Bornite, also known as peacock ore, is a

sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...

with chemical composition Cu₅ Fe S₄ that crystallizes in the orthorhombic system (pseudo-cubic).

Appearance

Bornite has a brown to copper-red color on fresh surfaces that tarnishes to various

iridescent Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfl ...

shades of blue to purple in places. Its striking iridescence gives it the nickname ''peacock copper'' or ''peacock ore''.

Mineralogy

Bornite is an important copper ore mineral and occurs widely in

porphyry copper deposit Porphyry copper deposits are copper ore bodies that are formed from hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those fluids are vertical dikes of ...

s along with the more common

chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...

. Chalcopyrite and bornite are both typically replaced by

chalcocite Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. The ...

and

covellite Covellite (also known as covelline) is a rare copper sulfide mineral with the formula CuS. This indigo blue mineral is commonly a secondary mineral in limited abundance and although it is not an important ore of copper itself, it is well known t ...

in the supergene enrichment zone of copper deposits. Bornite is also found as disseminations in

mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...

igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main The three types of rocks, rock types, the others being Sedimentary rock, sedimentary and metamorphic rock, metamorphic. Igneous rock ...

s, in

contact metamorphic Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of che ...

skarn Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals ...

deposits, in

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...

s and in

sedimentary Sedimentary rocks are types of rock (geology), rock that are formed by the accumulation or deposition of mineral or organic matter, organic particles at Earth#Surface, Earth's surface, followed by cementation (geology), cementation. Sedimentati ...

cupriferous

shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especial ...

s. It is important as an

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...

for its

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...

content of about 63 percent by mass.

Structure

At temperatures above , the structure is isometric with a unit cell that is about 5.50 Å on an edge. This structure is based on cubic close-packed

sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...

atoms, with copper and iron atoms randomly distributed into six of the eight

tetrahedral In geometry, a tetrahedron (plural: tetrahedra or tetrahedrons), also known as a triangular pyramid, is a polyhedron composed of four triangular faces, six straight edges, and four vertex corners. The tetrahedron is the simplest of all the ...

sites located in the octants of the cube. With cooling, the Fe and Cu become ordered, so that 5.5 Å subcells in which all eight tetrahedral sites are filled alternate with subcells in which only four of the tetrahedral sites are filled; symmetry is reduced to orthorhombic.Nesse, William D., "Sulfides and Related Minerals" in ''Introduction to Mineralogy,'' New York: Oxford University Press, 2000, p 429

Composition

Substantial variation in the relative amounts of copper and iron is possible and

solid solution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word ...

extends towards

(CuFeS₂) and

digenite Digenite is a copper sulfide mineral with formula: Cu9S5. Digenite is a black to dark blue opaque mineral that crystallizes with a trigonal - hexagonal scalenohedral structure. In habit it is usually massive, but does often show pseudo-cubic f ...

(Cu₉S₅).

Exsolution A solid solution, a term popularly used for metals, is a homogenous mixture of two different kinds of atoms in solid state and have a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The wor ...

of blebs and

lamellae Lamella (plural lamellae) means a small plate or flake in Latin, and in English may refer to: Biology * Lamella (mycology), a papery rib beneath a mushroom cap * Lamella (botany) * Lamella (surface anatomy), a plate-like structure in an animal * ...

of chalcopyrite, digenite, and

is common.

Form and twinning

Rare crystals are approximately cubic,

dodecahedral In geometry, a dodecahedron (Greek , from ''dōdeka'' "twelve" + ''hédra'' "base", "seat" or "face") or duodecahedron is any polyhedron with twelve flat faces. The most familiar dodecahedron is the regular dodecahedron with regular pentagon ...

, or

octahedral In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet at ea ...

. Usually massive. Penetration twinning on the crystallographic direction, .

Occurrence

It occurs globally in copper ores with notable crystal localities in

Butte __NOTOC__ In geomorphology, a butte () is an isolated hill with steep, often vertical sides and a small, relatively flat top; buttes are smaller landforms than mesas, plateaus, and tablelands. The word ''butte'' comes from a French word mea ...

