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Wobbe Index
The Wobbe index (WI) or Wobbe number is an indicator of the interchangeability of fuel gases such as natural gas, liquefied petroleum gas (LPG), and town gas and is frequently defined in the specifications of gas supply and transport utilities. If V_C is the higher heating value, or higher calorific value, and G_S is the specific gravity, the Wobbe index, I_W, is defined as: :I_W = \frac . :G_S = \frac = \frac \rho_ is the density of the gas at standard conditions (0 °C, 101.325 kPa), \rho_ is the density of air at standard conditions, M is the molar mass of the gas and M_ is the molar mass of air which is about 28.96 kg/kmol. The Wobbe index is used to compare the combustion energy output of different composition fuel gases in an appliance (fire, cooker etc.). If two fuels have identical Wobbe indices then for given pressure and valve settings the energy output will also be identical. Typically variations of up to 5% are allowed as these would not be noticeable to th ...
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Fuel Gas
Fuel gas is any one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane or propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources energy that can be readily transmitted and distributed through pipes. Fuel gas is contrasted with liquid fuels and from solid fuels, although some fuel gases are Liquefaction of gases, liquefied for storage or transport (for example, autogas). While their gaseous nature has advantages, avoiding the difficulty of transporting solid fuel and the dangers of spillage inherent in liquid fuels, it also has limitation. It is possible for a fuel gas to be undetected and cause gas explosion. For this reason, odorizers are added to most fuel gases. The most common type of fuel gas in current use is natural gas. Types There are two broad classes of fuel gases, based not on their chemical composition, but their source and the way they are produced: those found n ...
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Natural Gas
Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon dioxide, nitrogen, hydrogen sulfide, and helium are also usually present. Natural gas is colorless and odorless, so odorizers such as mercaptan (which smells like sulfur or rotten eggs) are commonly added to natural gas supplies for safety so that leaks can be readily detected. Natural gas is a fossil fuel and non-renewable resource that is formed when layers of organic matter (primarily marine microorganisms) decompose under anaerobic conditions and are subjected to intense heat and pressure underground over millions of years. The energy that the decayed organisms originally obtained from the sun via photosynthesis is stored as chemical energy within the molecules of methane and other hydrocarbons. Natural gas can be burned fo ...
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Town Gas
Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities. The original coal gas was produced by the coal gasification reaction, and thus the burnable component consisted of a roughly equal molecular mixture of carbon monoxide and hydrogen. Thus, coal gas was highly toxic. Other compositions contain additional calorific gases such as methane, produced by the Fischer-Tropsch process, and volatile hydrocarbons together with small quantities of non-calorific gases such as carbon dioxide and nitrogen. Prior to the development of natural gas supply and transmission—during the 1940s and 1950s in the United States and during the late 1960s and 1970s in the United Kingdom and Australia—almost all gas for fuel and lighting was manufactured fro ...
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Standard Cubic Foot
A standard cubic foot (scf) is a unit used both in the natural gas industry to represent an amount of natural gas and in other industries where other gases are used. It is the unit commonly used when following the customary system, a collection of standards set by the National Institute of Standards and Technology. Another unit used for the same purpose is the standard cubic metre (Sm3), customary when using SI units. Definitions A standard cubic foot defines an amount of gas contained in a volume of one cubic foot at standard temperature and pressure. This standard unit of molecular quantity for gases can be used with the ideal gas law to compute the quantity per unit of volume for other pressures and temperatures. In spite of the label "standard", there is a variety of definitions, mainly depending on the type of gas. Since, for a given volume, the quantity is proportional to the pressure and temperature, each definition fixes base values for pressure and temperature. Natural ...
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British Thermal Unit
The British thermal unit (BTU or Btu) is a unit of heat; it is defined as the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit. It is also part of the United States customary units. The modern SI unit for heat energy is the joule (J); one BTU equals about 1055  J (varying within the range 1054–1060 J depending on the specific definition; see below). While units of heat are often supplanted by energy units in scientific work, they are still used in some fields. For example, in the United States the price of natural gas is quoted in dollars per the amount of natural gas that would give 1 million BTUs (1 "MMBtu") of heat energy if burned. Definitions A BTU was originally defined as the amount of heat required to raise the temperature of 1 avoirdupois pound of liquid water by 1 degree Fahrenheit at a constant pressure of one atmospheric unit. There are several different definitions of the BTU that differ slightly. This ref ...
