White Tin
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White Tin
White tin is refined, metallic tin. White tin It contrasts with black tin, which is unrefined tin ore ( cassiterite) as extracted from the ground. The term "white tin" was historically associated with tin mining in Devon and Cornwall where it was smelted from black tin in blowing houses. White tin may also refer specifically to β-tin, the metallic allotrope of the pure element, as opposed to the nonmetallic allotrope α-tin (also known as gray tin) which occurs at temperatures below , a transformation known as tin pest Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, t ...). White tin has tetragonal unit cell. References * * * * Tin mining Mining in Cornwall {{mining-stub ...
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Refining (metallurgy)
In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining, the final material is usually identical chemically to the original one, only it is purer. The processes used are of many types, including pyrometallurgy, pyrometallurgical and hydrometallurgy, hydrometallurgical techniques. Lead Cupellation One ancient process for extracting the silver from lead was cupellation. Lead was melted in a bone ash 'test' or 'cupel' and air blown across the surface. This oxidised the lead to litharge, and also oxidised other base metals present, the silver (and gold if present) remaining unoxidised. In the 18th century, the process was carried on using a kind of reverberatory furnace, but differing from the usual kind in that air was blown over the surface of the molten lead from bellows or (in the 19th century) blowing cyl ...
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Black Tin
Black tin is the raw ore of tin, usually cassiterite, as sold by a tin mine to a smelting company. After mining, the ore must be concentrated by several processes to reduce the amount of gangue it contains before it can be sold. It contrasts with white tin, which is the refined, metallic tin produced after smelting. The term "black tin" was historically associated with tin mining in Devon and Cornwall Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic .... References * * * * Tin mining Mining in Cornwall {{Mining-stub ...
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Cassiterite
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today. Occurrence Most sources of cassiterite today are found in alluvial or placer deposits containing the weathering-resistant grains. The best sources of primary cassiterite are found in the tin mines of Bolivia, where it is found in crystallised hydrothermal veins. Rwanda has a nascent cassiterite mining industry. Fighting over cassiterite deposits (particularly in Walikale) is a major cause of the conflict waged in eastern parts of the Democratic Republic of the Congo. This has led to cassiterite being considered a conflict mineral. Cassiterite is a widespread minor constituent of igneous rocks. The Bolivian veins and the 4500 year old workings of Cornwall and Devon, England, are concentrated in ...
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Devon
Devon ( , historically known as Devonshire , ) is a ceremonial and non-metropolitan county in South West England. The most populous settlement in Devon is the city of Plymouth, followed by Devon's county town, the city of Exeter. Devon is a coastal county with cliffs and sandy beaches. Home to the largest open space in southern England, Dartmoor (), the county is predominately rural and has a relatively low population density for an English county. The county is bordered by Somerset to the north east, Dorset to the east, and Cornwall to the west. The county is split into the non-metropolitan districts of East Devon, Mid Devon, North Devon, South Hams, Teignbridge, Torridge, West Devon, Exeter, and the unitary authority areas of Plymouth, and Torbay. Combined as a ceremonial county, Devon's area is and its population is about 1.2 million. Devon derives its name from Dumnonia (the shift from ''m'' to ''v'' is a typical Celtic consonant shift). During the Briti ...
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Cornwall
Cornwall (; kw, Kernow ) is a historic county and ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people. Cornwall is bordered to the north and west by the Atlantic Ocean, to the south by the English Channel, and to the east by the county of Devon, with the River Tamar forming the border between them. Cornwall forms the westernmost part of the South West Peninsula of the island of Great Britain. The southwesternmost point is Land's End and the southernmost Lizard Point. Cornwall has a population of and an area of . The county has been administered since 2009 by the unitary authority, Cornwall Council. The ceremonial county of Cornwall also includes the Isles of Scilly, which are administered separately. The administrative centre of Cornwall is Truro, its only city. Cornwall was formerly a Brythonic kingdom and subsequently a royal duchy. It is the cultural and ethnic origin of the Cornish dias ...
