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Surface Rheology
{{more references, date=November 2011 Surface rheology is a description of the rheological properties of a free surface. When perfectly pure, the interface between fluids usually displays only surface tension. But when surfactants are adsorbed on the interface, because they lower the surface tension, the stress within the interface is affected by the flow for several reasons. * Change in the surface concentration of surfactants when the in-plane flow tends to alter the surface area of the interface (Gibbs' elasticity). * Adsorption/desorption of the surfactants to/from the interface. Importance of surface rheology The mechanical properties (rheology) of dispersed media such as liquid foams and emulsions is strongly affected by surface rheology. Indeed, when they consist of two (or more) fluid phases, deforming the material implies deforming the constitutive phases ( bubbles, drops) and thus their interfaces. The measurement of surface rheological properties is described by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rheology
Rheology (; ) is the study of the flow of matter, primarily in a fluid ( liquid or gas) state, but also as "soft solids" or solids under conditions in which they respond with plastic flow rather than deforming elastically in response to an applied force. Rheology is a branch of physics, and it is the science that deals with the deformation and flow of materials, both solids and liquids.W. R. Schowalter (1978) Mechanics of Non-Newtonian Fluids Pergamon The term ''rheology'' was coined by Eugene C. Bingham, a professor at Lafayette College, in 1920, from a suggestion by a colleague, Markus Reiner.The Deborah Number The term was inspired by the of |
Free Surface
In physics, a free surface is the surface of a fluid that is subject to zero parallel shear stress, such as the interface between two homogeneous fluids. An example of two such homogeneous fluids would be a body of water (liquid) and the air in the Earth's atmosphere (gas mixture). Unlike liquids, gases cannot form a free surface on their own. Fluidized/liquified solids, including slurries, granular materials, and powders may form a free surface. A liquid in a gravitational field will form a free surface if unconfined from above. Under mechanical equilibrium this free surface must be perpendicular to the forces acting on the liquid; if not there would be a force along the surface, and the liquid would flow in that direction. Thus, on the surface of the Earth, all free surfaces of liquids are horizontal unless disturbed (except near solids dipping into them, where surface tension distorts the surface in a region called the meniscus). In a free liquid that is not affected by ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Interface Between Fluids
In the physical sciences, an interface is the boundary between two spatial regions occupied by different matter, or by matter in different physical states. The interface between matter and air, or matter and vacuum, is called a surface, and studied in surface science. In thermal equilibrium, the regions in contact are called phases, and the interface is called a phase boundary. An example for an interface out of equilibrium is the grain boundary in polycrystalline matter. The importance of the interface depends on the type of system: the bigger the quotient area/volume, the greater the effect the interface will have. Consequently, interfaces are very important in systems with large interface area-to-volume ratios, such as colloids. Interfaces can be flat or curved. For example, oil droplets in a salad dressing are spherical but the interface between water and air in a glass of water is mostly flat. Surface tension is the physical property which rules interface processes invol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Tension
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play. One is an inward force on the surface molecules causing the liquid to contract. Second is a tangential force parallel to the surface of the liquid. This ''tangential'' force is generally referred to as the surface tension. The net effect is the liquid behaves as if its surface were covered with a stretched elastic membrane. But this analogy must not be taken too far as the tension in an elastic membrane is dependent on the amount of deformation of the m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surfactant
Surfactants are chemical compounds that decrease the surface tension between two liquids, between a gas and a liquid, or interfacial tension between a liquid and a solid. Surfactants may act as detergents, wetting agents, emulsifiers, foaming agents, or dispersants. The word "surfactant" is a blend of ''surface-active agent'', coined . Agents that increase surface tension are "surface active" in the literal sense but are not called surfactants as their effect is opposite to the common meaning. A common example of surface tension increase is salting out: by adding an inorganic salt to an aqueous solution of a weakly polar substance, the substance will precipitate. The substance may itself be a surfactant – this is one of the reasons why many surfactants are ineffective in sea water. Composition and structure Surfactants are usually organic compounds that are amphiphilic, meaning each molecule contains both a hydrophilic "water-seeking" group (the ''head''), and a hydro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Adsorption
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). Adsorption is a '' surface phenomenon'', while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term ''sorption'' encompasses both processes, while ''desorption'' is the reverse of it. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in the material. However, atoms on the surface of the adsorbent are not wholly surrounded by other adsorbent atoms and therefore can attract adsorbates. The exact nature of the bon ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Desorption
