Ultrasound Attenuation Spectroscopy
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Ultrasound Attenuation Spectroscopy
Ultrasound attenuation spectroscopy is a method for characterizing properties of fluids and dispersed particles. It is also known as acoustic spectroscopy There is an international standard for this method.Dukhin, A.S. and Goetz, P.J. "Ultrasound for characterizing colloids", Elsevier, 2002 Measurement of attenuation coefficient versus ultrasound frequency yields raw data for further calculation of various system properties. Such raw data are often used in the calculation of the particle size distribution in heterogeneous systems such as emulsions and colloids. In the case of acoustic rheometers, the raw data are converted into extensional viscosity or volume viscosity Volume viscosity (also called bulk viscosity, or dilatational viscosity) is a material property relevant for characterizing fluid flow. Common symbols are \zeta, \mu', \mu_\mathrm, \kappa or \xi. It has dimensions (mass / (length × time)), and the .... Instruments that employ ''ultrasound attenuation spectroscopy'' ...
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Fluids
In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear force applied to them. Although the term ''fluid'' generally includes both the liquid and gas phases, its definition varies among branches of science. Definitions of ''solid'' vary as well, and depending on field, some substances can be both fluid and solid. Viscoelastic fluids like Silly Putty appear to behave similar to a solid when a sudden force is applied. Substances with a very high viscosity such as pitch appear to behave like a solid (see pitch drop experiment) as well. In particle physics, the concept is extended to include fluidic matters other than liquids or gases. A fluid in medicine or biology refers any liquid constituent of the body (body fluid), whereas "liquid" is not used in this sense. Sometimes liquids given for flu ...
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Dispersed Particles
Dispersion may refer to: Economics and finance *Dispersion (finance), a measure for the statistical distribution of portfolio returns *Price dispersion, a variation in prices across sellers of the same item *Wage dispersion, the amount of variation in wages encountered in an economy *Dispersed knowledge, notion that any one person is unable to perceive all economic forces Science and mathematics Mathematics *Statistical dispersion, a quantifiable variation of measurements of differing members of a population **Index of dispersion, a normalized measure of the dispersion of a probability distribution *Dispersion point, a point in a topological space the removal of which leaves the space highly disconnected Physics *The dependence of wave velocity on frequency or wavelength: **Dispersion (optics), for light waves **Dispersion (water waves), for water waves **Acoustic dispersion, for sound waves **Dispersion relation, the mathematical description of dispersion in a system **Modal dis ...
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Attenuation Coefficient
The linear attenuation coefficient, attenuation coefficient, or narrow-beam attenuation coefficient characterizes how easily a volume of material can be penetrated by a beam of light, sound, particles, or other energy or matter. A coefficient value that is large represents a beam becoming 'attenuated' as it passes through a given medium, while a small value represents that the medium had little effect on loss. The SI unit of attenuation coefficient is the reciprocal metre (m−1). Extinction coefficient is another term for this quantity, often used in meteorology and climatology. Most commonly, the quantity measures the exponential decay of intensity, that is, the value of downward ''e''-folding distance of the original intensity as the energy of the intensity passes through a unit (''e.g.'' one meter) thickness of material, so that an attenuation coefficient of 1 m−1 means that after passing through 1 metre, the radiation will be reduced by a factor of '' e'', and for material ...
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Frequency
Frequency is the number of occurrences of a repeating event per unit of time. It is also occasionally referred to as ''temporal frequency'' for clarity, and is distinct from ''angular frequency''. Frequency is measured in hertz (Hz) which is equal to one event per second. The period is the interval of time between events, so the period is the reciprocal of the frequency. For example, if a heart beats at a frequency of 120 times a minute (2 hertz), the period, —the interval at which the beats repeat—is half a second (60 seconds divided by 120 beats). Frequency is an important parameter used in science and engineering to specify the rate of oscillatory and vibratory phenomena, such as mechanical vibrations, audio signals (sound), radio waves, and light. Definitions and units For cyclical phenomena such as oscillations, waves, or for examples of simple harmonic motion, the term ''frequency'' is defined as the number of cycles or vibrations per unit of time. Th ...
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Particle Size Distribution
The particle-size distribution (PSD) of a powder, or granular material, or particles dispersed in fluid, is a list of values or a mathematical function that defines the relative amount, typically by mass, of particles present according to size. Significant energy is usually required to disintegrate soil, etc. particles into the PSD that is then called a grain size distribution. Significance The PSD of a material can be important in understanding its physical and chemical properties. It affects the strength and load-bearing properties of rocks and soils. It affects the reactivity of solids participating in chemical reactions, and needs to be tightly controlled in many industrial products such as the manufacture of printer toner, cosmetics, and pharmaceutical products. Significance in the collection of particulate matter Particle size distribution can greatly affect the efficiency of any collection device. Settling chambers will normally only collect very large particles, those ...
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Heterogeneous
Homogeneity and heterogeneity are concepts often used in the sciences and statistics relating to the uniformity of a substance or organism. A material or image that is homogeneous is uniform in composition or character (i.e. color, shape, size, weight, height, distribution, texture, language, income, disease, temperature, radioactivity, architectural design, etc.); one that is heterogeneous is distinctly nonuniform in at least one of these qualities. Heterogeneous Mixtures, in chemistry, is where certain elements are unwillingly combined and, when given the option, will separate. Etymology and spelling The words ''homogeneous'' and ''heterogeneous'' come from Medieval Latin ''homogeneus'' and ''heterogeneus'', from Ancient Greek ὁμογενής (''homogenēs'') and ἑτερογενής (''heterogenēs''), from ὁμός (''homos'', “same”) and ἕτερος (''heteros'', “other, another, different”) respectively, followed by γένος (''genos'', “kind”); - ...
