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Wojciech Świętosławski
Wojciech Alojzy Świętosławski (1881 – 1968) was a Polish physical chemist, who is considered the "father of modern thermochemistry". He developed a static method of cryometric measurement and a new method of testing coal. Świętosławski was Vice-Chairman of the International Union of Pure and Applied Chemistry (IUPAC) and created the foundations for a new branch of physical chemistry: polyazeotropy. In 1933 he became a member of the Temporary Scientific and Advisory Committee Early Years Świętosławski was born on 21 June 1881 in the village of Kiryjowka, Podolian Governorate, Russian Empire. He spent his early years in Kiev, where he graduated from high school (1899). In 1906, he graduated with an engineering degree at Chemistry Department of Kiev Technical University. His first research paper, "Thermochemical Analysis of Organic Compounds" was published in 1908, in "Polish Yearly Magazine ("Rocznik Polski"). In appreciation of his work, Świętosławski was awarded t ...
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Russian Empire
The Russian Empire was an empire and the final period of the Russian monarchy from 1721 to 1917, ruling across large parts of Eurasia. It succeeded the Tsardom of Russia following the Treaty of Nystad, which ended the Great Northern War. The rise of the Russian Empire coincided with the decline of neighbouring rival powers: the Swedish Empire, the Polish–Lithuanian Commonwealth, Qajar Iran, the Ottoman Empire, and Qing China. It also held colonies in North America between 1799 and 1867. Covering an area of approximately , it remains the third-largest empire in history, surpassed only by the British Empire and the Mongol Empire; it ruled over a population of 125.6 million people per the 1897 Russian census, which was the only census carried out during the entire imperial period. Owing to its geographic extent across three continents at its peak, it featured great ethnic, linguistic, religious, and economic diversity. From the 10th–17th centuries, the land ...
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Amine
In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group (these may respectively be called alkylamines and arylamines; amines in which both types of substituent are attached to one nitrogen atom may be called alkylarylamines). Important amines include amino acids, biogenic amines, trimethylamine, and aniline; Inorganic derivatives of ammonia are also called amines, such as monochloramine (). The substituent is called an amino group. Compounds with a nitrogen atom attached to a carbonyl group, thus having the structure , are called amides and have different chemical properties from amines. Classification of amines Amines can be classified according to the nature and number of substituents on nitrogen. Aliphatic amines contain only H and alkyl substituents. A ...
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Temporary Advisory And Scientific Committee
Temporary Advisory and Scientific Committee ( pl, Tymczasowy Komitet Doradczo-Naukowy, TKDN) was established in 1933 under the patronage of the Ministry of National Defence (Poland), Ministry of Military Affairs in Poland. It was one of the first attempts in pre-Second World War Poland to institutionalise the army’s cooperation with the scientific community in order to increase the country's military and economic potential. The following eminent scientists participated in the work of the TKDN: Janusz Groszkowski, Maksymilian Huber, Stanisław Pawłowski, Mieczysław Pożaryski, Antoni Roman, Bohdan Stefanowski, Wojciech Świętosławski, Czesław Witoszyński, Mieczysław Wolfke and in 1936 Kazimierz Smoleński. The liaison officers of the Ministry of Military Affairs included: Col. Zagrodzki, MD, Col. Stanisław Witkowski, Dipl.Eng, (Head of the War Industry Bureau), and Lt. Col. Leopold Gebel, (Deputy Head of the Army Administration Office, secretary to the TKDN). An increasingl ...
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Polish Academy Of Learning
The Polish Academy of Arts and Sciences or Polish Academy of Learning ( pl, Polska Akademia Umiejętności), headquartered in Kraków and founded in 1872, is one of two institutions in contemporary Poland having the nature of an academy of sciences. (The other is the Polish Academy of Sciences, headquartered in Warsaw.) The Polish Academy of Arts and Sciences is co-owner of the Polish Library in Paris. History The Academy traces its origins to Academy of Learning founded in 1871, itself a result of the transformation of the , in existence since 1815. Though formally limited to the Austrian Partition, the Academy served from the beginning as a learned and cultural society for the entire Polish nation. Its activities extended beyond the boundaries of the Austrian Partition, gathering scholars from all of Poland, and many other countries as well. Some indication of how the Academy's influence extended beyond the boundaries of the Partitions came in 1893, when the collection of the ...
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Warsaw Scientific Society
Warsaw Scientific Society (Polish: ''Towarzystwo Naukowe Warszawskie''; TNW) is a Polish scientific society based in Warsaw Warsaw ( pl, Warszawa, ), officially the Capital City of Warsaw,, abbreviation: ''m.st. Warszawa'' is the capital and largest city of Poland. The metropolis stands on the River Vistula in east-central Poland, and its population is officia .... It was established in 1907 as a continuation of the Society of Friends of Science to advance the sciences and arts and to publish scientific papers. External links Warsaw Scientific Society homepage Scientific societies based in Poland Scientific organizations established in 1907 1907 establishments in Poland {{sci-org-stub ...
