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Tetragonal Crystal System
In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the cube becomes a rectangular prism with a square base (''a'' by ''a'') and height (''c'', which is different from ''a''). Bravais lattices There are two tetragonal Bravais lattices: the primitive tetragonal and the body-centered tetragonal. The base-centered tetragonal lattice is equivalent to the primitive tetragonal lattice with a smaller unit cell, while the face-centered tetragonal lattice is equivalent to the body-centered tetragonal lattice with a smaller unit cell. Crystal classes The point groups that fall under this crystal system are listed below, followed by their representations in international notation, Schoenflies notation, orbifold notation, Coxeter notation and mineral examples.Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., pp. ...
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Orbifold
In the mathematical disciplines of topology and geometry, an orbifold (for "orbit-manifold") is a generalization of a manifold. Roughly speaking, an orbifold is a topological space which is locally a finite group quotient of a Euclidean space. Definitions of orbifold have been given several times: by Ichirô Satake in the context of automorphic forms in the 1950s under the name ''V-manifold''; by William Thurston in the context of the geometry of 3-manifolds in the 1970s when he coined the name ''orbifold'', after a vote by his students; and by André Haefliger in the 1980s in the context of Mikhail Gromov's programme on CAT(k) spaces under the name ''orbihedron''. Historically, orbifolds arose first as surfaces with singular points long before they were formally defined. One of the first classical examples arose in the theory of modular forms with the action of the modular group \mathrm(2,\Z) on the upper half-plane: a version of the Riemann–Roch theorem holds after the ...
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Diaboleite
Diaboleite is a blue-colored mineral with formula Pb2CuCl2(OH)4. It was discovered in England in 1923 and named ''diaboleite'', from the Greek word διά and boleite, meaning "distinct from boleite". The mineral has since been found in a number of countries. Description Diaboleite is deep blue in color and pale blue in transmitted light. The mineral occurs as tabular crystals up to in size, as subparallel aggregates, or it has massive habit. Vicinal forms of the tabular crystals have a square or octagonal outline and rarely exhibit pyramidal hemihedralism. Formation Diaboleite occurs in manganese oxide ores, as a secondary mineral in lead and copper oxide ores, and in seawater-exposed slag. Diaboleite has been found in association with atacamite, boleite, caledonite, cerussite, chloroxiphite, hydrocerussite, leadhillite, mendipite, paratacamite, phosgenite, and wherryite. A study in 1986 synthesized diaboleite crystals up to in size using two different methods. The study de ...
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Wardite
Wardite is a hydrous sodium aluminium phosphate hydroxide mineral with formula: Na Al3( P O4)2(O H)4·2( H2O). Wardite is of interest for its rare crystallography. It crystallizes in the tetragonal trapezohedral class and is one of only a few minerals in that class. Wardite forms vitreous green to bluish green to white to colorless crystals, masses, and fibrous encrustations. It has a Mohs hardness of 5 and a specific gravity of 2.81–2.87. Occurrence It occurs with variscite in phosphate nodules and occurs uncommonly in pegmatites and phosphate deposits through alteration of amblygonite. Wardite was named for Henry Augustus Ward (1834–1906) of the University of Rochester in New York. It first described in 1896 for an occurrence in Clay Canyon, Fairfield, Utah County, Utah, US. Though rare it has been reported from many locations worldwide. See also *List of minerals *List of minerals named after people This is a list of minerals named after people. The chemical compos ...
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Cristobalite
Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the quartz group, which also include coesite, tridymite and stishovite. It is named after Cerro San Cristóbal in Pachuca Municipality, Hidalgo, Mexico. It is used in dentistry as a component of alginate impression materials as well as for making models of teeth. Properties Metastability Cristobalite is stable only above 1470 °C, but can crystallize and persist metastably at lower temperatures. The persistence of cristobalite outside its thermodynamic stability range occurs because the transition from cristobalite to quartz or tridymite is "reconstructive", requiring the breaking up and reforming of the silica framework. These frameworks are composed of Si O4 tetrahedra in which every oxygen atom is shared with a neighbouring t ...
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Leucite
Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in 1821, they are not optically isotropic, and are therefore pseudo-cubic. Goniometric measurements made by Gerhard vom Rath in 1873 led him to refer the crystals to the tetragonal system. Optical investigations have since proved the crystals to be still more complex in character, and to consist of several orthorhombic or monoclinic individuals, which are optically biaxial and repeatedly twinned, giving rise to twin-lamellae and to striations on the faces. When the crystals are raised to a temperature of about 500 °C they become optically isotropic and the twin-lamellae and striations disappear, although they reappear when the crystals are cooled again. This pseudo-cubic character of leucite is very similar to that of the mineral boracit ...
