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Afwillite
Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite. It was first described in 1925 for an occurrence in the Dutoitspan Mine, Kimberley, South Africa and was named for Alpheus Fuller Williams (1874–1953), a past official of the De Beers diamond company. Afwillite is typically found in veins of spurrite and it belongs to the nesosilicate sub-class. It is monoclinic, its space group is P2 and its point group is 2. Formation of afwillite It is suggested that afwillite forms in fractured veins of the mineral spurrite. Jennite, afwillite, oyelite and calcite are all minerals that form in layers ...
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Spurrite
Spurrite is a white, yellow or light blue mineral with monoclinic crystals. Its chemical formula is Ca5( Si O4)2 CO3. Spurrite is generally formed in contact metamorphism zones as mafic magmas are intruded into carbonate rocks.Smith, J.V. (1960) "The Crystal structure of Spurrite, Ca5(SiO4)2CO3". ''Acta. Cryst.'' 13, 454 Spurrite's space group is P 2/a. It is biaxial with a birefringence of 0.0390–0.0400, giving second order red interference colors when viewed under crossed polarizers in a petrographic microscope. The calcium is in six-fold coordination with the oxygen, the silicon is in a four-fold coordination with the oxygen and the carbon is in two-fold coordination. One unique characteristic of spurrite is that it actually abides by two twin laws. Polysynthetic twinning can occur along its (001) and another type of twinning can occur parallel to its optical axes. Discovery and occurrence Spurrite was first described in 1908 for an occurrence in the Terneras Mine, Ve ...
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Jennite
Jennite is a calcium silicate hydrate mineral of general chemical formula: Ca9Si6O18(OH)6·8H2O. Jennite occurs as an alteration mineral in metamorphosed limestone and skarn. It typically occurs as vein and open space fillings as a late mineral phase. It also occurs in hydrated cement paste. A first specimen of jennite found in 1966 at the Crestmore quarries (Crestmore, Riverside County, California, US) was analysed and identified as a new mineral by Carpenter in 1966 (Carpenter, 1966). They named it in honor of its discoverer: Clarence Marvin Jenni (1896–1973) director of the Geological Museum at the University of Missouri. In contrast to the first analysis made by Carpenter, jennite does not contain appreciable amount of sodium when the Crestmore specimen was reexamined (Gard, 1977). The structure of jennite is made of three distinct modules: ribbons of edge-sharing calcium octahedra, silicate chains of wollastonite-type running along the b axis, and additional calciu ...
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Thaumasite
Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca3 Si(O H)6( C O3)( SO4)·12 H2O, also sometimes more simply written as CaSiO3·CaCO3·CaSO4·15H2O. It occurs as colorless to white prismatic hexagonal crystals, typically as acicular radiating groups. It also occurs as fibrous masses. Its Mohs hardness is 3.5 and it has a specific gravity of 1.88 to 1.90. Optically it is uniaxial negative with indices of refraction of nω = 1.507 and nε = 1.468. It occurs as a hydrothermal alteration mineral in sulfide ore deposits and geothermal alteration of basalt and tuff. It occurs with zeolites, apophyllite, analcime, calcite, gypsum and pyrite. Thaumasite can also be formed in man-made concrete structures at the detriment of calcium silicate hydrates (C-S-H, with dashes denoting the non- stoichiometry of this hydrated cement phase acting as the "glue" in hardened cement paste) during cement alteration, especiall ...
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Gehlenite
Gehlenite, (Ca2Al lSiO7, is a sorosilicate, Al-rich endmember of the melilite complete solid solution series with akermanite.Deer et al., 1993 The type locality is in the Monzoni Mountains, Fassa Valley in Trentino in Italy, and is named after Adolf Ferdinand Gehlen (1775–1815) by A.J. Fuchs in 1815.Dana et al. 1997 Geological occurrence Gehlenite is found in carbonaceous chondrites from which it condensed as a refractory mineral in the hotter stages ( FU Ori) of the presolar nebula,Grossman L (1972) Condensation in the primitive solar nebula, Geochemica et Cosmochemica Acta, 36, 597-619 and was subsequently consumed in processes which created enstatite and other more abundant minerals making it a remnant mineral from the early solar nebula (along with corundum and spinel). Its occurrence in the early condensation phase of the solar nebula was predicted by Harry Lord in the 1950s, but studies of carbonaceous chondrites did not support this claim until the Allende meteorite ...