Montana Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columbi ...

and at

Bristol Bristol () is a city, ceremonial county and unitary authority in England. Situated on the River Avon, it is bordered by the ceremonial counties of Gloucestershire to the north and Somerset to the south. Bristol is the most populous city in ...

Connecticut Connecticut () is the southernmost state in the New England region of the Northeastern United States. It is bordered by Rhode Island to the east, Massachusetts to the north, New York to the west, and Long Island Sound to the south. Its cap ...

in the U.S. It is also collected from the Carn Brea mine,

Illogan Illogan (pronounced ''il'luggan'', kw, Egloshalow) is a village and civil parish in west Cornwall, UK, two miles (3 km) northwest of Redruth. The population of Illogan was 5,404 at the 2011 census. In the same year the population of the Ca ...

, and elsewhere in

Cornwall Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic ...

England England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...

. Large crystals are found from the Frossnitz Alps, eastern

Tirol Tyrol (; historically the Tyrole; de-AT, Tirol ; it, Tirolo) is a historical region in the Alps - in Northern Italy and western Austria. The area was historically the core of the County of Tyrol, part of the Holy Roman Empire, Austrian Emp ...

Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...

; the Mangula mine,

Lomagundi district Lomagundi is a former district of Zimbabwe, originally an alternative form of the name ''Nemakonde'', who was a chief of the Shona in the area. The eastern border of Lomagundi was the Great Dyke The Great Dyke is a linear geological feature t ...

Zimbabwe Zimbabwe (), officially the Republic of Zimbabwe, is a landlocked country located in Southeast Africa, between the Zambezi and Limpopo Rivers, bordered by South Africa to the south, Botswana to the south-west, Zambia to the north, and Mozam ...

; from the N'ouva mine, Talate,

Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to ...

, the West Coast of Tasmania and in Dzhezkazgan,

Kazakhstan Kazakhstan, officially the Republic of Kazakhstan, is a transcontinental country located mainly in Central Asia and partly in Eastern Europe. It borders Russia to the north and west, China to the east, Kyrgyzstan to the southeast, Uzbeki ...

. There are also traces of it found amongst the

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...

in the

Pilbara The Pilbara () is a large, dry, thinly populated region in the north of Western Australia. It is known for its Aboriginal peoples; its ancient landscapes; the red earth; and its vast mineral deposits, in particular iron ore. It is also a glo ...

region of

Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to th ...

History and etymology

It was first described in 1725 for an occurrence in the Krušné Horny Mountains ( Erzgebirge),

Karlovy Vary Region The Karlovy Vary Region or Carlsbad Region ( cs, Karlovarský kraj, German: ''Karlsbader Region'') is an administrative unit ( cs, kraj) of the Czech Republic, located in the westernmost part of its historical region of Bohemia. It is named after ...

Bohemia Bohemia ( ; cs, Čechy ; ; hsb, Čěska; szl, Czechy) is the westernmost and largest historical region of the Czech Republic. Bohemia can also refer to a wider area consisting of the historical Lands of the Bohemian Crown ruled by the Bohem ...

in what is now the

Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...

. It was named in 1845 for

Austrian Austrian may refer to: * Austrians, someone from Austria or of Austrian descent ** Someone who is considered an Austrian citizen, see Austrian nationality law * Austrian German dialect * Something associated with the country Austria, for example: ...

mineralogist Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proce ...

Ignaz von Born Ignaz Edler von Born, also known as Ignatius von Born ( hu, Born Ignác, ro, Ignațiu von Born, cs, Ignác Born) (26 December 1742 in Alba Iulia, Grand Principality of Transylvania, Habsburg monarchy – 24 July 1791 in Vienna), was a miner ...

(born as Born Ignác into a Hungarian family) (1742–1791).

References

Bibliography

* Palache, C., H. Berman, and C. Frondel (1944) ''Dana’s system of mineralogy'', (7th edition), v. I, 195–197.
Manning, P.G. (1966) ''A study of the bonding Properties of Sulphur in Bornite,'' The Canadian Mineralogist, 9, 85-94
{{ores Copper ores Iron minerals Sulfide minerals Orthorhombic minerals Minerals in space group 61