Coupled Substitution
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Coupled Substitution
Coupled substitution is the geological process by which two Chemical element, elements simultaneous substitute into a crystal in order to maintain overall electrical neutrality and keep the charge constant. In forming a solid solution series, Ionic radius, ionic size is more important than Cationic, ionic charge, as this can be compensated for elsewhere in the structure. Ionic size To make a geometrically stable structure in a mineral, atoms must fit together in terms of both their size and charge. The atoms have to fit together so that their electron shells can interact with one another and they also have to produce a neutral molecule. For these reasons the sizes and electron shell structure of atoms determine what element combinations are possible and the geometrical form that various minerals take. Because electrons are donated and received, it is the ionic radius of the element that controls the size and determines how atoms fit together in minerals. Examples * Coupled sub ...
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Feldspar Series
Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspars and the ''alkali'' (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight. Feldspars crystalize from magma as both Intrusive rock, intrusive and extrusive igneous rocks and are also present in many types of metamorphic rock. Rock formed almost entirely of calcic plagioclase feldspar is known as anorthosite. Feldspars are also found in many types of sedimentary rocks. Compositions The feldspar group of minerals consists of Silicate minerals, tectosilicates, silicate minerals in which silicon ions are linked by shared oxygen ions to form a three-dimensional network. Compositions of major elements in common feldspars can be expressed in terms of three Endmember ( ...
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Arsenic
Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, but only the gray form, which has a metallic appearance, is important to industry. The primary use of arsenic is in alloys of lead (for example, in car batteries and ammunition). Arsenic is a common n-type dopant in semiconductor electronic devices. It is also a component of the III-V compound semiconductor gallium arsenide. Arsenic and its compounds, especially the trioxide, are used in the production of pesticides, treated wood products, herbicides, and insecticides. These applications are declining with the increasing recognition of the toxicity of arsenic and its compounds. A few species of bacteria are able to use arsenic compounds as respiratory metabolites. Trace quantities of arsenic are an essential dietary element in rats, ham ...
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Bityite
Bityite is considered a rare mineral, and it is an endmember to the margarite mica sub-group found within the phyllosilicate group. The mineral was first described by Antoine François Alfred Lacroix in 1908, and later its chemical composition was concluded by Professor Hugo Strunz.Strunz, H. (1956) Bityit, ein berylliumglimmer. Zeitschrift für Kristallographie, 107, 325-330. Bityite has a close association with beryl, and it generally crystallizes in pseudomorphs after it, or in cavities associated with reformed beryl crystals.Lahti, S. I. and Saikkonen, R. (1985) Bityite 2M1 from Eräjärvi compared with related Li-Be brittle micas. Bulletin of the Geological Society of Finland, 57, 207-215. The mineral is considered a late-stage constituent in lithium bearing pegmatites,Lin, J-C. and Guggenheim, S. (1983) The crystal structure of a Li,Be-rich brittle mica: a dioctaheral-trioctahedral intermediate. American Mineralogist, 68, 130-142. and has only been encountered in a few lo ...
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Hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks. The general formula is . Physical properties Hornblende has a hardness of 5–6, a specific gravity of 3.0 to 3.6, and is typically an opaque green, dark green, brown, or black color. It tends to form slender prismatic to bladed crystals, diamond-shaped in cross-section, or is present as irregular grains or fibrous masses. Its planes of cleavage intersect at 56° and 124° angles. Hornblende is most often confused with the pyroxene series and biotite mica, which are also dark minerals found in granite and charnockite. Pyroxenes differ in their cleavage planes, which intersect at 87° and 93°. Hornblende is an inosilicate (chain silicate) mineral, built around double chains of silica tetrahedra. These chains extend the length of t ...
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Edenite
Edenite is a double chain silicate mineral of the amphibole group with the general chemical composition NaCa2Mg5(Si7Al)O22(OH)2. Edenite is named for the locality of Edenville, Orange County, New York, where it was first described. Occurrence Edenite has been found primarily in metamorphic rocks, occurring in pods of other magnesium rich minerals within a marble formation or with garnet rich lherzolites from deep within the Earth's crust. Thus, finding edenite in the field can indicate high temperature regional metamorphism of the surrounding rocks. Uses and importance While edenite is not important for commercial or industrial applications, it is often studied because of its unique chemical substitution properties. Results from research performed on amphiboles have shown that edenite is particularly suited for fitting chloride anions into its chemical framework. This makes edenite a good candidate for use in chlorine isotope fractionation in amphibole-bearing rocks. Many s ...
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