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Discotic Liquid Crystal
Discotic liquid crystals are mesophases formed from disc-shaped molecules known as "discotic mesogens". These phases are often also referred to as columnar phases. Discotic mesogens are typically composed of an aromatic core surrounded by flexible alkyl chains. The aromatic cores allow charge transfer in the stacking direction through the π conjugate systems. The charge transfer allows the discotic liquid crystals to be electrically semiconductive along the stacking direction. Applications have been focusing on using these systems in photovoltaic devices, organic light emitting diodes (OLED), and molecular wires. Discotics have also been suggested for use in compensation films, for LCD displays. Photovoltaic devices Discotic liquid crystals have similar potential to the conducting polymers for their use in photovoltaic cells, they have the same technical challenges of low conductivity and sensitivity to UV damage as the polymer designs. However one advantage is the self-healing p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mesophase
In chemistry and chemical physics, a mesophase is a state of matter intermediate between liquid and solid. Gelatin is a common example of a partially ordered structure in a mesophase. Further, biological structures such as the lipid bilayers of cell membranes are examples of mesophases. Georges Friedel (1922) called attention to the "mesomorphic states of matter" in his scientific assessment of observations of the so-called liquid crystals. Conventionally a crystal is solid, and crystallization converts liquid to solid. The oxymoron of the liquid crystal is resolved through the notion of mesophases. The observations noted an optic axis persisting in materials that had been melted and had begun to flow. The term ''liquid crystal'' persists as a colloquialism, but use of the term was criticized in 1993: In ''The Physics of Liquid Crystals''P.G. de Gennes & J. Prost (1993) ''The Physics of Liquid Crystals'', 2nd edition, Oxford University Press the mesophases are introduced from ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Columnar Phase
The columnar phase is a class of mesophases in which molecules assemble into cylindrical structures to act as mesogens. Originally, these kinds of liquid crystals were called discotic liquid crystals or bowlic liquid crystals because the columnar structures are composed of flat-shaped discotic or bowl-shaped molecules stacked one-dimensionally. Since recent findings provide a number of columnar liquid crystals consisting of non-discoid mesogens, it is more common now to classify this state of matter and compounds with these properties as columnar liquid crystals. Takuzo Aida and co-workers recently reported cyclic peptides that self-assemble into polar columnar organizations. These materials can be unidirectionally aligned over large areas by application of an external electric field. Classes Columnar liquid crystals are grouped by their structural order and the ways of packing of the columns. Nematic columnar liquid crystals have no long-range order and are less organized than ot ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Intervalence Charge Transfer
192 px, The intense blue color of Prussian blue is a consequence of an intervalence charge transfer band. In chemistry, intervalence charge transfer, often abbreviated IVCT or even IT, is a type of charge-transfer band that is associated with mixed valence compounds. It is most common for systems with two metal sites differing only in oxidation state. Quite often such electron transfer reverses the oxidation states of the sites. The term is frequently extended to the case of metal-to-metal charge transfer between non-equivalent metal centres. The transition produces a characteristically intense absorption in the electromagnetic spectrum. The band is usually found in the visible or near infrared region of the spectrum and is broad. The process can be described as follows: :LnM+-bridge-M'Ln + hν → LnM-bridge-M'+Ln where L is a bridging ligand In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions. The ligand may be a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Liquid Crystal
Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid crystal may flow like a liquid, but its molecules may be oriented in a crystal-like way. There are many types of LC phases, which can be distinguished by their optical properties (such as textures). The contrasting textures arise due to molecules within one area of material ("domain") being oriented in the same direction but different areas having different orientations. LC materials may not always be in a LC state of matter (just as water may be ice or water vapor). Liquid crystals can be divided into 3 main types: * thermotropic, *lyotropic, and * metallotropic. Thermotropic and lyotropic liquid crystals consist mostly of organic molecules, although a few minerals are also known. Thermotropic LCs exhibit a phase transition into the LC phase as temperature changes. Lyotropic LCs exhibit phase transitions as a function of b ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Light-emitting Diode
A light-emitting diode (LED) is a semiconductor device that emits light when current flows through it. Electrons in the semiconductor recombine with electron holes, releasing energy in the form of photons. The color of the light (corresponding to the energy of the photons) is determined by the energy required for electrons to cross the band gap of the semiconductor. White light is obtained by using multiple semiconductors or a layer of light-emitting phosphor on the semiconductor device. Appearing as practical electronic components in 1962, the earliest LEDs emitted low-intensity infrared (IR) light. Infrared LEDs are used in remote-control circuits, such as those used with a wide variety of consumer electronics. The first visible-light LEDs were of low intensity and limited to red. Early LEDs were often used as indicator lamps, replacing small incandescent bulbs, and in seven-segment displays. Later developments produced LEDs available in visible, ultraviolet (UV) ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conductive Polymer
