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Fluorine Cycle
The fluorine cycle is the series of biogeochemical processes through which fluorine moves through the lithosphere, hydrosphere, atmosphere, and biosphere. Fluorine originates from the Earth’s crust, and its cycling between various sources and sinks is modulated by a variety of natural and anthropogenic processes. Overview Fluorine is the thirteenth most abundant element on Earth and the 24th most abundant element in the universe. It the most electronegative element and it is highly reactive. Thus, it is rarely found in its elemental state, although elemental fluorine has been identified in certain geochemical contexts. Instead, it is most frequently found in ionic compounds (e.g. HF, CaF2). The major mechanisms that mobilize fluorine are chemical and mechanical weathering of rocks. Major anthropogenic sources include industrial chemicals and fertilizers, brick manufacturing, and groundwater extraction. Fluorine is primarily carried by rivers to the oceans, where it has a res ...
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Brick-making
A brickworks, also known as a brick factory, is a factory for the manufacturing of bricks, from clay or shale. Usually a brickworks is located on a clay bedrock (the most common material from which bricks are made), often with a quarry for clay on site. In earlier times bricks were made at brickfields, which would be returned to agricultural use after the clay layer was exhausted. Equipment Most brickworks have some or all of the following: *A kiln, for firing, or 'burning' the bricks. *Drying yard or shed, for drying bricks before firing. *A building or buildings for manufacturing the bricks. *A quarry for clay. *A pugmill or clay preparation plant (see below). Brick making Bricks were originally made by hand, and that practice continues in developing countries and with a few specialty suppliers. Large industrial brickworks supply clay from a quarry, moving it by conveyor belt or truck/lorry to the main factory, although it may be stockpiled outside before entering the mac ...
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Fluorapatite
Fluorapatite, often with the alternate spelling of fluoroapatite, is a phosphate mineral with the formula Ca5(PO4)3F (calcium fluorophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blue, yellow, violet, or colorless), the pure mineral is colorless, as expected for a material lacking transition metals. Along with hydroxylapatite, it can be a component of tooth enamel, but for industrial use both minerals are mined in the form of phosphate rock, whose usual mineral composition is primarily fluorapatite but often with significant amounts of the other. Fluorapatite crystallizes in a hexagonal crystal system. It is often combined as a solid solution with hydroxylapatite (Ca5(PO4)3OH or Ca10(PO4)6(OH)2) in biological matrices. Chlorapatite (Ca5(PO4)3Cl) is another related structure. Industrially, the mineral is an important source of both phosphoric and hydrofluoric acids. Fluorapatite as a mineral is the most common p ...
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Stratosphere
The stratosphere () is the second layer of the atmosphere of the Earth, located above the troposphere and below the mesosphere. The stratosphere is an atmospheric layer composed of stratified temperature layers, with the warm layers of air high in the sky and the cool layers of air in the low sky, close to the planetary surface of the Earth. The increase of temperature with altitude is a result of the absorption of the Sun's ultraviolet (UV) radiation by the ozone layer. The temperature inversion is in contrast to the troposphere, near the Earth's surface, where temperature decreases with altitude. Between the troposphere and stratosphere is the tropopause border that demarcates the beginning of the temperature inversion. Near the equator, the lower edge of the stratosphere is as high as , at midlatitudes around , and at the poles about . Temperatures range from an average of near the tropopause to an average of near the mesosphere. Stratospheric temperatures also vary w ...
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Photochemistry
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400  nm), visible light (400–750 nm) or infrared radiation (750–2500 nm). In nature, photochemistry is of immense importance as it is the basis of photosynthesis, vision, and the formation of vitamin D with sunlight. Photochemical reactions proceed differently than temperature-driven reactions. Photochemical paths access high energy intermediates that cannot be generated thermally, thereby overcoming large activation barriers in a short period of time, and allowing reactions otherwise inaccessible by thermal processes. Photochemistry can also be destructive, as illustrated by the photodegradation of plastics. Concept Grotthuss–Draper law and Stark-Einstein law Photoexcitation is the first step in a photochemical process where the reactant is elevated ...
