The forces that cause adhesion and cohesion can be divided into several types. The intermolecular forces responsible for the function of various kinds of stickers and sticky tape fall into the categories of chemical adhesion, dispersive adhesion, and diffusive adhesion. In addition to the cumulative magnitudes of these intermolecular forces, there are also certain emergent mechanical effects. Surface energy Surface energy is conventionally defined as the work that is required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cleave a bulk sample, creating two surfaces. If the new surfaces are identical, the surface energy γ of each surface is equal to half the work of cleavage, W: γ = (1/2)W11. If the surfac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydroxyl Radical
The hydroxyl radical is the diatomic molecule . The hydroxyl radical is very stable as a dilute gas, but it decays very rapidly in the condensed phase. It is pervasive in some situations. Most notably the hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also important in the field of radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen, which can enhance corrosion and SCC in coolant systems subjected to radioactive environments. In organic synthesis, hydroxyl radicals are most commonly generated by photolysis of 1-hydroxy-2(1''H'')-pyridinethione. Notation The unpaired electron of the hydroxyl radical is officially represented by a middle dot, •, beside the O. Biology Hydroxyl radicals can occasionally be produced as a byproduct of immune action. Macrophages and microglia most frequently generate this compound when exp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Finishing
Surface finishing is a broad range of industrial processes that alter the surface of a manufactured item to achieve a certain property. Finishing processes may be employed to: improve appearance, adhesion or wettability, solderability, corrosion resistance, tarnish resistance, chemical resistance, wear resistance, hardness, modify electrical conductivity, remove burrs and other surface flaws, and control the surface friction.. In limited cases some of these techniques can be used to restore original dimensions to salvage or repair an item. An unfinished surface is often called '' mill finish''. Surface finishing processes can be categorized by how they affect the workpiece: *Removing or reshaping finishing *Adding or altering finishing Mechanical processes may also be categorized together because of similarities the final surface finish. Adding and altering *Blanching * Burnishing * Calendering *Case hardening *Ceramic glaze *Cladding *Corona treatment *Diffusion processes: **C ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stone Flaming
Stone flaming or thermaling is the application of high temperature to the surface of stone to make it look like natural weathering. The sudden application of a torch to the surface of stone causes the surface layer to expand and flake off, exposing rough stone. Flaming works well on granite, because granite is made up of minerals with differing heat expansion rates. Process After removing a rock from a quarry, the rock is sliced into multiple flat slabs using a diamond gang saw. The saw leaves flat surfaces with circular marks. Flaming is done by wetting, and then running an oxygen-acetylene or oxygen-propane torch over the surface. As shown in both pictures, the torch is usually held at a 45 degree angle to the stone, so that released glowing sand grains are blown away in a harmless direction. Alternatives Alternative techniques for creating a rough surface on sawed stone include: * bush hammering * sandblasting Sandblasting, sometimes known as abrasive blas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymeric Surface
Polymeric materials have widespread application due to their versatile characteristics, cost-effectiveness, and highly tailored production. The science of polymer synthesis allows for excellent control over the properties of a bulk polymer sample. However, surface interactions of polymer substrates are an essential area of study in biotechnology, nanotechnology, and in all forms of coating applications. In these cases, the surface characteristics of the polymer and material, and the resulting forces between them largely determine its utility and reliability. In biomedical applications for example, the bodily response to foreign material, and thus biocompatibility, is governed by surface interactions. In addition, surface science is integral part of the formulation, manufacturing, and application of coatings. __TOC__ Chemical methods A polymeric material can be functionalized by the addition of small moieties, oligomers, and even other polymers (grafting copolymers) onto the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Corona Treatment
Corona treatment (sometimes referred to as air plasma) is a surface modification technique that uses a low temperature corona discharge plasma to impart changes in the properties of a surface. The corona plasma is generated by the application of high voltage to an electrode that has a sharp tip. The plasma forms at the tip. A linear array of electrodes is often used to create a curtain of corona plasma. Materials such as plastics, cloth, or paper may be passed through the corona plasma curtain in order to change the surface energy of the material. All materials have an inherent surface energy. Surface treatment systems are available for virtually any surface format including dimensional objects, sheets and roll goods that are handled in a web format. Corona treatment is a widely used surface treatment method in the plastic film, extrusion, and converting industries. History The corona treatment was invented by the Danish engineer Verner Eisby in 1951. Eisby had been asked by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Plasma Activation
