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Alloxane
Alloxan, sometimes referred to as ''alloxan hydrate'', is the name of the organic compound with the formula OC(N(H)CO)2C(OH)2. It is classified as a derivative of pyrimidine. The anhydrous derivative OC(N(H)CO)2CO is also known, as well as a dimeric derivative. These are some of the earliest known organic compounds. They exhibit a variety of biological activities. History and literature The compound was discovered by Justus von Liebig and Friedrich Wöhler. It is one of the oldest named organic compounds. It was originally prepared in 1818 by Luigi Valentino Brugnatelli (1761-1818) and was named in 1838 by Wöhler and Liebig. The name "Alloxan" emerged from an amalgamation of the words "allantoin" and "Oxalsäure" (oxalic acid). The alloxan model of diabetes was first described in rabbits by Dunn, Sheehan and McLetchie in 1943. The name is derived from allantoin, a product of uric acid excreted by the fetus into the allantois, and oxaluric acid derived from oxalic acid and u ...
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Pyrimidine
Pyrimidine (; ) is an aromatic, heterocyclic, organic compound similar to pyridine (). One of the three diazines (six-membered heterocyclics with two nitrogen atoms in the ring), it has nitrogen atoms at positions 1 and 3 in the ring. The other diazines are pyrazine (nitrogen atoms at the 1 and 4 positions) and pyridazine (nitrogen atoms at the 1 and 2 positions). In nucleic acids, three types of nucleobases are pyrimidine derivatives: cytosine (C), thymine (T), and uracil (U). Occurrence and history The pyrimidine ring system has wide occurrence in nature as substituted and ring fused compounds and derivatives, including the nucleotides cytosine, thymine and uracil, thiamine (vitamin B1) and alloxan. It is also found in many synthetic compounds such as barbiturates and the HIV drug, zidovudine. Although pyrimidine derivatives such as alloxan were known in the early 19th century, a laboratory synthesis of a pyrimidine was not carried out until 1879, when Grimaux reported the ...
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Barbituric Acid
Barbituric acid or malonylurea or 6-hydroxyuracil is an organic compound based on a pyrimidine heterocyclic skeleton. It is an odorless powder soluble in water. Barbituric acid is the parent compound of barbiturate drugs, although barbituric acid itself is not pharmacologically active. The compound was first synthesised by Adolf von Baeyer. Naming It remains unclear why Baeyer chose to name the compound that he discovered "barbituric acid". In his textbook ''Organic Chemistry'', the American organic chemist Louis Frederick Fieser (1899–1977) initially speculated that the name stemmed from the German word ''Schlüsselbart'' (literally, the beard (''Bart Latin: ''barba'') of a key (''Schlüssel'')' that is, the bit of a key), because Baeyer had regarded barbituric acid as central (or "key") to understanding uric acid and its derivatives. However, Fieser subsequently decided that Baeyer had named the compound after a young lady whom he had met and who was called "Barbara"' hence t ...
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Merck Index
''The Merck Index'' is an encyclopedia of chemical substance, chemicals, pharmaceutical drug, drugs and biomolecule, biologicals with over 10,000 monographs, monograph on single substances or groups of related chemical compound, compounds published online by the Royal Society of Chemistry. History The first edition of the Merck's Index was published in 1889 by the German chemical company Merck Group, Emanuel Merck and was primarily used as a sales catalog for Merck's growing list of chemicals it sold. The American subsidiary was established two years later and continued to publish it. During World War I the US government seized Merck's US operations and made it a separate American "Merck" company that continued to publish the Merck Index. In 2012 the Merck Index was licensed to the Royal Society of Chemistry. An online version of The Merck Index, including historic records and new updates not in the print edition, is commonly available through research libraries. It also include ...
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Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ...
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Chromium Trioxide
Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. This compound is a dark-purple solid under anhydrous conditions, bright orange when wet and which dissolves in water concomitant with hydrolysis. Millions of kilograms are produced annually, mainly for electroplating. Chromium trioxide is a powerful oxidiser and a carcinogen. Production, structure, and basic reactions Chromium trioxide is generated by treating sodium dichromate with sulfuric acid: :H2SO4 + Na2Cr2O7 → 2 CrO3 + Na2SO4 + H2O Approximately 100,000 tonnes are produced annually by this or similar routes. The solid consists of chains of tetrahedrally coordinated chromium atoms that share vertices. Each chromium center therefore shares two oxygen centers with neighbors. Two oxygen atoms are not shared, giving an overall stoichiometry of 1:3. : The s ...
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Nitric Acid
Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as pigments in inks and dyes. Nitric acid is also commonly used as a strong oxidizing agen ...