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Cleavage (crystal)
Cleavage, in mineralogy and materials science, is the tendency of crystalline materials to split along definite crystallographic structural planes. These planes of relative weakness are a result of the regular locations of atoms and ions in the crystal, which create smooth repeating surfaces that are visible both in the microscope and to the naked eye. If bonds in certain directions are weaker than others, the crystal will tend to split along the weakly bonded planes. These flat breaks are termed "cleavage."Hurlbut, Cornelius S.; Klein, Cornelis, 1985, '' Manual of Mineralogy'', 20th ed., Wiley, The classic example of cleavage is mica, which cleaves in a single direction along the basal pinacoid, making the layers seem like pages in a book. In fact, mineralogists often refer to "books of mica." Diamond and graphite provide examples of cleavage. Both are composed solely of a single element, carbon. But in diamond, each carbon atom is bonded to four others in a tetrahedral pa ...
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Hydrogen Bonds
In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. The most frequent donor and acceptor atoms are the second-row elements nitrogen (N), oxygen (O), and fluorine (F). Hydrogen bonds can be intermolecular (occurring between separate molecules) or intramolecular (occurring among parts of the same molecule). The energy of a hydrogen bond depends on the geometry, the environment, and the nature of the specific donor and acceptor atoms and can vary between 1 and 40 kcal/mol. This makes them somewhat stronger than a van der Waals interaction, and weaker than fully covalent ...
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Magma
Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles. Magma is produced by melting of the mantle or the crust in various tectonic settings, which on Earth include subduction zones, continental rift zones, mid-ocean ridges and hotspots. Mantle and crustal melts migrate upwards through the crust where they are thought to be stored in magma chambers or trans-crustal crystal-rich mush zones. During magma's storage in the crust, its composition may be modified by fractional crystallization, contamination with crustal melts, magma mixing, and degassing. Following its ascent through the crust, magma may feed a volcano and be extruded as lava, or it may solidify underground to form an intrusion, such as a ...
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De Beers
De Beers Group is an international corporation that specializes in diamond mining, diamond exploitation, diamond retail, diamond trading and industrial diamond manufacturing sectors. The company is active in open-pit, large-scale alluvial and coastal mining. It operates in 35 countries and mining takes place in Botswana, Namibia, South Africa, Canada and Australia. From its inception in 1888 until the start of the 21st century, De Beers controlled 80% to 85% of rough diamond distribution and was considered a monopoly. Competition has since dismantled the complete monopoly; the De Beers Group now sells approximately 29.5% of the world's rough diamond production by value through its global sightholder and auction sales businesses. The company was founded in 1888 by British businessman Cecil Rhodes, who was financed by the South African diamond magnate Alfred Beit and the London-based N M Rothschild & Sons bank. In 1926, Ernest Oppenheimer, a German immigrant to Britain and later ...
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Kimberley, South Africa
Kimberley is the capital and largest city of the Northern Cape province of South Africa. It is located approximately 110 km east of the confluence of the Vaal and Orange Rivers. The city has considerable historical significance due to its diamond mining past and the siege during the Second Anglo-Boer war. British businessmen Cecil Rhodes and Barney Barnato made their fortunes in Kimberley, and Rhodes established the De Beers diamond company in the early days of the mining town. On 2 September 1882, Kimberley was the first city in the Southern Hemisphere and the second in the world after Philadelphia, Pennsylvania in the United States to integrate electric street lights into its infrastructure. The first stock exchange in Africa was built in Kimberley, as early as 1881. History Discovery of diamonds In 1866, Erasmus Jacobs found a small brilliant pebble on the banks of the Orange River, on the farm ''De Kalk'' leased from local Griquas, near Hopetown, which was his f ...
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Calcite
Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on the Mohs scale of mineral hardness, based on Scratch hardness, scratch hardness comparison. Large calcite crystals are used in optical equipment, and limestone composed mostly of calcite has numerous uses. Other polymorphs of calcium carbonate are the minerals aragonite and vaterite. Aragonite will change to calcite over timescales of days or less at temperatures exceeding 300 °C, and vaterite is even less stable. Etymology Calcite is derived from the German ''Calcit'', a term from the 19th century that came from the Latin word for Lime (material), lime, ''calx'' (genitive calcis) with the suffix "-ite" used to name minerals. It is thus etymologically related to chalk. When applied by archaeology, archaeologists and stone trade pr ...
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Brucite
Brucite is the mineral form of magnesium hydroxide, with the chemical formula Mg( OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal vein mineral in metamorphosed limestones and chlorite schists; and formed during serpentinization of dunites. Brucite is often found in association with serpentine, calcite, aragonite, dolomite, magnesite, hydromagnesite, artinite, talc and chrysotile. It adopts a layered CdI2-like structure with hydrogen-bonds between the layers. Discovery Brucite was first described in 1824 by François Sulpice Beudant and named for the discoverer, American mineralogist, Archibald Bruce (1777–1818). A fibrous variety of brucite is called nemalite. It occurs in fibers or laths, usually elongated along 010 but sometimes 120 crystalline directions. Occurrence A notable location in the U.S. is Wood's Chrome Mine, Cedar Hill Quarry, Lancaster County, Pennsylvania. Yellow, white and blue Brucite with a botryoidal habit ...
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