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Velocity Map Imaging
Photofragment ion imaging or, more generally, Product Imaging is an experimental technique for making measurements of the velocity of product molecules or particles following a chemical reaction or the photodissociation of a parent molecule. The method uses a two-dimensional detector, usually a microchannel plate, to record the arrival positions of state-selected ions created by resonantly enhanced multi-photon ionization ( REMPI). The first experiment using photofragment ion imaging was performed by David W Chandler and Paul L Houston in 1987 on the phototodissociation dynamics of methyl iodide ( iodomethane, CH3I). Background Many problems in molecular reaction dynamics demand the simultaneous measurement of a particle's speed and angular direction; the most demanding require the measurement of this velocity in coincidence with internal energy. Studies of molecular reactions, energy transfer processes and photodissociation can only be understood completely if the internal en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photodissociation
Photodissociation, photolysis, photodecomposition, or photofragmentation is a chemical reaction in which molecules of a chemical compound are broken down by photons. It is defined as the interaction of one or more photons with one target molecule. Photodissociation is not limited to visible light. Any photon with sufficient energy can affect the chemical bonds of a chemical compound. Since a photon's energy is inversely proportional to its wavelength, electromagnetic radiations with the energy of visible light or higher, such as ultraviolet light, x-rays, and gamma rays can induce such reactions. Photolysis in photosynthesis Photolysis is part of the light-dependent reaction or light phase or photochemical phase or Hill reaction of photosynthesis. The general reaction of photosynthetic photolysis can be given in terms of photons as: :\ce + 2 \text \longrightarrow \ce The chemical nature of "A" depends on the type of organism. Purple sulfur bacteria oxidize hydrogen sulfide () ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Angular Momentum
In physics, angular momentum (rarely, moment of momentum or rotational momentum) is the rotational analog of linear momentum. It is an important physical quantity because it is a conserved quantity—the total angular momentum of a closed system remains constant. Angular momentum has both a direction and a magnitude, and both are conserved. Bicycles and motorcycles, frisbees, rifled bullets, and gyroscopes owe their useful properties to conservation of angular momentum. Conservation of angular momentum is also why hurricanes form spirals and neutron stars have high rotational rates. In general, conservation limits the possible motion of a system, but it does not uniquely determine it. The three-dimensional angular momentum for a point particle is classically represented as a pseudovector , the cross product of the particle's position vector (relative to some origin) and its momentum vector; the latter is in Newtonian mechanics. Unlike linear momentum, angular m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ultrashort Pulse
In optics, an ultrashort pulse, also known as an ultrafast event, is an electromagnetic pulse whose time duration is of the order of a picosecond (10−12 second) or less. Such pulses have a broadband optical spectrum, and can be created by mode-locked oscillators. Amplification of ultrashort pulses almost always requires the technique of chirped pulse amplification, in order to avoid damage to the gain medium of the amplifier. They are characterized by a high peak intensity (or more correctly, irradiance) that usually leads to nonlinear interactions in various materials, including air. These processes are studied in the field of nonlinear optics. In the specialized literature, "ultrashort" refers to the femtosecond (fs) and picosecond (ps) range, although such pulses no longer hold the record for the shortest pulses artificially generated. Indeed, x-ray pulses with durations on the attosecond time scale have been reported. The 1999 Nobel Prize in Chemistry was awarded ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectron Spectroscopy
Photoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy measurement of electrons emitted from solids, gases or liquids by the photoelectric effect, in order to determine the binding energies of electrons in the substance. The term refers to various techniques, depending on whether the ionization energy is provided by X-ray, XUV or UV photons. Regardless of the incident photon beam, however, all photoelectron spectroscopy revolves around the general theme of surface analysis by measuring the ejected electrons. Types X-ray photoelectron spectroscopy (XPS) was developed by Kai Siegbahn starting in 1957 and is used to study the energy levels of atomic core electrons, primarily in solids. Siegbahn referred to the technique as "electron spectroscopy for chemical analysis" (ESCA), since the core levels have small chemical shifts depending on the chemical environment of the atom that is ionized, allowing chemical structure to be determined. Siegbahn ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photoelectron Photoion Coincidence Spectroscopy
