Tube-based Nanostructures
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Tube-based Nanostructures
Tube-based nanostructures are nanolattices made of connected tubes and exhibit nanoscale organization above the molecular level. Lattices Lattices are structures formed of arrays of uniformly sized cells. Ceramic lattice nanostructures have been formed using hollow tubes of titanium nitride (TiN). Using vertex-connected, tessellated octahedra with 7-nm hollow struts with elliptical cross-sections and wall thickness of 75-nm produced approximately cubic cells 100-nm on a side at a scale of up to 1 cubic millimeter. The material's relative density was of the order of 0.013 (similar to aerogels). Compression experiments with multiple deformation cycles revealed tensile strengths of 1.75 GPa without failure. The material was constructed from a digital design with direct laser writing onto a photopolymer using 2-photon lithography followed by conformal deposition of TiN using atomic layer deposition and a final etching to remove the polymer. An earlier metallic tube lattice produced ...
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Nanolattices
A nanolattice is a synthetic porous material consisting of nanometer-size members patterned into an ordered lattice structure, like a space frame. The nanolattice is a newly emerged material class that has been rapidly developed over the last decade. Nanolattices redefine the limits of the material property space. Despite being composed of 50-99% of air, nanolattices are very mechanically robust because they take advantage of size-dependent properties that we generally see in nanoparticles, nanowires, and thin films. The most typical mechanical properties of nanolattices include ultrahigh strength, damage tolerance, and high stiffness. Thus, nanolattices have a wide range of applications. Driven by the evolution of 3D printing techniques, nanolattices aiming to exploit beneficial material size effects through miniaturized lattice designs were first developed in the mid-2010s,. Nanolattices are the smallest man-made lattice truss structures and a class of metamaterials that derive ...
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Carbon Nanotube
A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nanotubes'' (''SWCNTs'') are one of the allotropes of carbon, intermediate between fullerene cages and flat graphene, with diameters in the range of a nanometre. Although not made this way, single-wall carbon nanotubes can be idealized as cutouts from a two-dimensional Hexagonal tiling, hexagonal lattice of carbon atoms rolled up along one of the Bravais lattice vectors of the hexagonal lattice to form a hollow cylinder. In this construction, periodic boundary conditions are imposed over the length of this roll-up vector to yield a helical lattice of seamlessly bonded carbon atoms on the cylinder surface. ''Multi-wall carbon nanotubes'' (''MWCNTs'') consisting of nested single-wall carbon nanotubes weakly bound together by van der Waals ...
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Condensed Matter Physics
Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid phases which arise from electromagnetic forces between atoms. More generally, the subject deals with "condensed" phases of matter: systems of many constituents with strong interactions between them. More exotic condensed phases include the superconducting phase exhibited by certain materials at low temperature, the ferromagnetic and antiferromagnetic phases of spins on crystal lattices of atoms, and the Bose–Einstein condensate found in ultracold atomic systems. Condensed matter physicists seek to understand the behavior of these phases by experiments to measure various material properties, and by applying the physical laws of quantum mechanics, electromagnetism, statistical mechanics, and other theories to develop mathematical models. The diversity of systems and phenomena available for study makes condensed matter phy ...
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Nanostructure
A nanostructure is a structure of intermediate size between microscopic and molecular structures. Nanostructural detail is microstructure at nanoscale. In describing nanostructures, it is necessary to differentiate between the number of dimensions in the volume of an object which are on the nanoscale. Nanotextured surfaces have ''one dimension'' on the nanoscale, i.e., only the thickness of the surface of an object is between 0.1 and 100 nm. Nanotubes have ''two dimensions'' on the nanoscale, i.e., the diameter of the tube is between 0.1 and 100 nm; its length can be far more. Finally, spherical nanoparticles have ''three dimensions'' on the nanoscale, i.e., the particle is between 0.1 and 100 nm in each spatial dimension. The terms nanoparticles and ultrafine particles (UFP) are often used synonymously although UFP can reach into the micrometre range. The term ''nanostructure'' is often used when referring to magnetic technology. Nanoscale structure in biology i ...
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Superlattice
A superlattice is a periodic structure of layers of two (or more) materials. Typically, the thickness of one layer is several nanometers. It can also refer to a lower-dimensional structure such as an array of quantum dots or quantum wells. Discovery Superlattices were discovered early in 1925 by Johansson and Linde after the studies on gold-copper and palladium-copper systems through their special X-ray diffraction patterns. Further experimental observations and theoretical modifications on the field were done by Bradley and Jay, Gorsky, Borelius, Dehlinger and Graf, Bragg and Williams and Bethe. Theories were based on the transition of arrangement of atoms in crystal lattices from disordered state to an ordered state. Mechanical properties J.S. Koehler theoretically predicted that by using alternate (nano-)layers of materials with high and low elastic constants, shearing resistance is improved by up to 100 times as the Frank–Read source of dislocations cannot operate in ...
