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The Wobbe index (WI) or Wobbe number is an indicator of the interchangeability of
fuel gas Fuel gas is any one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane or propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources energy t ...
es such as
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
, liquefied petroleum gas (LPG), and
town gas Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous ...
and is frequently defined in the specifications of gas supply and transport utilities. If V_C is the
higher heating value The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy relea ...
, or higher calorific value, and G_S is the
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...
, the Wobbe index, I_W, is defined as: :I_W = \frac . :G_S = \frac = \frac \rho_ is the density of the gas at
standard conditions Standard temperature and pressure (STP) are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union ...
(0 °C, 101.325 kPa), \rho_ is the density of air at standard conditions, M is the
molar mass In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance which is the number of moles in that sample, measured in moles. The molar mass is a bulk, not molecular, ...
of the gas and M_ is the molar mass of air which is about 28.96 kg/kmol. The Wobbe index is used to compare the combustion energy output of different composition fuel gases in an appliance (fire, cooker etc.). If two fuels have identical Wobbe indices then for given pressure and valve settings the energy output will also be identical. Typically variations of up to 5% are allowed as these would not be noticeable to the consumer. The Wobbe index is a critical factor to minimise the impact of the changeover when analyzing the use of ''
substitute natural gas Substitute natural gas (SNG), or synthetic natural gas, is a fuel gas (predominantly methane, CH4) that can be produced from fossil fuels such as lignite coal, oil shale, or from biofuels (when it is named Renewable natural gas, bio-SNG) or using e ...
'' (SNG) fuels such as propane-
air The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing f ...
mixtures. The Wobbe index also requires the addition of propane to some upgraded biomethane products, particularly in regions where natural gas has a high calorific value such as Sweden. The Wobbe index has its origins in the 1920's with
Italian Italian(s) may refer to: * Anything of, from, or related to the people of Italy over the centuries ** Italians, an ethnic group or simply a citizen of the Italian Republic or Italian Kingdom ** Italian language, a Romance language *** Regional Ita ...
physicist and engineer Goffredo Wobbe.


Wobbe index of common fuel gases

:Note: 1
Joule The joule ( , ; symbol: J) is the unit of energy in the International System of Units (SI). It is equal to the amount of work done when a force of 1 newton displaces a mass through a distance of 1 metre in the direction of the force applie ...
= .


Usage

The Wobbe index is expressed in MJ/ Nm³ (where the ill-advised symbol 'Nm³' is intended to mean 'm³ in Normal conditions, much against the BIPM prescription for writing SI units), or sometimes in
BTU The British thermal unit (BTU or Btu) is a unit of heat; it is defined as the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit. It is also part of the United States customary units. The modern SI u ...
/ scf. In the case of natural gas (
molar mass In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance which is the number of moles in that sample, measured in moles. The molar mass is a bulk, not molecular, ...
17 g/mol), the typical heating value is around 39 MJ/Nm³ (1,050 BTU/scf) and the specific gravity is approximately 0.59, giving a typical Wobbe index of 51 MJ/Nm³ (1,367 BTU/scf). There are three ranges or "families" of fuel gases that have been internationally agreed based on Wobbe index. Family 1 covers manufactured gases, family 2 covers natural gases (with high and low ranges) and family 3 covers liquefied petroleum gas ( LPG). Combustion equipment is typically designed to burn a fuel gas within a particular family: hydrogen-rich town gas, natural gas or LPG. Other flame characteristics and composition limits may determine the acceptability of the replacement gas, e.g.
flame speed The flame speed is the measured rate of expansion of the flame front in a combustion reaction. Whereas ''flame velocity'' is generally used for a fuel, a related term is explosive velocity, which is the same relationship measured for an explosive. ...
, "yellow tipping" due to incomplete combustion, sulfur content, oxygen content, etc.


Limitations

In spite of its usefulness, Wobbe index alone is not a good indicator of the interchangeability of two or more gases, or mixtures of them. It is necessary to bear in mind other criteria while determining the plenty substitution of a fuel by other, different of the one used to adjust the burning system.


References

* {{Reflist Fuel gas Gas technologies