Photoelectron photoion coincidence spectroscopy (PEPICO) is a combination of photoionization mass spectrometry and Photoemission spectroscopy, photoelectron spectroscopy. It is largely based on the photoelectric effect. Free molecules from a gas-phase sample are ionized by incident Ultraviolet#Vacuum UV, vacuum ultraviolet (VUV) radiation. In the ensuing Photoelectrochemical processes#Photoionization, photoionization, a Ion, cation and a photoelectron are formed for each sample molecule. The mass of the photoion is determined by time-of-flight mass spectrometry, whereas, in current setups, photoelectrons are typically detected by Photofragment-ion imaging#Velocity Map Imaging, velocity map imaging. Electron times-of-flight are three orders of magnitude smaller than those of ions, which allows electron detection to be used as a time stamp for the ionization event, starting the clock for the ion time-of-flight analysis. In contrast with pulsed experiments, such as Resonance-enhanced ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrostatic Lens
An electrostatic lens is a device that assists in the transport of charged particles. For instance, it can guide electrons emitted from a sample to an electron analyzer, analogous to the way an optical lens assists in the transport of light in an optical instrument. Systems of electrostatic lenses can be designed in the same way as optical lenses, so electrostatic lenses easily magnify or converge the electron trajectories. An electrostatic lens can also be used to focus an ion beam, for example to make a microbeam for irradiating individual cells. Cylinder lens A cylinder lens consists of several cylinders whose sides are thin walls. Each cylinder lines up parallel to the optical axis into which electrons enter. There are small gaps put between the cylinders. When each cylinder has a different voltage, the gap between the cylinders works as a lens. The magnification is able to be changed by choosing different voltage combinations. Although the magnification of two cylinder lenses ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Abel Transform
In mathematics, the Abel transform,N. H. Abel, Journal für die reine und angewandte Mathematik, 1, pp. 153–157 (1826). named for Niels Henrik Abel, is an integral transform often used in the analysis of spherically symmetric or axially symmetric functions. The Abel transform of a function ''f''(''r'') is given by : F(y) = 2 \int_y^\infty \frac \,dr. Assuming that ''f''(''r'') drops to zero more quickly than 1/''r'', the inverse Abel transform is given by : f(r) = -\frac \int_r^\infty \frac \,\frac. In image analysis, the forward Abel transform is used to project an optically thin, axially symmetric emission function onto a plane, and the inverse Abel transform is used to calculate the emission function given a projection (i.e. a scan or a photograph) of that emission function. In absorption spectroscopy of cylindrical flames or plumes, the forward Abel transform is the integrated absorbance along a ray with closest distance ''y'' from the center of the flame, while the inve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Charge-coupled Device
A charge-coupled device (CCD) is an integrated circuit containing an array of linked, or coupled, capacitors. Under the control of an external circuit, each capacitor can transfer its electric charge to a neighboring capacitor. CCD sensors are a major technology used in digital imaging. In a CCD image sensor, pixels are represented by p-doped metal–oxide–semiconductor (MOS) capacitors. These MOS capacitors, the basic building blocks of a CCD, are biased above the threshold for inversion when image acquisition begins, allowing the conversion of incoming photons into electron charges at the semiconductor-oxide interface; the CCD is then used to read out these charges. Although CCDs are not the only technology to allow for light detection, CCD image sensors are widely used in professional, medical, and scientific applications where high-quality image data are required. In applications with less exacting quality demands, such as consumer and professional digital cameras, act ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methyl Iodide
Iodomethane, also called methyl iodide, and commonly abbreviated "MeI", is the chemical compound with the formula CH3I. It is a dense, colorless, volatile liquid. In terms of chemical structure, it is related to methane by replacement of one hydrogen atom by an atom of iodine. It is naturally emitted by rice plantations in small amounts. It is also produced in vast quantities estimated to be greater than 214,000 tons annually by algae and kelp in the world's temperate oceans, and in lesser amounts on land by terrestrial fungi and bacteria. It is used in organic synthesis as a source of methyl groups. Preparation and handling Iodomethane is formed via the exothermic reaction that occurs when iodine is added to a mixture of methanol with red phosphorus. The iodinating reagent is phosphorus triiodide that is formed ''in situ:'' :3 CH3OH + PI3 → 3 CH3I + H2PO3H Alternatively, it is prepared from the reaction of dimethyl sulfate with potassium iodide in the presence of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polarization (waves)
Polarization (also polarisation) is a property applying to transverse waves that specifies the geometrical orientation of the oscillations. In a transverse wave, the direction of the oscillation is perpendicular to the direction of motion of the wave. A simple example of a polarized transverse wave is vibrations traveling along a taut string ''(see image)''; for example, in a musical instrument like a guitar string. Depending on how the string is plucked, the vibrations can be in a vertical direction, horizontal direction, or at any angle perpendicular to the string. In contrast, in longitudinal waves, such as sound waves in a liquid or gas, the displacement of the particles in the oscillation is always in the direction of propagation, so these waves do not exhibit polarization. Transverse waves that exhibit polarization include electromagnetic waves such as light and radio waves, gravitational waves, and transverse sound waves (shear waves) in solids. An electromagnetic wa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