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Emulsion
An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms ''colloid'' and ''emulsion'' are sometimes used interchangeably, ''emulsion'' should be used when both phases, dispersed and continuous, are liquids. In an emulsion, one liquid (the dispersed phase) is dispersed in the other (the continuous phase). Examples of emulsions include vinaigrettes, homogenized milk, liquid biomolecular condensates, and some cutting fluids for metal working. Two liquids can form different types of emulsions. As an example, oil and water can form, first, an oil-in-water emulsion, in which the oil is the dispersed phase, and water is the continuous phase. Second, they can form a water-in-oil emulsion, in which water is the dispersed phase and oil is the continuous phase. Multiple emulsions are also pos ...
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Colloid
A colloid is a mixture in which one substance consisting of microscopically dispersed insoluble particles is suspended throughout another substance. Some definitions specify that the particles must be dispersed in a liquid, while others extend the definition to include substances like aerosols and gels. The term colloidal suspension refers unambiguously to the overall mixture (although a narrower sense of the word ''suspension'' is distinguished from colloids by larger particle size). A colloid has a dispersed phase (the suspended particles) and a continuous phase (the medium of suspension). The dispersed phase particles have a diameter of approximately 1 nanometre to 1 micrometre. Some colloids are translucent because of the Tyndall effect, which is the scattering of light by particles in the colloid. Other colloids may be opaque or have a slight color. Colloidal suspensions are the subject of interface and colloid science. This field of study was introduced in 1845 by Itali ...
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Acoustic Rheometer
An acoustic rheometer employs a piezo-electric crystal that can easily launch a successive wave of extensions and contractions into the fluid. It applies an oscillating extensional stress to the system. System response can be interpreted in terms of extensional rheology. :This interpretation is based on a link between shear rheology, extensional rheology and acoustics. Relationship between these scientific disciplines was described in details by Litovitz and Davis in 1964. It is well known that properties of viscoelastic fluid are characterised in shear rheology with a shear modulus ''G'', which links shear stress ''Tij'' and shear strain ''Sij'' :: There is similar linear relationship in extensional rheology between extensional stress ''P'', extensional strain ''S'' and extensional modulus ''K'': :: Detail theoretical analysis indicates that propagation of sound or ultrasound through a viscoelastic fluid depends on both shear modulus ''G'' and extensional modulus ''K' ...
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Extensional Viscosity
Extensional viscosity (also known as elongational viscosity) is a viscosity coefficient when applied stress is extensional stress. It is often used for characterizing polymer solutions. Extensional viscosity can be measured using rheometers that apply ''extensional stress''. Acoustic rheometer is one example of such devices. Extensional viscosity is defined as the ratio of the normal stress difference to the rate of strain. For uniaxial extension along direction z:Guyon, E., Hulin, JP. and Petit, L., Physical Hydrodynamics, Oxford University Press (2015), p113 :\eta_e = \frac\,\! where :\eta_e\,\! is the extensional viscosity or elongational viscosity :\sigma_\,\! is the normal stress along direction n. :\dot\,\! is the rate of strain: \dot = \frac\,\! The ratio between the extensional viscosity \eta_e and the dynamic viscosity \eta is known as Trouton's Ratio Tr = \eta_e/\eta. For a Newtonian Fluid, the Trouton ratio equals three. See also *Rheology Rheology (; ) is ...
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Volume Viscosity
Volume viscosity (also called bulk viscosity, or dilatational viscosity) is a material property relevant for characterizing fluid flow. Common symbols are \zeta, \mu', \mu_\mathrm, \kappa or \xi. It has dimensions (mass / (length × time)), and the corresponding International System of Units, SI unit is the Pascal (unit), pascal-second (Pa·s). Like other material properties (e.g. density, shear viscosity, and thermal conductivity) the value of volume viscosity is specific to each fluid and depends additionally on the fluid state, particularly its temperature and pressure. Physically, volume viscosity represents the irreversible resistance, over and above the reversible resistance caused by isentropic bulk modulus, to a compression or expansion of a fluid. At the molecular level, it stems from the finite time required for energy injected in the system to be distributed among the rotational and vibrational degrees of freedom of molecular motion. Knowledge of the volume viscosity is ...
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Acoustics
Acoustics is a branch of physics that deals with the study of mechanical waves in gases, liquids, and solids including topics such as vibration, sound, ultrasound and infrasound. A scientist who works in the field of acoustics is an acoustician while someone working in the field of acoustics technology may be called an Acoustical engineering, acoustical engineer. The application of acoustics is present in almost all aspects of modern society with the most obvious being the audio and noise control industries. Hearing (sense), Hearing is one of the most crucial means of survival in the animal world and speech is one of the most distinctive characteristics of human development and culture. Accordingly, the science of acoustics spreads across many facets of human society—music, medicine, architecture, industrial production, warfare and more. Likewise, animal species such as songbirds and frogs use sound and hearing as a key element of mating rituals or for marking territories. Art, ...
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