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Chlorine Oxide
Chlorine and oxygen can bond in many ways: * chlorine monoxide, , chlorine (II) oxide * chlorine peroxide, , dimer of chlorine (II) oxide *chlorine dioxide, , chlorine (IV) oxide * chloroperoxyl, *chlorine trioxide, ClO3, chlorine (VI) oxide *dichlorine monoxide, Cl2O, chlorine (I) oxide *Three dichlorine dioxides: **ClO dimer, Cl2O2, chlorine (I) peroxide **chloryl chloride, ClO2Cl, chlorine (0,IV) oxide ** chlorine chlorite, ClOClO, chlorine (I,III) oxide * dichlorine trioxide, Cl2O3, chlorine (I,V) oxide *dichlorine tetroxide, also known as chlorine perchlorate, ClOClO3, chlorine (I,VII) oxide *dichlorine pentoxide, Cl2O5, is hypothetical *dichlorine hexoxide, chloryl perchlorate, Cl2O6, chlorine (V,VII) oxide *dichlorine heptoxide, Cl2O7, chlorine (VII) oxide *chlorine tetroxide, * chlorine (VII) oxide peroxide, (OClO3)2 Several ions are also chlorine oxides: *chloryl, * perchloryl, * hypochlorite, ClO− * chlorite, ClO2− * chlorate, ClO3− *perchlorate, ClO4− See a ...
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Chlorine
Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between them. Chlorine is a yellow-green gas at room temperature. It is an extremely reactive element and a strong oxidising agent: among the elements, it has the highest electron affinity and the third-highest electronegativity on the revised Electronegativity#Pauling electronegativity, Pauling scale, behind only oxygen and fluorine. Chlorine played an important role in the experiments conducted by medieval Alchemy, alchemists, which commonly involved the heating of chloride Salt (chemistry), salts like ammonium chloride (sal ammoniac) and sodium chloride (common salt), producing various chemical substances containing chlorine such as hydrogen chloride, mercury(II) chloride (corrosive sublimate), and hydrochloric acid (in the form of ). However ...
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Chlorofluorocarbon
Chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are fully or partly halogenated hydrocarbons that contain carbon (C), hydrogen (H), chlorine (Cl), and fluorine (F), produced as volatile derivatives of methane, ethane, and propane. They are also commonly known by the DuPont brand name Freon. The most common representative is dichlorodifluoromethane (R-12 or Freon-12). Many CFCs have been widely used as refrigerants, propellants (in aerosol applications), and solvents. Because CFCs contribute to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs) including R-410A and R-134a. Structure, properties and production As in simpler alkanes, carbon in the CFCs bond with tetrahedral symmetry. Because the fluorine and chlorine atoms differ greatly in size and effective charge from hydrogen and from each other, t ...
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Uranium Fluoride
Uranium fluoride can refer to: * Uranium trifluoride, UF3 * Uranium tetrafluoride, UF4 * Uranium pentafluoride, UF5 * Uranium hexafluoride, UF6 * Tetrauranium heptadecafluoride, U4F17 * Tetrauranium octadecafluoride, U4F18 See also *Uranyl fluoride Uranyl fluoride is the inorganic compound with the formula UO2F2. As shown by x-ray crystallography, the uranyl (UO22+) centers are complemented by six fluoride ligands. This salt is very soluble in water as well as hygroscopic. It is forms in th ..., UO2F2 {{Chemistry index ...
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Semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glass. Its electrical resistivity and conductivity, resistivity falls as its temperature rises; metals behave in the opposite way. Its conducting properties may be altered in useful ways by introducing impurities ("doping (semiconductor), doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common s ...
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Micromolar
Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter, having the unit symbol mol/L or mol/ dm3 in SI unit. A solution with a concentration of 1 mol/L is said to be 1 molar, commonly designated as 1 M. Definition Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase c: :c = \frac = \frac = \frac. Here, n is the amount of the solute in moles, N is the number of constituent particles present in volume V (in litres) of the solution, and N_\text is t ...
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Surface Runoff
Surface runoff (also known as overland flow) is the flow of water occurring on the ground surface when excess rainwater, stormwater, meltwater, or other sources, can no longer sufficiently rapidly infiltrate in the soil. This can occur when the soil is saturated by water to its full capacity, and the rain arrives more quickly than the soil can absorb it. Surface runoff often occurs because impervious areas (such as roofs and pavement) do not allow water to soak into the ground. Furthermore, runoff can occur either through natural or man-made processes. Surface runoff is a major component of the water cycle. It is the primary agent of soil erosion by water. The land area producing runoff that drains to a common point is called a drainage basin. Runoff that occurs on the ground surface before reaching a channel can be a nonpoint source of pollution, as it can carry man-made contaminants or natural forms of pollution (such as rotting leaves). Man-made contaminants in runoff i ...
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