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X-ray Magnetic Circular Dichroism
X-ray magnetic circular dichroism (XMCD) is a difference spectrum of two X-ray absorption spectra (XAS) taken in a magnetic field, one taken with left circularly polarized light, and one with right circularly polarized light. By closely analyzing the difference in the XMCD spectrum, information can be obtained on the magnetic properties of the atom, such as its spin and orbital magnetic moment. Using XMCD magnetic moments below 10−5 µB can be observed. In the case of transition metals such as iron, cobalt, and nickel, the absorption spectra for XMCD are usually measured at the L-edge. This corresponds to the process in the iron case: with iron, a 2p electron is excited to a 3d state by an X-ray of about 700 eV. Because the 3d electron states are the origin of the magnetic properties of the elements, the spectra contain information on the magnetic properties. In rare-earth elements usually, the M4,5-edges are measured, corresponding to electron excitations from a 3d sta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments ( cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transition Metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can use d orbitals as valence orbitals to form chemical bonds. The lanthanide and actinide elements (the f-block) are called inner transition metals and are sometimes considered to be transition metals as well. Since they are metals, they are lustrous and have good electrical and thermal conductivity. Most (with the exception of group 11 and group 12) are hard and strong, and have high melting and boiling temperatures. They form compounds in any of two or more different oxidation states and bind to a variety of ligands to form coordination complexes that are often coloured. They form many useful alloys and are often employed as catalysts in elemental form or in compounds such as coordination complexes and oxides. Most are strongly param ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
EMCD
Electron magnetic circular dichroism (EMCD) (also known as electron energy-loss magnetic chiral dichroism) is the EELS equivalent of XMCD. The effect was first proposed in 2003 and experimentally confirmed in 2006 by the group of Prof. Peter Schattschneider at the Vienna University of Technology. Similarly to XMCD, EMCD is a difference spectrum of two EELS spectra taken in a magnetic field with opposite helicities. Under appropriate scattering conditions virtual photons with specific circular polarizations can be absorbed, giving rise to spectral differences. The largest difference is expected between the case where one virtual photon with left circular polarization and one with right circular polarization are absorbed. By closely analyzing the difference in the EMCD spectrum, information can be obtained on the magnetic properties of the atom, such as its spin and orbital magnetic moment. In the case of transition metals such as iron, cobalt, and nickel, the absorption spectra f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Faraday Effect
The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation. Formally, it is a special case of gyroelectromagnetism obtained when the dielectric permittivity tensor is diagonal. This effect occurs in most optically transparent dielectric materials (including liquids) under the influence of magnetic fields. Discovered by Michael Faraday in 1845, the Faraday effect was the first experimental evidence that light and electromagnetism are related. The theoretical basis of electromagnetic radiation (which includes visible light) was completed by James Clerk Maxwell in the 1860s. Maxwell's equations were rewritten in their current form in the 1870s by Oliver Heaviside. The Faraday effect is caused by left and right circularly polarized waves pr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Magnetic Circular Dichroism
Magnetic circular dichroism (MCD) is the differential absorption of left and right circularly polarized (LCP and RCP) light, induced in a sample by a strong magnetic field oriented parallel to the direction of light propagation. MCD measurements can detect transitions which are too weak to be seen in conventional optical absorption spectra, and it can be used to distinguish between overlapping transitions. Paramagnetic systems are common analytes, as their near-degenerate magnetic sublevels provide strong MCD intensity that varies with both field strength and sample temperature. The MCD signal also provides insight into the symmetry of the electronic levels of the studied systems, such as metal ion sites. History It was first shown by Faraday that optical activity (the Faraday effect) could be induced in matter by a longitudinal magnetic field (a field in the direction of light propagation). The development of MCD really began in the 1930s when a quantum mechanical theory of MOR ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rare-earth Element
The rare-earth elements (REE), also called the rare-earth metals or (in context) rare-earth oxides or sometimes the lanthanides (yttrium and scandium are usually included as rare earths), are a set of 17 nearly-indistinguishable lustrous silvery-white soft heavy metals. Compounds containing rare earths have diverse applications in electrical and electronic components, lasers, glass, magnetic materials, and industrial processes. Scandium and yttrium are considered rare-earth elements because they tend to occur in the same ore deposits as the lanthanides and exhibit similar chemical properties, but have different electronic and magnetic properties. These metals tarnish slowly in air at room temperature and react slowly with cold water to form hydroxides, liberating hydrogen. They react with steam to form oxides, and at elevated temperature (400°C) ignite spontaneously. These elements and their compounds have no biological function other than in several specialized enzymes, s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electronvolt
In physics, an electronvolt (symbol eV, also written electron-volt and electron volt) is the measure of an amount of kinetic energy In physics, the kinetic energy of an object is the energy that it possesses due to its motion. It is defined as the work needed to accelerate a body of a given mass from rest to its stated velocity. Having gained this energy during its acc ... gained by a single electron accelerating from rest through an Voltage, electric potential difference of one volt in vacuum. When used as a Units of energy, unit of energy, the numerical value of 1 eV in joules (symbol J) is equivalent to the numerical value of the Electric charge, charge of an electron in coulombs (symbol C). Under the 2019 redefinition of the SI base units, this sets 1 eV equal to the exact value Historically, the electronvolt was devised as a standard unit of measure through its usefulness in Particle accelerator#Electrostatic particle accelerators, electrostatic particle accel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electron Configuration
In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. For example, the electron configuration of the neon atom is , meaning that the 1s, 2s and 2p subshells are occupied by 2, 2 and 6 electrons respectively. Electronic configurations describe each electron as moving independently in an orbital, in an average field created by all other orbitals. Mathematically, configurations are described by Slater determinants or configuration state functions. According to the laws of quantum mechanics, for systems with only one electron, a level of energy is associated with each electron configuration and in certain conditions, electrons are able to move from one configuration to another by the emission or absorption of a quantum of energy, in the form of a photon. Knowledge of the electron configuration of different atoms is useful in understanding the structu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
X-ray Notation
X-ray notation is a method of labeling atomic orbitals that grew out of X-ray science. Also known as IUPAC notation, it was adopted by the International Union of Pure and Applied Chemistry in 1991 as a simplification of the older Siegbahn notation. In X-ray notation, every principal quantum number is given a letter associated with it. In many areas of physics and chemistry, atomic orbitals are described with spectroscopic notation (1s, 2s, 2p, 3s, 3p, etc.), but the more traditional X-ray notation is still used with most X-ray spectroscopy techniques including AES and XPS. Conversion Uses *X-ray sources are classified by the type of material and orbital used to generate them. For example, CuKα X-rays are emitted from the K orbital of copper. *X-ray absorption is reported as which orbital absorbed the x-ray photon. In EXAFS and XMCD the L-edge or the L absorption edge is the point where the L orbital begins to absorb x-rays. *Auger peaks are identified with three orbital defini ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified as an e ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in front of oxygen (32.1% and 30.1%, respectively), forming much of Earth's outer and inner core. It is the fourth most common element in the Earth's crust. In its metallic state, iron is rare in the Earth's crust, limited mainly to deposition by meteorites. Iron ores, by contrast, are among the most abundant in the Earth's crust, although extracting usable metal from them requires kilns or furnaces capable of reaching or higher, about higher than that required to smelt copper. Humans started to master that process in Eurasia during the 2nd millennium BCE and the use of iron tools and weapons began to displace copper alloys, in some regions, only around 1200 BCE. That event is considered the transition from the Bronze Age to the Iron A ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