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Ebulliometer
An ebulliometer is designed to accurately measure the boiling point of liquids by measuring the temperature of the vapor–liquid equilibrium either isobarically or isothermally. The primary components in a Świętosławski ebulliometer, which operates isobarically, are the boiler, the Cottrell pumps, the thermowell, and the condenser. Such an ebulliometer can be used for extremely accurate measurements of boiling temperature, molecular weights, mutual solubilities, and solvent purities by using a resistance thermometer (RTD) to measure the near-equilibrium conditions of the thermowell. The ebulliometer is frequently used for measuring the alcohol content of dry wines. See also Sweetness of wine and Oechsle scale The Oechsle scale is a hydrometer scale measuring the density of grape must, which is an indication of grape ripeness and sugar content used in wine-making. It is named for Ferdinand Oechsle (1774–1852) and it is widely used in the German, Swiss .... References * ...
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Boiling
Boiling is the rapid vaporization of a liquid, which occurs when a liquid is heated to its boiling point, the temperature at which the vapour pressure of the liquid is equal to the pressure exerted on the liquid by the surrounding atmosphere. There are two main types of boiling: nucleate boiling where small bubbles of vapour form at discrete points, and critical heat flux boiling where the boiling surface is heated above a certain critical temperature and a film of vapor forms on the surface. Transition boiling is an intermediate, unstable form of boiling with elements of both types. The boiling point of water is 100 °C or 212 °F but is lower with the decreased atmospheric pressure found at higher altitudes. Boiling water is used as a method of making it potable by killing microbes and viruses that may be present. The sensitivity of different micro-organisms to heat varies, but if water is held at for one minute, most micro-organisms and viruses are inactivated. Ten ...
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Vapor Pressure
Vapor pressure (or vapour pressure in English-speaking countries other than the US; see spelling differences) or equilibrium vapor pressure is defined as the pressure exerted by a vapor in thermodynamic equilibrium with its condensed phases (solid or liquid) at a given temperature in a closed system. The equilibrium vapor pressure is an indication of a liquid's evaporation rate. It relates to the tendency of particles to escape from the liquid (or a solid). A substance with a high vapor pressure at normal temperatures is often referred to as '' volatile''. The pressure exhibited by vapor present above a liquid surface is known as vapor pressure. As the temperature of a liquid increases, the kinetic energy of its molecules also increases. As the kinetic energy of the molecules increases, the number of molecules transitioning into a vapor also increases, thereby increasing the vapor pressure. The vapor pressure of any substance increases non-linearly with temperature according ...
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Heat Of Combustion
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions. The chemical reaction is typically a hydrocarbon or other organic molecule reacting with oxygen to form carbon dioxide and water and release heat. It may be expressed with the quantities: * energy/mole of fuel * energy/mass of fuel * energy/volume of the fuel There are two kinds of enthalpy of combustion, called high(er) and low(er) heat(ing) value, depending on how much the products are allowed to cool and whether compounds like are allowed to condense. The high heat values are conventionally measured with a bomb calorimeter. Low heat values are calculated from high heat value test data. They may also be calculated as the difference betw ...
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Benzoic Acid
Benzoic acid is a white (or colorless) solid organic compound with the formula , whose structure consists of a benzene ring () with a carboxyl () substituent. It is the simplest aromatic carboxylic acid. The name is derived from gum benzoin, which was for a long time its only source. Benzoic acid occurs naturally in many plants and serves as an intermediate in the biosynthesis of many secondary metabolites. Salts of benzoic acid are used as food preservatives. Benzoic acid is an important precursor for the industrial synthesis of many other organic substances. The salts and esters of benzoic acid are known as benzoates . History Benzoic acid was discovered in the sixteenth century. The dry distillation of gum benzoin was first described by Nostradamus (1556), and then by Alexius Pedemontanus (1560) and Blaise de Vigenère (1596). Justus von Liebig and Friedrich Wöhler determined the composition of benzoic acid. These latter also investigated how hippuric acid is related ...
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Rome
, established_title = Founded , established_date = 753 BC , founder = King Romulus (legendary) , image_map = Map of comune of Rome (metropolitan city of Capital Rome, region Lazio, Italy).svg , map_caption = The territory of the ''comune'' (''Roma Capitale'', in red) inside the Metropolitan City of Rome (''Città Metropolitana di Roma'', in yellow). The white spot in the centre is Vatican City. , pushpin_map = Italy#Europe , pushpin_map_caption = Location within Italy##Location within Europe , pushpin_relief = yes , coordinates = , coor_pinpoint = , subdivision_type = Country , subdivision_name = Italy , subdivision_type2 = Region , subdivision_name2 = Lazio , subdivision_type3 = Metropolitan city , subdivision_name3 = Rome Capital , government_footnotes= , government_type = Strong Mayor–Council , leader_title2 = Legislature , leader_name2 = Capitoline Assemb ...
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Enthalpy Of Vaporization
The enthalpy of vaporization (symbol ), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy (enthalpy) that must be added to a liquid substance to transform a quantity of that substance into a gas. The enthalpy of vaporization is a function of the pressure at which that transformation takes place. The enthalpy of vaporization is often quoted for the normal boiling temperature of the substance. Although tabulated values are usually corrected to 298  K, that correction is often smaller than the uncertainty in the measured value. The heat of vaporization is temperature-dependent, though a constant heat of vaporization can be assumed for small temperature ranges and for reduced temperature T_r \ll 1. The heat of vaporization diminishes with increasing temperature and it vanishes completely at a certain point called the critical temperature (T_r = 1). Above the critical temperature, the liquid and vapor phases are indistinguishabl ...
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