Plasma activation (or plasma functionalization) is a method of surface modification employing plasma processing, which improves surface adhesion properties of many materials including metals, glass, ceramics, a broad range of polymers and textiles and even natural materials such as wood and seeds. Plasma functionalization also refers to the introduction of functional groups on the surface of exposed materials. It is widely used in industrial processes to prepare surfaces for bonding, gluing, coating and painting. Plasma processing achieves this effect through a combination of reduction of metal oxides, ultra-fine surface cleaning from organic contaminants, modification of the surface topography and deposition of functional chemical groups. Importantly, the plasma activation can be performed at atmospheric pressure using air or typical industrial gases including hydrogen, nitrogen and oxygen. Thus, the surface functionalization is achieved without expensive vacuum equipment or wet ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemistry Of Pressure-sensitive Adhesives
The chemistry of pressure-sensitive adhesives describes the chemical science associated with pressure-sensitive adhesives (PSA). PSA tapes and labels have become an important part of everyday life. These rely on adhesive material affixed to a backing such as paper or plastic film. Because of the inherent tackiness of the adhesive material and low surface energy, these tapes can be placed onto a variety of substrates when light pressure is applied, including paper, wood, metals, and ceramics. The design of tapes requires a balance of the need for long service life and adaptation to a variety of environmental and human effects, including temperature, UV exposure, mechanical wear, contamination of the substrate surface, and adhesive degradation.Werner Karmann and Andreas B. Kummer "Tapes, Adhesive" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2000. Composition A typical PSA tape consists of a pressure-sensitive adhesive (the sticky part of the tape) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Species
A chemical species is a chemical substance or ensemble composed of chemically identical molecular entity, molecular entities that can explore the same set of molecular energy levels on a characteristic or delineated time scale. These energy levels determine the way the chemical species will interact with others (engaging in chemical bonds, etc.). The species can be an atom, molecule, ion, or radical, and it has a specific chemical name and chemical formula. The term is also applied to a set of chemically identical atomic or molecular structural units in a solid array. In supramolecular chemistry, chemical species are those supramolecular structures whose interactions and associations are brought about via intermolecular bonding and debonding actions, and function to form the basis of this branch of chemistry. For instance: * The chemical species argon is an atom, atomic species of formula Ar; * dioxygen and ozone are different molecule, molecular species, of respective formulas O ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Allotropes Of Oxygen
There are several known allotropy, allotropes of oxygen. The most familiar is oxygen, molecular oxygen (O2), present at significant levels in Atmosphere of Earth, Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (O3). Others are: *Atomic oxygen (O1), a Radical (chemistry), free radical. *Singlet oxygen (O2*), one of two metastable states of molecular oxygen. *Tetraoxygen (O4), another metastable form. *Solid oxygen, existing in six variously colored phases, of which one is and another one metallic. Atomic oxygen Atomic oxygen, denoted O(3P) or O(3P), is very reactive, as the single atoms of oxygen tend to quickly bond with nearby molecules. On Earth's surface, it exists naturally for a very short time. In outer space, the presence of ample ultraviolet radiation results in a low Earth orbit atmosphere in which 96% of the oxygen occurs in atomic form. Ryan D. McCulla, Saint Louis University (2010). [//acswebcontent.acs.o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Materials Today
''Materials Today'' is a monthly peer-reviewed scientific journal, website, and journal family. The parent journal was established in 1998 and covers all aspects of materials science. It is published by Elsevier and the editors-in-chief are Jun Lou (Rice University) and Gleb Yushin (Georgia Institute of Technology). The journal principally publishes invited review articles, but other formats are also included, such as primary research articles, news items, commentaries, and opinion pieces on subjects of interest to the field. The website publishes news, educational webinars, podcasts, and blogs, as well as a jobs and events board. According to the ''Journal Citation Reports'', the journal has a 2020 impact factor of 31.041. The journal family includes ''Applied Materials Today'', ''Materials Today Chemistry'', ''Materials Today Energy'', ''Materials Today Physics'', ''Materials Today Nano, Materials Today Sustainability,'' ''Materials Today Communications'', ''Materials Today Adva ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Radical (chemistry)
In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most organic radicals have short lifetimes. A notable example of a radical is the hydroxyl radical (HO·), a molecule that has one unpaired electron on the oxygen atom. Two other examples are triplet oxygen and triplet carbene (꞉) which have two unpaired electrons. Radicals may be generated in a number of ways, but typical methods involve redox reactions. Ionizing radiation, heat, electrical discharges, and electrolysis are known to produce radicals. Radicals are intermediates in many chemical reactions, more so than is apparent from the balanced equations. Radicals are important in combustion, atmospheric chemistry, polymerization, plasma chemistry, biochemistry, and many other chemical processes. A majority of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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