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Uranyl Carbonate
Uranyl carbonate refers to the inorganic compound with the formula UO2CO3. Also known by its mineral name rutherfordine, this material consists of uranyl (UO22+) and carbonate (CO32-). Like most uranyl salts, the compound is a polymeric, each uranium(VI) center being bonded to eight O atoms. Hydrolysis products of rutherfordine are also found in both the mineral and organic fractions of coal and its fly ash and is the main component of uranium in mine tailing seepage water. Uranyl carbonates as a class of materials Many uranyl carbonates exist, rutherfordine being the simplest stoichiometry. Most uranyl carbonates additional components including water and diverse anions and cations. A common method for concentrating uranium from a solution uses solutions of uranyl carbonates, which are passed through a resin bed where the complex ions are transferred to the resin by ion exchange with a negative ion like chloride. After build-up of the uranium complex on the resin, the uranium is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of modern ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Uranyl Compounds
The uranyl ion is an oxycation In chemistry, an oxycation is a polyatomic ion with a positive charge that contains oxygen. Examples * Dioxygenyl ion, * Nitrosonium ion, * Nitronium ion, * Vanadyl ion, VO2+, a very stable oxycation * Uranyl ion, , all natural U6+ occurs in t ... of uranium in the oxidation state +6, with the chemical formula . It has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen. Four or more ligands may be bound to the uranyl ion in an equatorial plane around the uranium atom. The uranyl ion forms many complex (chemistry), complexes, particularly with ligands that have oxygen donor atoms. Complexes of the uranyl ion are important in the extraction of uranium from its ores and in nuclear fuel reprocessing. Structure and bonding The uranyl ion is linear and symmetrical, with both U–O bond lengths of about 180 pm. The bond lengths are indicative of the presence of multiple bonding between ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Znucalite
Znucalite or CaZn11(UO2)(CO3)3(OH)20·4(H2O) is a rare, radioactive, white to pale cream colored uranium-containing carbonate mineral, hydrated calcium zinc uranyl carbonate hydroxide. Znucalite crystallizes in the orthorhombic system, often forming aggregates or crusts, and is found as a rare secondary species in carbonate-hosted (meaning it is mined from carbonate containing formations such as limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...) polymetallic veins, and nearby oxidizing uranium veins; on dump material and coating mine walls, apparently of post-mine origin. It fluoresces yellow-green under UV light. It was first described in 1989, after being discovered in Lill Mine, Černojamské deposit (Black pits deposit) in the Czech Republic. It was named in 1990 by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zellerite
Zellerite is a uranium mineral, named after its discoverer, geologist Howard Davis Zeller. It has a type locality of the Lucky MC uranium mine in Wyoming, USA. It was approved by the IMA in 1965, but was first published a year after its approval. Properties Zellerite is a dimorph of meyrowitzite. It is a uranyl carbonate. It is an acicular mineral, and occurs in crystals that resemble the shape of needles. It can occur as fine hairlike fibers as well. The size of each crystal is up to 2 mm, and it grows in roughly radial aggregates, veinlets, and incrustations. Elongation is possible. It has pleochroic attributes, which is an optical phenomenon. Depending on which axis the specimen is being inspected, it can occur as it changes color. Upon being inspected on the x or y axis, the mineral can seem to be colorless, but on the z axis, it is seen in a pale yellow color. The mineral also shows luminescence. Under both a short wave and a long wave ultraviolet light, it fluoresces in ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wyartite
Wyartite ·7H2O is a uranium bearing mineral named after Jean Wyart (1902–1992), mineralogist at the Sorbonne, Paris. It has greenish-black, black, or violet-black, translucent to opaque orthorhombic crystals. A hardness of 3 - 4 Mohs. Its other names are Ianthinite (of Bignand), Wyartit and Wyartita. It belongs to the uranium carbonate group of minerals. It is found next to rutherfordine in Shinkolobwe, Shaba, Zaire. Determination of the structure of wyartite provided the first evidence for a pentavalent uranium mineral. Like all uranium minerals it is radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consid .... References Uranium minerals Calcium minerals Carbonate minerals Orthorhombic minerals Minerals in space group 19 Uranium(V) compounds Uranyl compounds ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Schröckingerite
Schröckingerite is a radioactive yellow uranium-containing carbonate mineral, hydrated sodium calcium uranyl sulfate carbonate fluoride.http://www.webmineral.com/data/Schrockingerite.shtml Webmineralhttp://www.mindat.org/min-3584.html Mindat Schröckingerite crystallizes in the orthorhombic system, occurring as globular clusters, and fluoresces yellow-green under ultraviolet light. Schröckingerite was first described in 1783 from an occurrence in Jáchymov, Bohemia, Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ..., and named for its discoverer, Julius Freiherr Schröckinger von Neudenberg (1814–1882). References Uranium(VI) minerals Carbonate minerals Sulfate minerals Triclinic minerals Minerals in space group 2 {{Carbonate-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