Conductive polymers or, more precisely, intrinsically conducting polymers (ICPs) are organic polymers that conduct electricity. Such compounds may have metallic conductivity or can be semiconductors. The biggest advantage of conductive polymers is their processability, mainly by dispersion. Conductive polymers are generally not thermoplastics, ''i.e.'', they are not thermoformable. But, like insulating polymers, they are organic materials. They can offer high electrical conductivity but do not show similar mechanical properties to other commercially available polymers. The electrical properties can be fine-tuned using the methods of organic synthesis and by advanced dispersion techniques. History Polyaniline was first described in the mid-19th century by Henry Letheby, who investigated the electrochemical and chemical oxidation products of aniline in acidic media. He noted that reduced form was colourless but the oxidized forms were deep blue. The first highly-conductive organ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solar Cell
A solar cell, or photovoltaic cell, is an electronic device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physical and chemical phenomenon.Solar Cells chemistryexplained.com It is a form of photoelectric cell, defined as a device whose electrical characteristics, such as , , or resistance, vary when exposed to light. Individual solar cell devices are often the electrical ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Self-healing
Self-healing refers to the process of recovery (generally from psychological disturbances, trauma, etc.), motivated by and directed by the patient, guided often only by instinct. Such a process encounters mixed fortunes due to its amateur nature, although self-motivation is a major asset. The value of self-healing lies in its ability to be tailored to the unique experience and requirements of the individual. The process can be helped and accelerated with introspection techniques such as Meditation. The different meanings of self-healing Self-healing is the ultimate phase of Gestalt Therapy. Self-healing may refer to automatic, homeostatic processes of the body that are controlled by physiological mechanisms inherent in the organism. Disorders of the spirit and the absence of faith can be self-healed. In a figurative sense, self-healing properties can be ascribed to systems or processes, which by nature or design tend to correct any disturbances brought into them. Such as the reg ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Physics
Chemical physics is a subdiscipline of chemistry and physics that investigates physicochemical phenomena using techniques from atomic and molecular physics and condensed matter physics; it is the branch of physics that studies chemical processes from the point of view of physics. While at the interface of physics and chemistry, chemical physics is distinct from physical chemistry in that it focuses more on the characteristic elements and theories of physics. Meanwhile, physical chemistry studies the physical nature of chemistry. Nonetheless, the distinction between the two fields is vague, and scientists often practice in both fields during the course of their research. The United States Department of Education defines chemical physics as "A program that focuses on the scientific study of structural phenomena combining the disciplines of physical chemistry and atomic/molecular physics. Includes instruction in heterogeneous structures, alignment and surface phenomena, quantum t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perylene
Perylene or perilene is a polycyclic aromatic hydrocarbon with the chemical formula C20H12, occurring as a brown solid. It or its derivatives may be carcinogenic, and it is considered to be a hazardous pollutant. In cell membrane cytochemistry, perylene is used as a fluorescent lipid probe. It is the parent compound of a class of rylene dyes. Reactions Like other polycyclic aromatic compounds, perylene is reduced by alkali metals to give a deeply colored radical anion and a dianion. The diglyme solvates of these salts have been characterized by X-ray crystallography. Emission Perylene displays blue fluorescence. It is used as a blue-emitting dopant material in OLEDs, either pure or substituted. Perylene can be also used as an organic photoconductor. It has an absorption maximum at 434 nm, and as with all polycyclic aromatic compounds, low water solubility (1.2 x 10−5 mmol/L). Perylene has a molar absorptivity of 38,500 M−1cm−1 at 435.7 nm. Image:Perylene ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hexabenzocoronene
Hexa-peri-hexabenzocoronene (HBC) is a polycyclic aromatic hydrocarbon with the molecular formula C42H18. It consists of a central coronene molecule, with an additional benzene ring fused between each adjacent pair of rings around the periphery. It is sometimes simply called hexabenzocoronene, however, there are other chemicals that share this less-specific name, such as hexa-cata-hexabenzocoronene. Hexa-peri-hexabenzocoronene has been imaged by atomic force microscopy (AFM) providing the first example of a molecule in which differences in bond order and bond lengths of the individual bonds can be distinguished by a measurement in Position and momentum space, direct space. Supramolecular structures Various hexabenzocoronenes have been investigated in supramolecular electronics. They are known to Molecular self-assembly, self-assemble into a columnar phase. One derivative in particular forms carbon nanotubes with interesting electrical properties. The columnar phase in this com ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Triphenylene
Triphenylene is an organic compound with the formula (C6H4)3. A flat polycyclic aromatic hydrocarbon (PAH), it consists of four fused benzene rings. Triphenylene has delocalized 18-''π''-electron systems based on a planar structure, corresponding to the symmetry group ''D''3h. It is a white or colorless solid. Preparation Triphenylene can be isolated from coal tar. It is also be synthesized in various ways. One method is trimerization of benzyne. Another method involves trapping benzyne with a biphenyl derivative. Properties Triphenylene is more resonance stable than its isomers chrysene, benz 'a''nthracene, benzo 'c''henanthrene, and tetracene. For this reason triphenylene resists hydrogenation. As a disc-shaped, planar molecule, triphenylene has attracted attention as the core of discotic mesogen in liquid crystal Liquid crystal (LC) is a state of matter whose properties are between those of conventional liquids and those of solid crystals. For example, a liquid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
