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Covellite
Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known to mineral collectors. The mineral is generally found in zones of secondary enrichment ( supergene) of copper sulfide deposits. Commonly found as coatings on chalcocite, chalcopyrite, bornite, enargite, pyrite, and other sulfides, it often occurs as pseudomorphic replacements of other minerals. The first records are from Mount Vesuvius, formally named in 1832 after N. Covelli. Composition Covellite belongs to the binary copper sulfides group, which has the formula CuxSy and can have a wide-ranging copper/sulfur ratio, from 1:2 to 2:1 (Cu/S). However, this series is by no means continuous and the homogeneity range of covellite CuS is narrow. Materials rich in sulfur CuSx where x~ 1.1- 1.2 do exist, but they exhibit " superstructures", a m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Covellite And Pyrite (V)
Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known to mineral collectors. The mineral is generally found in zones of secondary enrichment ( supergene) of copper sulfide deposits. Commonly found as coatings on chalcocite, chalcopyrite, bornite, enargite, pyrite, and other sulfides, it often occurs as pseudomorphic replacements of other minerals. The first records are from Mount Vesuvius, formally named in 1832 after N. Covelli. Composition Covellite belongs to the binary copper sulfides group, which has the formula CuxSy and can have a wide-ranging copper/sulfur ratio, from 1:2 to 2:1 (Cu/S). However, this series is by no means continuous and the homogeneity range of covellite CuS is narrow. Materials rich in sulfur CuSx where x~ 1.1- 1.2 do exist, but they exhibit " superstructures", a m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper Monosulfide
Copper monosulfide is a chemical compound of copper and sulfur. It was initially thought to occur in nature as the dark indigo blue mineral covellite. However, it was later shown to be rather a cuprous compound, formula Cu+3S(S2).Liang, W., Whangbo, M.H. (1993) ''Conductivity anisotropy and structural phase transition in Covellite CuS'' Solid State Communications, 85(5), 405-408 CuS is a moderate conductor of electricity.Wells A.F. (1962) ''Structural Inorganic Chemistry'' 3d edition Oxford University Press A black colloidal precipitate of CuS is formed when hydrogen sulfide, H2S, is bubbled through solutions of Cu(II) salts. It is one of a number of binary compounds of copper and sulfur (see copper sulfide for an overview of this subject), and has attracted interest because of its potential uses in catalysis and photovoltaics. Manufacturing Copper monosulfide can be prepared by passing hydrogen sulfide gas into a solution of copper(II) salt. Alternatively, it can be prepared by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper Sulfide
Copper sulfides describe a family of chemical compounds and minerals with the formula CuxSy. Both minerals and synthetic materials comprise these compounds. Some copper sulfides are economically important ores. Prominent copper sulfide minerals include Cu2S (chalcocite) and CuS (covellite). In the mining industry, the minerals bornite or chalcopyrite, which consist of mixed copper-iron sulfides, are often referred to as "copper sulfides". In chemistry, a "binary copper sulfide" is any binary chemical compound of the elements copper and sulfur. Whatever their source, copper sulfides vary widely in composition with 0.5 ≤ Cu/S ≤ 2, including numerous non-stoichiometric compounds. Known copper sulfides The naturally occurring mineral binary compounds of copper and sulfur are listed below. Investigations of covellite (CuS) indicate that there are other metastable Cu-S phases still to be fully characterised. * CuS2, villamaniniteWells A.F. (1984) ''Structural Inorganic Chemistr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Copper
Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. Copper is one of the few metals that can occur in nature in a directly usable metallic form ( native metals). This led to very early human use in several regions, from circa 8000 BC. Thousands of years later, it was the first metal to be smelted from sulfide ores, circa 5000 BC; the first metal to be cast into a shape in a mold, c. 4000 BC; and the first metal to be purposely alloyed with another metal, tin, to create ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Supergene (geology)
In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary (hypogene) sulfide ore minerals and redistribute the metallic ore elements. Supergene ''enrichment'' occurs at the base of the oxidized portion of an ore deposit. Metals that have been leached from the oxidized ore are carried downward by percolating groundwater, and react with hypogene sulfides at the supergene-hypogene boundary. The reaction produces secondary sulfides with metal contents higher than those of the primary ore. This is particularly noted in copper ore deposits where the copper sulfide minerals chalcocite (Cu2S), covellite (CuS), digenite (Cu18S10), and djurleite (Cu31S16) are deposited by the descending surfa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chalcopyrite
Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green-tinged black. On exposure to air, chalcopyrite tarnishes to a variety of oxides, hydroxides, and sulfates. Associated copper minerals include the sulfides bornite (Cu5FeS4), chalcocite (Cu2S), covellite (CuS), digenite (Cu9S5); carbonates such as malachite and azurite, and rarely oxides such as cuprite (Cu2O). Is rarely found in association with native copper. Chalcopyrite is a conductor of electricity. Etymology The name chalcopyrite comes from the Greek words , which means copper, and ', which means striking fire. It was sometimes historically referred to as "yellow copper". Identification Chalcopyrite is often confused with pyrite and gold since all three of these minerals have a yell ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Enargite
Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as well as massive aggregates. It has a hardness of 3 and a specific gravity of 4.45. Enargite is dimorph of the tetragonal luzonite. Occurrence It is a medium to low temperature hydrothermal mineral occurring with quartz, pyrite, sphalerite, galena, bornite, tetrahedrite–tennantite, chalcocite, covellite and baryte. It occurs in the mineral deposits at Butte, Montana, San Juan Mountains, Colorado and at both Bingham Canyon and Tintic, Utah. It is also found in the copper mines of Canada, Mexico, Argentina, Chile, Peru, and the Philippines. Enargite was originally described as a new species from the copper mines of the San Francisco vein, Junin Department, Peru , image_flag = Flag of Peru.svg , image_coat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bornite
Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5 Fe S4 that crystallizes in the orthorhombic system (pseudo-cubic). Appearance Bornite has a brown to copper-red color on fresh surfaces that tarnishes to various iridescent shades of blue to purple in places. Its striking iridescence gives it the nickname ''peacock copper'' or ''peacock ore''. Mineralogy Bornite is an important copper ore mineral and occurs widely in porphyry copper deposits along with the more common chalcopyrite. Chalcopyrite and bornite are both typically replaced by chalcocite and covellite in the supergene enrichment zone of copper deposits. Bornite is also found as disseminations in mafic igneous rocks, in contact metamorphic skarn deposits, in pegmatites and in sedimentary cupriferous shales. It is important as an ore for its copper content of about 63 percent by mass. Structure At temperatures above , the structure is isometric with a unit cell that is about 5.5 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chalcocite
Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. The term ''chalcocite'' comes from the alteration of the obsolete name ''chalcosine'', from the Greek ''khalkos'', meaning "copper". It is also known as redruthite, vitreous copper, or copper-glance. Occurrence Chalcocite is sometimes found as a primary vein mineral in hydrothermal veins. However, most chalcocite occurs in the supergene enriched environment below the oxidation zone of copper deposits as a result of the leaching of copper from the oxidized minerals. It is also often found in sedimentary rocks. It has been mined for centuries and is one of the most profitable copper ores. The reasons for this is its high copper content (66.7% atomic ratio and nearly 80% by weight) and the ease at which copper can be separated from sulfur. ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfide Mineral
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the arsenides, the antimonides, the bismuthinides, the sulfarsenides and the sulfosalts.http://www.minerals.net/mineral/sort-met.hod/group/sulfgrp.htm Minerals.net Dana Classification, SulfidesKlein, Cornelis and Cornelius S. Hurlbut, Jr., 1986, ''Manual of Mineralogy'', Wiley, 20th ed., pp 269-293 Sulfide minerals are inorganic compounds. Minerals Common or important examples include: * Acanthite *Chalcocite *Bornite * Galena * Sphalerite *Chalcopyrite *Pyrrhotite *Millerite *Pentlandite *Covellite *Cinnabar *Realgar *Orpiment *Stibnite *Pyrite *Marcasite *Molybdenite Sulfarsenides: *Cobaltite *Arsenopyrite *Gersdorffite Sulfosalts: *Pyrargyrite *Proustite *Tetrahedrite *Tennantite *Enargite *Bournonite * ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Semiconductor
A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glass. Its electrical resistivity and conductivity, resistivity falls as its temperature rises; metals behave in the opposite way. Its conducting properties may be altered in useful ways by introducing impurities ("doping (semiconductor), doping") into the crystal structure. When two differently doped regions exist in the same crystal, a semiconductor junction is created. The behavior of charge carriers, which include electrons, ions, and electron holes, at these junctions is the basis of diodes, transistors, and most modern electronics. Some examples of semiconductors are silicon, germanium, gallium arsenide, and elements near the so-called "metalloid staircase" on the periodic table. After silicon, gallium arsenide is the second-most common s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pauli Paramagnetism
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, Magnetization, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetism, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some Chemical compound, compounds; they have a relative magnetic permeability slightly greater than 1 (i.e., a small positive magnetic susceptibility) and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer. Paramagnetism is due to the presence of unpaire ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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