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Nanolattice
A nanolattice is a synthetic porous material consisting of nanometer-size members patterned into an ordered lattice structure, like a space frame. The nanolattice is a newly emerged material class that has been rapidly developed over the last decade. Nanolattices redefine the limits of the material property space. Despite being composed of 50-99% of air, nanolattices are very mechanically robust because they take advantage of size-dependent properties that we generally see in nanoparticles, nanowires, and thin films. The most typical mechanical properties of nanolattices include ultrahigh strength, damage tolerance, and high stiffness. Thus, nanolattices have a wide range of applications. Driven by the evolution of 3D printing techniques, nanolattices aiming to exploit beneficial material size effects through miniaturized lattice designs were first developed in the mid-2010s,. Nanolattices are the smallest man-made lattice truss structures and a class of metamaterials that derive ...
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Tissue Engineering
Tissue engineering is a biomedical engineering discipline that uses a combination of Cell (biology), cells, engineering, Materials science, materials methods, and suitable biochemistry, biochemical and physicochemical factors to restore, maintain, improve, or replace different types of biology, biological tissues. Tissue engineering often involves the use of cells placed on tissue scaffolds in the formation of new viable tissue for a medical purpose but is not limited to applications involving cells and tissue scaffolds. While it was once categorized as a sub-field of biomaterials, having grown in scope and importance it can be considered as a field of its own. While most definitions of tissue engineering cover a broad range of applications, in practice the term is closely associated with applications that repair or replace portions of or whole tissues (i.e. bone, Autologous chondrocyte implantation, cartilage, blood vessels, Urinary bladder, bladder, skin, muscle etc.). Often, t ...
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Adhesion
Adhesion is the tendency of dissimilar particles or surfaces to cling to one another ( cohesion refers to the tendency of similar or identical particles/surfaces to cling to one another). The forces that cause adhesion and cohesion can be divided into several types. The intermolecular forces responsible for the function of various kinds of stickers and sticky tape fall into the categories of chemical adhesion, dispersive adhesion, and diffusive adhesion. In addition to the cumulative magnitudes of these intermolecular forces, there are also certain emergent mechanical effects. Surface energy Surface energy is conventionally defined as the work that is required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cleave a bulk sample, creating two surfaces. If the new surfaces are identical, the surface energy γ of each surface is equal to half the work of cleavage, W: γ = (1/2)W11. If the surfac ...
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Genipin
Genipin is a chemical compound found in ''Genipa americana'' fruit extract. It is an aglycone derived from an iridoid glycoside called geniposide which is also present in fruit of ''Gardenia jasminoides''. Genipin is an excellent natural cross-linker for proteins, collagen, gelatin, and chitosan cross-linking. It has a low acute toxicity, with i.v. 382 mg/kg in mice, therefore, much less toxic than glutaraldehyde and many other commonly used synthetic cross-linking reagents. Furthermore, genipin can be used as a regulating agent for drug delivery, as the raw material for gardenia blue pigment preparation, and as the intermediate for alkaloid syntheses. The blue color of genipin is stabilized in milk due to the natural pH of milk ''In vitro ''In vitro'' (meaning in glass, or ''in the glass'') studies are performed with microorganisms, cells, or biological molecules outside their normal biological context. Colloquially called "test-tube experiments", these studi ...
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Infrared Spectroscopy
Infrared spectroscopy (IR spectroscopy or vibrational spectroscopy) is the measurement of the interaction of infrared radiation with matter by absorption, emission, or reflection. It is used to study and identify chemical substances or functional groups in solid, liquid, or gaseous forms. It can be used to characterize new materials or identify and verify known and unknown samples. The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance) on the vertical axis vs. frequency, wavenumber or wavelength on the horizontal axis. Typical units of wavenumber used in IR spectra are reciprocal centimeters, with the symbol cm−1. Units of IR wavelength are commonly given in micrometers (formerly called "microns"), symbol μm, which are related to the wavenumber in a reciprocal way. A com ...
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Fourier Transform
A Fourier transform (FT) is a mathematical transform that decomposes functions into frequency components, which are represented by the output of the transform as a function of frequency. Most commonly functions of time or space are transformed, which will output a function depending on temporal frequency or spatial frequency respectively. That process is also called ''analysis''. An example application would be decomposing the waveform of a musical chord into terms of the intensity of its constituent pitches. The term ''Fourier transform'' refers to both the frequency domain representation and the mathematical operation that associates the frequency domain representation to a function of space or time. The Fourier transform of a function is a complex-valued function representing the complex sinusoids that comprise the original function. For each frequency, the magnitude (absolute value) of the complex value represents the amplitude of a constituent complex sinusoid with that ...
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Polyelectrolyte
Polyelectrolytes are polymers whose repeating units bear an electrolyte group. Ion#Anions and cations, Polycations and polyanions are polyelectrolytes. These groups dissociation (chemistry), dissociate in aqueous solutions (water), making the polymers charge (physics), charged. Polyelectrolyte properties are thus similar to both electrolytes (salts) and polymers (high molecular weight compounds) and are sometimes called polysalts. Like salts, their solutions are electrically conductive. Like polymers, their solutions are often viscosity, viscous. Charged molecular chains, commonly present in soft matter systems, play a fundamental role in determining structure, stability and the interactions of various molecular assemblies. Theoretical approaches to describing their statistical properties differ profoundly from those of their electrically neutral counterparts, while technological and industrial fields exploit their unique properties. Many biological molecules are polyelectrolytes. ...
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