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Megajoule
The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applied. It is also the energy dissipated as heat when an electric current of one ampere passes through a resistance of one ohm for one second. It is named after the English physicist James Prescott Joule (1818–1889). Definition In terms of SI base units and in terms of SI derived units with special names, the joule is defined as One joule can also be defined by any of the following: * The work required to move an electric charge of one coulomb through an electrical potential difference of one volt, or one coulomb-volt (C⋅V). This relationship can be used to define the volt. * The work required to produce one watt of power for one second, or one watt-second (W⋅s) (compare kilowatt-hour, which is 3.6 megajoules). This relationship can be ...
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Joule
The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applied. It is also the energy dissipated as heat when an electric current of one ampere passes through a resistance of one ohm for one second. It is named after the English physicist James Prescott Joule (1818–1889). Definition In terms of SI base units and in terms of SI derived units with special names, the joule is defined as One joule can also be defined by any of the following: * The work required to move an electric charge of one coulomb through an electrical potential difference of one volt, or one coulomb-volt (C⋅V). This relationship can be used to define the volt. * The work required to produce one watt of power for one second, or one watt-second (W⋅s) (compare kilowatt-hour, which is 3.6 megajoules). This relationship can b ...
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Carbon Monoxide
Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simplest molecule of the oxocarbon family. In coordination complexes the carbon monoxide ligand is called carbonyl. It is a key ingredient in many processes in industrial chemistry. The most common source of carbon monoxide is the partial combustion of carbon-containing compounds, when insufficient oxygen or heat is present to produce carbon dioxide. There are also numerous environmental and biological sources that generate and emit a significant amount of carbon monoxide. It is important in the production of many compounds, including drugs, fragrances, and fuels. Upon emission into the atmosphere, carbon monoxide affects several processes that contribute to climate change. Carbon monoxide has important biological roles across phylogenetic ...
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Acetylene
Acetylene (systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure form and thus is usually handled as a solution. Pure acetylene is odorless, but commercial grades usually have a marked odor due to impurities such as divinyl sulfide and phosphine.Compressed Gas Association (1995Material Safety and Data Sheet – Acetylene As an alkyne, acetylene is unsaturated because its two carbon atoms are bonded together in a triple bond. The carbon–carbon triple bond places all four atoms in the same straight line, with CCH bond angles of 180°. Discovery Acetylene was discovered in 1836 by Edmund Davy, who identified it as a "new carburet of hydrogen". It was an accidental discovery while attempting to isolate potassium metal. By heating potassium carbonate with carbon at very high temperatures, he produced a ...
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Liquefied Petroleum Gas
Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking equipment, and vehicles. It is increasingly used as an aerosol propellant and a refrigerant, replacing chlorofluorocarbons in an effort to reduce damage to the ozone layer. When specifically used as a vehicle fuel, it is often referred to as autogas or even just as gas. Varieties of LPG that are bought and sold include mixes that are mostly propane (), mostly butane (), and, most commonly, mixes including both propane and butane. In the northern hemisphere winter, the mixes contain more propane, while in summer, they contain more butane. In the United States, mainly two grades of LPG are sold: commercial propane and HD-5. These specifications are published by the Gas Processors Association (GPA) and the American Society of Testing and Ma ...
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Butylene-1
Butene, also known as butylene, is an alkene with the formula . The word ''butene'' may refer to any of the individual compounds. They are colourless gases that are present in crude oil as a minor constituent in quantities that are too small for viable extraction. Butene is therefore obtained by catalytic cracking of long-chain hydrocarbons left during refining of crude oil. Cracking produces a mixture of products, and the butene is extracted from this by fractional distillation. Butene can be used as the monomer for polybutene, but this polymer is more expensive than alternatives with shorter carbon chains such as polypropylene. Polybutene is therefore used in more specialized applications. Butenes are more commonly used to make copolymer (mixed with another monomer such as ethylene). Isomers Among the molecules which have the chemical formula four isomers are alkenes. All four of these hydrocarbons have four carbon atoms and one double bond in their molecules, but have diffe ...
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Iso-butane
Isobutane, also known as ''i''-butane, 2-methylpropane or methylpropane, is a chemical compound with molecular formula HC(CH3)3. It is an isomer of butane. Isobutane is a colourless, odourless gas. It is the simplest alkane with a tertiary carbon atom. Isobutane is used as a precursor molecule in the petrochemical industry, for example in the synthesis of isooctane. Production Isobutane is obtained by isomerization of butane. : Uses Isobutane is the principal feedstock in alkylation units of refineries. Using isobutane, gasoline-grade "blendstocks" are generated with high branching for good combustion characteristics. Typical products created with isobutane are 2,4-dimethylpentane and especially 2,2,4-trimethylpentane. Solvent In the Chevron Phillips slurry process for making high-density polyethylene, isobutane is used as a diluent. As the slurried polyethylene is removed, isobutane is "flashed" off, and condensed, and recycled back into the loop reactor for this purpose. Precu ...
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