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Blowing House
A blowing house or blowing mill was a building used for smelting tin in Cornwall and on Dartmoor in Devon, in South West England. Blowing houses contained a furnace and a pair of bellows that were powered by an adjacent water wheel, and they were in use from the early 14th century until they were gradually replaced by reverberatory furnaces in the 18th century. The remains of over 40 blowing houses have been identified on Dartmoor. History The blowing house method of smelting tin was probably introduced early in the 14th century to replace the earliest method of smelting which had to be done in two stages – a first smelting probably took place near to the tinworks and the roughly smelted metal was taken to a stannary town to be smelted again to produce the final refined product. Each of these smeltings was taxed separately until 1303 when they were replaced by a single tax on the finished product. It is likely that this tax change was due to the improved smelting process provid ...
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Beta-tin
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, the so-called "tin cry" can be heard as a result of twinning in tin crystals; this trait is shared by indium, cadmium, zinc, and mercury in the solid state. Pure tin after solidifying presents a mirror-like appearance similar to most metals. In most tin alloys (such as pewter) the metal solidifies with a dull gray color. Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth and has, with 10 stable isotopes, the largest nu ...
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Allotrope
Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: the atoms of the element are bonded together in a different manner. For example, the allotropes of carbon include diamond (the carbon atoms are bonded together to form a cubic lattice of tetrahedra), graphite (the carbon atoms are bonded together in sheets of a hexagonal lattice), graphene (single sheets of graphite), and fullerenes (the carbon atoms are bonded together in spherical, tubular, or ellipsoidal formations). The term ''allotropy'' is used for elements only, not for compounds. The more general term, used for any compound, is polymorphism, although its use is usually restricted to solid materials such as crystals. Allotropy refers only to different forms of an element within the same physical phase (the state of matter, such as ...
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Alpha-tin
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, the so-called "tin cry" can be heard as a result of twinning in tin crystals; this trait is shared by indium, cadmium, zinc, and mercury in the solid state. Pure tin after solidifying presents a mirror-like appearance similar to most metals. In most tin alloys (such as pewter) the metal solidifies with a dull gray color. Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth and has, with 10 stable isotopes, the larges ...
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Tin Pest
Tin is a chemical element with the symbol Sn (from la, stannum) and atomic number 50. Tin is a silvery-coloured metal. Tin is soft enough to be cut with little force and a bar of tin can be bent by hand with little effort. When bent, the so-called "tin cry" can be heard as a result of twinning in tin crystals; this trait is shared by indium, cadmium, zinc, and mercury in the solid state. Pure tin after solidifying presents a mirror-like appearance similar to most metals. In most tin alloys (such as pewter) the metal solidifies with a dull gray color. Tin is a post-transition metal in group 14 of the periodic table of elements. It is obtained chiefly from the mineral cassiterite, which contains stannic oxide, . Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element on Earth and has, with 10 stable isotopes, the largest n ...
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Tetragonal Crystal System
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square base (''a'' by ''a'') and height (''c'', which is different from ''a''). Bravais lattices There are two tetragonal Bravais lattices: the primitive tetragonal and the body-centered tetragonal. The base-centered tetragonal lattice is equivalent to the primitive tetragonal lattice with a smaller unit cell, while the face-centered tetragonal lattice is equivalent to the body-centered tetragonal lattice with a smaller unit cell. Crystal classes The point groups that fall under this crystal system are listed below, followed by their representations in international notation, Schoenflies notation, orbifold notation, Coxeter notation and mineral examples.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., pp. ...
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Tin Mining
Tin mining began early in the Bronze Age, as bronze is a copper-tin alloy. Tin is a relatively rare element in the Earth's crust, with approximately 2 ppm (parts per million), compared to iron with 50,000 ppm. History Tin extraction and use can be dated to the beginnings of the Bronze Age around 3000 BC, when it was observed that copper objects formed of polymetallic ores with different metal contents had different physical properties. The earliest bronze objects had tin or arsenic content of less than 2% and are therefore believed to be the result of unintentional alloying due to trace metal content in the copper ore It was soon discovered that the addition of tin or arsenic to copper increased its hardness and made casting much easier, which revolutionized metal working techniques and brought humanity from the Copper Age or Chalcolithic to the Bronze Age around 3000 BC. Early tin exploitation appears to have been centered on placer deposits of cassiterite. The first evidence ...
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