Desorption is the physical process where a previously adsorbed substance is released from a surface. This happens when a molecule gains enough energy to overcome the activation barrier of the bounding energy that keeps it in the surface. There are a lot of different types of desorption, depending on the mechanism that separates the adsorbate from the substrate; therefore there is no one equation that describes the process. Note that desorption is the opposite of adsorption, which differs from absorption because it refers to substances being stuck to the surface, as opposed to being absorbed into the bulk. Desorption can occur after a reaction between a catalyst and an adsorbed compound; or during stripping or chromatography which are types of separation processes. Desorption mechanisms Depending on the nature of the adsorbent-to-surface bond, there are a multitude of mechanisms for desorption. The surface bond of a sorbant can be cleaved thermally, through chemical react ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dispersed Media
A dispersed medium consists of two media that do not mix. More specifically, it contains discrete elements of one medium which are dispersed in a continuous second medium. The two media can be of very different nature. In particular, they can be a gas, a liquid or a solid. Many materials which we encounter during the day are dispersed media. For example, milk consists of oil drops dispersed in water, fog contains tiny water drops dispersed in air, shaving cream contains bubbles dispersed in a liquid, sand consists of solid grains in air and a kitchen sponge of bubbles dispersed in a solid. Dispersed media are commonly classified according to the nature of the two media and the volume fraction of the dispersed medium. At very low volume fraction the dispersed objects are not in contact with each other. At intermediate volume fraction they start to be in contact (they jam). And at even higher volume fraction, the dispersed objects deform in a tight packing. Another classification ta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Foams
Foams are materials formed by trapping pockets of gas in a liquid or solid. A bath sponge and the head on a glass of beer are examples of foams. In most foams, the volume of gas is large, with thin films of liquid or solid separating the regions of gas. Soap foams are also known as suds. Solid foams can be closed-cell or open-cell. In closed-cell foam, the gas forms discrete pockets, each completely surrounded by the solid material. In open-cell foam, gas pockets connect to each other. A bath sponge is an example of an open-cell foam: water easily flows through the entire structure, displacing the air. A sleeping mat is an example of a closed-cell foam: gas pockets are sealed from each other so the mat cannot soak up water. Foams are examples of dispersed media. In general, gas is present, so it divides into gas bubbles of different sizes (i.e., the material is polydisperse)—separated by liquid regions that may form films, thinner and thinner when the liquid phase drain ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Emulsions
An emulsion is a mixture of two or more liquids that are normally immiscible (unmixable or unblendable) owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms ''colloid'' and ''emulsion'' are sometimes used interchangeably, ''emulsion'' should be used when both phases, dispersed and continuous, are liquids. In an emulsion, one liquid (the dispersed phase) is dispersed in the other (the continuous phase). Examples of emulsions include vinaigrettes, homogenized milk, liquid biomolecular condensates, and some cutting fluids for metal working. Two liquids can form different types of emulsions. As an example, oil and water can form, first, an oil-in-water emulsion, in which the oil is the dispersed phase, and water is the continuous phase. Second, they can form a water-in-oil emulsion, in which water is the dispersed phase and oil is the continuous phase. Multiple emulsions are also pos ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Soap Bubbles
A soap bubble is an extremely thin film of soap or detergent and water enclosing air that forms a hollow sphere with an iridescent surface. Soap bubbles usually last for only a few seconds before bursting, either on their own or on contact with another object. They are often used for children's enjoyment, but they are also used in artistic performances. Assembling many bubbles results in foam. When light shines onto a bubble it appears to change colour. Unlike those seen in a rainbow, which arise from differential refraction, the colours seen in a soap bubble arise from light wave interference, reflecting off the front and back surfaces of the thin soap film. Depending on the thickness of the film, different colours interfere constructively and destructively. Mathematics Soap bubbles are physical examples of the complex mathematical problem of minimal surface. They will assume the shape of least surface area possible containing a given volume. A true minimal surface i ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Drop (liquid)
A drop or droplet is a small column of liquid, bounded completely or almost completely by free surfaces. A drop may form when liquid accumulates at the lower end of a tube or other surface boundary, producing a hanging drop called a pendant drop. Drops may also be formed by the condensation of a vapor or by atomizer nozzle, atomization of a larger mass of solid. Water vapor will condense into droplets depending on the temperature. The temperature at which droplets form is called the dew point. Surface tension Liquid forms drops because it exhibits surface tension. A simple way to form a drop is to allow liquid to flow slowly from the lower end of a vertical tube of small diameter. The surface tension of the liquid causes the liquid to hang from the tube, forming a pendant. When the drop exceeds a certain size it is no longer stable and detaches itself. The falling liquid is also a drop held together by surface tension. Viscosity and pitch drop experiments Some substa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