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Chicken
The chicken (''Gallus gallus domesticus'') is a domesticated junglefowl species, with attributes of wild species such as the grey and the Ceylon junglefowl that are originally from Southeastern Asia. Rooster or cock is a term for an adult male bird, and a younger male may be called a cockerel. A male that has been castrated is a capon. An adult female bird is called a hen and a sexually immature female is called a pullet. Humans now keep chickens primarily as a source of food (consuming both their meat and eggs) and as pets. Traditionally they were also bred for cockfighting, which is still practiced in some places. Chickens are one of the most common and widespread domestic animals, with a total population of 23.7 billion , up from more than 19 billion in 2011. There are more chickens in the world than any other bird. There are numerous cultural references to chickens – in myth, folklore and religion, and in language and literature. Genetic studies have pointed to mult ...
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Turin
Turin ( , Piedmontese language, Piedmontese: ; it, Torino ) is a city and an important business and cultural centre in Northern Italy. It is the capital city of Piedmont and of the Metropolitan City of Turin, and was the first Italian capital from 1861 to 1865. The city is mainly on the western bank of the Po (river), Po River, below its Susa Valley, and is surrounded by the western Alps, Alpine arch and Superga Hill. The population of the city proper is 847,287 (31 January 2022) while the population of the urban area is estimated by Larger Urban Zones, Eurostat to be 1.7 million inhabitants. The Turin metropolitan area is estimated by the Organisation for Economic Co-operation and Development, OECD to have a population of 2.2 million. The city used to be a major European political centre. From 1563, it was the capital of the Duchy of Savoy, then of the Kingdom of Sardinia ruled by the House of Savoy, and the first capital of the Kingdom of Italy from 1861 to 1865. T ...
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Pythonidae
The Pythonidae, commonly known as pythons, are a family of nonvenomous snakes found in Africa, Asia, and Australia. Among its members are some of the largest snakes in the world. Ten genera and 42 species are currently recognized. Distribution and habitat Pythons are found in sub-Saharan Africa, Nepal, India, Bangladesh, Sri Lanka, Southeast Asia, southeastern Pakistan, southern China, the Philippines and Australia. In the United States, an introduced population of Burmese pythons, ''Python bivittatus'', has existed as an invasive species in the Everglades National Park since the late 1990s. Common names * Sinhala - පිඹුරා (''Pimbura'') *Telugu - కొండచిలువ (Kondachiluva) * Odia - ଅଜଗର (Ajagara) *Malayalam - പെരുമ്പാമ്പ് (perumpāmp) *Hindi - अजगर ('Ajgar') Conservation Many species have been hunted aggressively, which has greatly reduced the population of some, such as the Indian python, ''Python molu ...
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Primo Levi
Primo Michele Levi (; 31 July 1919 – 11 April 1987) was an Italian chemist, partisan, writer, and Jewish Holocaust survivor. He was the author of several books, collections of short stories, essays, poems and one novel. His best-known works include ''If This Is a Man'' (1947, published as ''Survival in Auschwitz'' in the United States), his account of the year he spent as a prisoner in the Auschwitz concentration camp in Nazi-occupied Poland; and '' The Periodic Table'' (1975), linked to qualities of the elements, which the Royal Institution named the best science book ever written. Levi died in 1987 from injuries sustained in a fall from a third-story apartment landing. His death was officially ruled a suicide, but some, after careful consideration, have suggested that the fall was accidental because he left no suicide note, there were no witnesses, and he was on medication that could have affected his blood pressure and caused him to fall accidentally. Biography Earl ...
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The Periodic Table (short Story Collection)
''The Periodic Table'' ( it, Il sistema periodico) is a 1975 short story collection by Primo Levi, named after the periodic table in chemistry. In 2006, the Royal Institution of Great Britain named it the best science book ever. Content The stories are autobiographical episodes based on the author's experiences as a Jewish-Italian doctoral-level chemist under the Fascist regime in Italy and afterwards. They include various themes that follow a chronological sequence: his ancestry, his study of chemistry and practising the profession in wartime Italy, a pair of imaginative tales he wrote at that time, and his subsequent experiences as an anti-Fascist partisan, his arrest and imprisonment, interrogation, and internment in the Fossoli di Carpi and Auschwitz camps, and postwar life as an industrial chemist. Each of the twenty-one stories in the book bears the name of a chemical element as its title and has a connection to the element in some way. Chapters #"Argon" – The aut ...
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Boa (genus)
''Boa'' is a genus of non-venomous Boinae, boas found in Mexico, the Caribbean, and Central America, Central and South America. Five species are currently recognized. Etymology The Online Etymology Dictionary says that the word comes from the "late 14c., "large snake," from Latin boa, type of large serpent mentioned in Pliny the Elder, Pliny's Naturalis Historia, "Natural History;" origin unknown (in medieval folk etymology the name was associated with Greek bous "ox")." Species Boa is a polytypic genus and so contains more than one species. The boa constrictor has been reported to grow to a maximum of 14 feet (4.3 m) in length.Mehrtens JM. 1987. Living Snakes of the World in Color. New York: Sterling Publishers. 480 pp. . Numerous subspecies are currently recognised. A now extinct species, the Marie-Galante boa (''Boa blanchardensis''), lived during the Pleistocene on Marie Galante in the Lesser Antilles. Distribution and habitat ''Boa'' species are found in northern Mex ...
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