Jennite is a

calcium silicate hydrate Calcium silicate hydrate (or C-S-H) is the main product of the hydration of Portland cement and is primarily responsible for the strength in cement based materials (e.g. concrete). Preparation When water is added to cement, each of the compounds ...

mineral of general chemical formula: Ca₉Si₆O₁₈(OH)₆·8H₂O. Jennite occurs as an alteration mineral in

metamorphosed Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causin ...

limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...

and

skarn Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals ...

. It typically occurs as

vein Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...

and open space fillings as a late mineral phase. It also occurs in hydrated

cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mix ...

paste. A first specimen of jennite found in 1966 at the Crestmore quarries (Crestmore,

Riverside County, California Riverside County is a County (United States), county located in the southern California, southern portion of the U.S. state of California. As of the 2020 United States Census, 2020 census, the population was 2,418,185, making it the fourth-most ...

, US) was analysed and identified as a new mineral by Carpenter in 1966 (Carpenter, 1966). They named it in honor of its discoverer:

Clarence Marvin Jenni Clarence may refer to: Places Australia * Clarence County, New South Wales, a Cadastral division * Clarence, New South Wales, a place near Lithgow * Clarence River (New South Wales) * Clarence Strait (Northern Territory) * City of Clarence, a loc ...

(1896–1973) director of the Geological Museum at the

University of Missouri The University of Missouri (Mizzou, MU, or Missouri) is a public university, public Land-grant university, land-grant research university in Columbia, Missouri. It is Missouri's largest university and the flagship of the four-campus Universit ...

. In contrast to the first analysis made by Carpenter, jennite does not contain appreciable amount of sodium when the Crestmore specimen was reexamined (Gard, 1977). The structure of jennite is made of three distinct modules: ribbons of edge-sharing

calcium Calcium is a chemical element with the symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to ...

octahedra In geometry, an octahedron (plural: octahedra, octahedrons) is a polyhedron with eight faces. The term is most commonly used to refer to the regular octahedron, a Platonic solid composed of eight equilateral triangles, four of which meet a ...

, silicate chains of

wollastonite Wollastonite is a calcium inosilicate mineral ( Ca Si O3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature ...

-type running along the b axis, and additional calcium octahedra on

inversion center In geometry, a point reflection (point inversion, central inversion, or inversion through a point) is a type of isometry of Euclidean space. An object that is invariant under a point reflection is said to possess point symmetry; if it is invari ...

s. The

hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy ...

groups are bonded to three calcium cations while no SiOH groups are observed (Bonaccorsi, 2004). Jennite transforms to metajennite at by losing four water molecules (Gard, 1977).

Cement chemistry

Jennite is often used in thermodynamical calculations to represent the pole of the less evolved calcium silicate hydrate (C-S-H). The value of its atomic Ca/Si or molecular CaO/SiO₂ (C/S) ratio is 1.50 (9/6), as directly calculated from its elementary composition formula.

Tobermorite Tobermorite is a calcium silicate hydrate mineral with chemical formula: Ca5Si6O16(OH)2·4H2O or Ca5Si6(O,OH)18·5H2O. Two structural varieties are distinguished: tobermorite-11 Å and tobermorite-14 Å. Tobermorite occurs in hydrated cemen ...

represents the more evolved pole with a C/S ratio of 0.83 (5/6).

References

;Bibliography * * * *

Cement chemistry

See also

References

Further reading