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Wulfenite
Wulfenite is a lead molybdate mineral with the formula Pb Mo O4. It can be most often found as thin tabular crystals with a bright orange-red to yellow-orange color, sometimes brown, although the color can be highly variable. In its yellow form it is sometimes called "yellow lead ore". It crystallizes in the tetragonal system, often occurring as stubby, pyramidal or tabular crystals. It also occurs as earthy, granular masses. It is found in many localities, associated with lead ores as a secondary mineral associated with the oxidized zone of lead deposits. It is also a secondary ore of molybdenum, and is sought by collectors. Discovery and occurrence Wulfenite was first described in 1845 for an occurrence in Bad Bleiberg, Carinthia, Austria. It was named for Franz Xavier von Wulfen (1728–1805), an Austrian mineralogist. It occurs as a secondary mineral in oxidized hydrothermal lead deposits. It occurs with cerussite, anglesite, smithsonite, hemimorphite, vanadinite, pyromor ...
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Scheelite
Scheelite is a calcium tungstate mineral with the chemical formula Ca W O4. It is an important ore of tungsten (wolfram). Scheelite is originally named after Swedish chemist K. Scheele (1742-1786). Well-formed crystals are sought by collectors and are occasionally fashioned into gemstones when suitably free of flaws. Scheelite has been synthesized using the Czochralski process; the material produced may be used to imitate diamond, as a scintillator, or as a solid-state lasing medium. It was also used in radium paint in the same fashion as was zinc sulphide, and Thomas Edison invented a fluoroscope with a calcium tungstate-coated screen, making the images six times brighter than those with barium platinocyanide; the latter chemical allowed Röntgen to discover X-rays in early November 1895. Properties Its crystals are in the tetragonal crystal system, appearing as dipyramidal pseudo-octahedra. Colors include golden yellow, brownish green to dark brown, pinkish to reddish ...
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Centrosymmetric
In crystallography, a centrosymmetric point group contains an inversion center as one of its symmetry elements. In such a point group, for every point (x, y, z) in the unit cell there is an indistinguishable point (-x, -y, -z). Such point groups are also said to have ''inversion'' symmetry. Point reflection is a similar term used in geometry. Crystals with an inversion center cannot display certain properties, such as the piezoelectric effect. The following space groups have inversion symmetry: the triclinic space group 2, the monoclinic 10-15, the orthorhombic 47-74, the tetragonal 83-88 and 123-142, the trigonal 147, 148 and 162-167, the hexagonal 175, 176 and 191-194, the cubic 200-206 and 221-230. Point groups lacking an inversion center (non-centrosymmetric) can be ''polar'', ''chiral'', both, or neither. A ''polar'' point group is one whose symmetry operations leave more than one common point unmoved. A polar point group has no unique origin because each of those unmoved ...
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Tugtupite
Tugtupite is a beryllium aluminium tectosilicate. It also contains sodium and chlorine and has the formula Na4 Al Be Si4 O12 Cl. Tugtupite is a member of the silica-deficient feldspathoid mineral group. It occurs in high alkali intrusive igneous rocks. Tugtupite is tenebrescent, sharing much of its crystal structure with sodalite, and the two minerals are occasionally found together in the same sample. Tugtupite occurs as vitreous, transparent to translucent masses of tetragonal crystals and is commonly found in white, pink, to crimson, and even blue and green. It has a Mohs hardness of 4 and a specific gravity of 2.36. It fluoresces crimson under ultraviolet radiation. It was first found in 1962 at Tugtup agtakôrfia Ilimaussaq intrusive complex of southwest Greenland. It has also been found at Mont-Saint-Hilaire in Quebec and in the Lovozero Massif of the Kola Peninsula in Russia The name is derived from the Greenlandic Inuit word for reindeer Reindeer (in North ...
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Cahnite
Cahnite (Cahnit in German, Cahnita in Spanish, Канит in Russian) is a brittle white or colorless mineral that has perfect cleavage and is usually transparent. It usually forms tetragonal-shaped crystals and it has a hardness of 3 mohs. Cahnite was discovered in the year 1921. It was named Cahnite to honor Lazard Cahn (1865–1940), who was a mineral collector and dealer. It is usually found in the Franklin Mine, in Franklin, New Jersey, but has also been found in Japan as well as in the Vallerano quarries in Rome, Italy. The geological environment that it occurs in is in pegmatites cutting a changed zinc orebody. The chemical formula for cahnite is Ca2B sO4OH)4. It is made up of 26.91% calcium, 3.63% boron, 25.15% arsenic, 1.35% hydrogen, and 42.96% oxygen. It has a molecular weight of 297.91 grams. Cahnite is not radioactive. Cahnite is associated with these other minerals: willemite, rhodonite, pyrochroite, hedyphane, datolite, and baryte Baryte, barite or barytes ( o ...
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Piypite
Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster. It was first described in 1982 for an occurrence in the Main Fracture of the Tolbachik volcano, Kamchatka Oblast, Russia. It has also been reported from Mount Vesuvius, Italy, and in a slag deposit in the Bad Ems District in the Rhineland-Palatinate, Germany. Piypite occurs as a sublimate phase in a fumarole environment. Associated minerals include halite, sylvite, langbeinite, tenorite, hematite, tolbachite, dolerophanite, urusovite, aphthitalite, ponomarevite, cotunnite, chalcocyanite, sofiite, euchlorine, averievite, fedotovite, alarsite, alumoklyuchevskite, nabokoite and lammerite at the type locality in Kamchatka. On Vesuvius, it occurs with paratacamite Parata ...
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