Hornblende is a complex

inosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...

series of

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...

s. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark

amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is A ...

. Hornblende minerals are common in

igneous Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or ...

and

metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...

s. The general formula is .

Physical properties

Hornblende has a

hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...

of 5–6, a

specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water (molecule), wa ...

of 3.0 to 3.6, and is typically an opaque green, dark green, brown, or black color. It tends to form slender prismatic to bladed crystals, diamond-shaped in cross-section, or is present as irregular grains or fibrous masses. Its planes of cleavage intersect at 56° and 124° angles. Hornblende is most often confused with the

pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe II) ...

series and biotite mica, which are also dark minerals found in

granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...

and

charnockite Charnockite () is any orthopyroxene-bearing quartz-feldspar rock formed at high temperature and pressure, commonly found in granulite facies metamorphic regions, ''sensu stricto'' as an endmember of the charnockite series. Charnockite series Th ...

. Pyroxenes differ in their cleavage planes, which intersect at 87° and 93°. Hornblende is an inosilicate (chain silicate) mineral, built around double chains of silica tetrahedra. These chains extend the length of the crystal and are bonded to their neighbors by additional metal ions to form the complete crystal structure.

Compositional variances

Hornblende is part of the calcium-amphibole group of amphibole minerals. It is highly variable in composition, and includes at least five solid solution series: * Magnesiohornblende-ferrohornblende, *

Tschermakite The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the therm ...

-ferrotschermakite, * Edenite-ferroedenite, *

Pargasite Pargasite is a complex inosilicate mineral of the amphibole group with formula NaCa2(Mg4Al)(Si6Al2)O22(OH)2. It was first described for an occurrence in Pargas, Finland in 1814 and named for the locality. It occurs in high temperature regional ...

-ferropargasite, * Magnesiohastingstite- hastingsite, In addition,

titanium Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...

, or

chromium Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardne ...

can substitute for some of the cations and oxygen,

fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reacti ...

, or

chlorine Chlorine is a chemical element with the Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate betwee ...

for some of the

hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. I ...

(OH). The different chemical types are almost impossible to distinguish even by optical or X-ray methods, and detailed chemical analysis using an electron microprobe is required. There is a solid solution series between hornblende and the closely related amphibole minerals,

tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and fe ...

actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite is ...

, at elevated temperature. A

miscibility gap A miscibility gap is a region in a phase diagram for a mixture of components where the mixture exists as two or more phases – any region of composition of mixtures where the constituents are not completely miscible. The IUPAC Gold Book defines ...

exists at lower temperatures, and, as a result, hornblende often contains exsolution lamellae of

grunerite Grunerite is a mineral of the amphibole group of minerals with formula Fe7 Si8 O22( OH)2. It is the iron endmember of the grunerite-cummingtonite series. It forms as fibrous, columnar or massive aggregates of crystals. The crystals are monoclini ...

Occurrence

Hornblende is a common constituent of many

and

metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...

such as

syenite Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations (< 5%). Some syenites contain larger proport ...

diorite Diorite ( ) is an intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is intermediate in composition between low-silic ...

gabbro Gabbro () is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is che ...

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predomi ...

gneiss Gneiss ( ) is a common and widely distributed type of metamorphic rock. It is formed by high-temperature and high-pressure metamorphic processes acting on formations composed of igneous or sedimentary rocks. Gneiss forms at higher temperatures an ...

, and

schist Schist ( ) is a medium-grained metamorphic rock showing pronounced schistosity. This means that the rock is composed of mineral grains easily seen with a low-power hand lens, oriented in such a way that the rock is easily split into thin flakes o ...

. It crystallizes in preference to pyroxene minerals from cooler magma that is richer in silica and water. It is the principal mineral of

amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky ...

s, which form during medium- to high-grade

metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...

mafic A mafic mineral or rock is a silicate mineral or igneous rock rich in magnesium and iron. Most mafic minerals are dark in color, and common rock-forming mafic minerals include olivine, pyroxene, amphibole, and biotite. Common mafic rocks include ...

to intermediate igneous rock (igneous rocks with relative low silica content) in the presence of pore water. Much of the pore water comes from the breakdown of

mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...

s or other hydrous minerals. However, hornblende itself breaks down at very high temperatures. Hornblende alters easily to chlorite,

biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron-endmember annite, and the magnesium-endmember phlogopite; more alumino ...

, or other mafic minerals. A rare variety of hornblende contains less than 5% of

iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of whic ...

, is gray to white in color, and is named edenite from its locality in Edenville,

Orange County, New York Orange County is a county located in the U.S. state of New York. As of the 2020 census, the population was 401,310. The county seat is Goshen. This county was first created in 1683 and reorganized with its present boundaries in 1798. Orange ...

. ''Oxyhornblende'' is a variety in which most of the iron has been oxidized to the

ferric In chemistry, iron(III) refers to the element iron in its +3 oxidation state. In ionic compounds (salts), such an atom may occur as a separate cation (positive ion) denoted by Fe3+. The adjective ferric or the prefix ferri- is often used to sp ...

state, . Charge balance is preserved by the substitution of oxygen ions for hydroxide. Oxyhornblende is also typically enriched in titanium. It is found almost exclusively in volcanic rock and is sometimes called ''basaltic hornblende''.

Etymology

The word ''hornblende'' is derived from

German German(s) may refer to: * Germany (of or related to) ** Germania (historical use) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizens of Germany, see also German nationality law **Ge ...

('horn') and ('deceive'), in allusion to its similar appearance to metal-bearing ore minerals.

References

{{Reflist Inosilicates Calcium minerals Iron minerals Magnesium minerals Aluminium minerals Monoclinic minerals Minerals in space group 12 de:Amphibolgruppe#Calcium-Amphibole

Physical properties

Compositional variances

Occurrence

Etymology

See also

References