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Titanium Powder
Titanium powder metallurgy (P/M) offers the possibility of creating net shape or near net shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the blended elemental technique or by pre-alloying and then consolidated by metal injection moulding, hot isostatic pressing, direct powder rolling or laser engineered net shaping. Blended elemental technique (BE) The traditional technique of titanium production is via the Kroll process which involves chlorination of TiO2 ore in the presence of carbon and reacting the resulting TiCl4 with magnesium to produce titanium sponge. These processes take place at temperatures as high as 1040 °C. The sponge particle range in size from 45 to 180 μm, with particles ~150 μm termed 'sponge fines'. These fines are irregularly shaped and porous with a sponge-like morphology. The fines are then blended with alloy additions; cold compacted into ...
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Titanium
Titanium is a chemical element with the symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine. Titanium was discovered in Cornwall, Great Britain, by William Gregor in 1791 and was named by Martin Heinrich Klaproth after the Titans of Greek mythology. The element occurs within a number of minerals, principally rutile and ilmenite, which are widely distributed in the Earth's crust and lithosphere; it is found in almost all living things, as well as bodies of water, rocks, and soils. The metal is extracted from its principal mineral ores by the Kroll and Hunter processes. The most common compound, titanium dioxide, is a popular photocatalyst and is used in the manufacture of white pigments. Other compounds include titanium tetrachloride (TiCl4), a component of smoke screens and catalysts; and ...
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Metal Injection Moulding
Metal injection molding (MIM) is a metalworking process in which finely-powdered metal is mixed with binder material to create a "feedstock" that is then shaped and solidified using injection molding. The molding process allows high volume, complex parts to be shaped in a single step. After molding, the part undergoes conditioning operations to remove the binder (debinding) and densify the powders. Finished products are small components used in many industries and applications. The behavior of MIM feedstock is governed by rheology, the study of sludges, suspensions, and other non-Newtonian fluids. Due to current equipment limitations, products must be molded using quantities of 100 grams or less per "shot" into the mold. This shot can be distributed into multiple cavities, making MIM cost-effective for small, intricate, high-volume products, which would otherwise be expensive to produce. MIM feedstock can be composed of a plethora of metals, but most common are stainle ...
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Hot Isostatic Pressing
Hot isostatic pressing (HIP) is a manufacturing process, used to reduce the porosity of metals and increase the density of many ceramic materials. This improves the material's mechanical properties and workability. The process can be used to produce waste form classes. Calcined radioactive waste (waste with additives) is packed into a thin walled metal canister. The adsorbed gases are removed with high heat and the remaining material compressed to full density using argon gas during the heat cycle. This process can shrink steel canisters to minimize space in disposal containers and during transport. It was invented in the 1950s at the Battelle Memorial Institute and has been used to prepare nuclear fuel for submarines since the 1960s. It is used to prepare inactive ceramics as well, and the Idaho National Laboratory has validated it for the consolidation of radioactive ceramic waste forms. ANSTO (Australian Nuclear Science and Technology Organisation) is using HIP as part of a ...
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Laser Engineered Net Shaping
Laser powder forming, also known by the proprietary name (laser engineered net shaping) is an additive manufacturing technology developed for fabricating metal parts directly from a computer-aided design (CAD) solid model by using a metal powder injected into a molten pool created by a focused, high-powered laser beam. This technique is also equivalent to several trademarked techniques that have the monikers direct metal deposition (DMD), and laser consolidation (LC). Compared to processes that use powder beds, such as selective laser melting (SLM) objects created with this technology can be substantially larger, even up to several feet long. Method A high power laser is used to melt metal powder supplied coaxially to the focus of the laser beam through a deposition head. The laser beam typically travels through the center of the head and is focused to a small spot by one or more lenses. The X-Y table is moved in raster fashion to fabricate each layer of the object. The head ...
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Kroll Process
The Kroll process is a pyrometallurgical industrial process used to produce metallic titanium from titanium tetrachloride. The Kroll process replaced the Hunter process for almost all commercial production. Process In the Kroll process, the TiCl4 is reduced by liquid magnesium to give titanium metal: :TiCl4 + 2Mg -> 25^oCi + 2MgCl2 The reduction is conducted at 800–850 °C in a stainless steel retort. Complications result from partial reduction of the TiCl4, giving to the lower chlorides TiCl2 and TiCl3. The MgCl2 can be further refined back to magnesium. The resulting porous metallic titanium sponge is purified by leaching or vacuum distillation. The sponge is crushed, and pressed before it is melted in a consumable carbon electrode vacuum arc furnace. The melted ingot is allowed to solidify under vacuum. It is often remelted to remove inclusions and ensure uniformity. These melting steps add to the cost of the product. Titanium is about six times as expensive as ...
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Selective Laser Sintering
Selective laser sintering (SLS) is an additive manufacturing (AM) technique that uses a laser as the power and heat source to sinter powdered material (typically nylon or polyamide), aiming the laser automatically at points in space defined by a 3D model, binding the material together to create a solid structure. It is similar to selective laser melting; the two are instantiations of the same concept but differ in technical details. SLS (as well as the other mentioned AM techniques) is a relatively new technology that so far has mainly been used for rapid prototyping and for low-volume production of component parts. Production roles are expanding as the commercialization of AM technology improves. History Selective laser sintering (SLS) was developed and patented by Dr. Carl Deckard and academic adviser, Dr. Joe Beaman at the University of Texas at Austin in the mid-1980s, under sponsorship of DARPA. Deckard and Beaman were involved in the resulting start up company DTM, e ...
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Spark Plasma Sintering
Spark plasma sintering (SPS), also known as field assisted sintering technique (FAST) or pulsed electric current sintering (PECS), or plasma pressure compaction (P2C) is a sintering technique. The main characteristic of SPS is that the pulsed or unpulsed DC or AC current directly passes through the graphite die, as well as the powder compact, in case of conductive samples. Joule heating has been found to play a dominant role in the densification of powder compacts, which results in achieving near theoretical density at lower sintering temperature compared to conventional sintering techniques. The heat generation is internal, in contrast to the conventional hot pressing, where the heat is provided by external heating elements. This facilitates a very high heating or cooling rate (up to 1000 K/min), hence the sintering process generally is very fast (within a few minutes). The general speed of the process ensures it has the potential of densifying powders with nanosize or nanostruc ...
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Titanium Sponge Plant In India
Titanium Sponge Plant of India is located at Kerala Minerals and Metals Ltd (Kerala Minerals and Metals, KMML), Chavara, Kollam district of Kerala. Titanium sponge plant is a manufacturing plant which produces titanium sponge, a material which has very useful applications in space programme and other strategic areas like aeronautics, light defence vehicles etc. The plant in India is the only one in the world which can undertake all the different activities of manufacturing aerospace grade titanium sponge under one roof. The material is an alloy product which is produced through Kroll process which includes leaching or heated vacuum distillation to make the metal almost 99.7% pure. History The importance of establishing the Titanium Sponge Plant was realised keeping in view of the country's huge demand and import of titanium and magnesium alloys from countries like China, Russia and Japan. Former President of India and scientist, Dr A. P. J. Abdul Kalam, APJ Abdul Kalam highlighted ab ...
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Metallurgical Processes
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist. The science of metallurgy is further subdivided into two broad categories: chemical metallurgy and physical metallurgy. Chemical metallurgy is chiefly concerned with the reduction and oxidation of metals, and the chemical performance of metals. Subjects of study in chemical metallurgy include mi ...
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