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Shell Higher Olefin Process
The Shell higher olefin process (SHOP) is a chemical process for the production of linear alpha olefins via ethylene oligomerization and olefin metathesis invented and exploited by Royal Dutch Shell.''Industrial Organic Chemistry'', Klaus Weissermel, Hans-Jurgen Arpe John Wiley & Sons; 3rd 1997 The olefin products are converted to fatty aldehydes and then to fatty alcohols, which are precursors plasticizers and detergents. The annual global production of olefines through this method is over one million tonnes.Keim, W. (2013), ''Oligomerization of Ethylene to α-Olefins: Discovery and Development of the Shell Higher Olefin Process (SHOP)''. Angew. Chem. Int. Ed., 52: 12492–12496. History The process was discovered by chemists at Shell Development Emeryville in 1968. At the time ecological considerations demanded the replacement of branched fatty alcohols used widely in detergents, by linear fatty alcohols because the biodegradation of the branched compounds was slow, causing f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chemical Process
In a scientific sense, a chemical process is a method or means of somehow changing one or more chemicals or chemical compounds. Such a chemical process can occur by itself or be caused by an outside force, and involves a chemical reaction of some sort. In an "engineering" sense, a chemical process is a method intended to be used in manufacturing or on an industrial scale (see Industrial process) to change the composition of chemical(s) or material(s), usually using technology similar or related to that used in chemical plants or the chemical industry. Neither of these definitions are exact in the sense that one can always tell definitively what is a chemical process and what is not; they are practical definitions. There is also significant overlap in these two definition variations. Because of the inexactness of the definition, chemists and other scientists use the term "chemical process" only in a general sense or in the engineering sense. However, in the "process (engineer ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ethenolysis
In organic chemistry, ethenolysis is a chemical process in which internal olefins are degraded using ethylene () as the reagent. The reaction is an example of cross metathesis. The utility of the reaction is driven by the low cost of ethylene as a reagent and its selectivity. It produces compounds with terminal alkene functional groups (α-olefins), which are more amenable to other reactions such as polymerization and hydroformylation. The general reaction equation is: :\ce + \longrightarrow \ce + \ce Ethenolysis is a form of methylenation, i.e., the installation of methylene () groups. Applications Using ethenolysis, higher molecular weight internal alkenes can be converted to more valuable terminal alkenes. The Shell higher olefin process (SHOP process) uses ethenolysis on an industrial scale. The SHOP α-olefin mixtures are separated by distillation, the higher molecular weight fractions are isomerized by alkaline alumina catalysts in the liquid phase. The resulti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogenation
Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate organic compounds. Hydrogenation typically constitutes the addition of pairs of hydrogen atoms to a molecule, often an alkene. Catalysts are required for the reaction to be usable; non-catalytic hydrogenation takes place only at very high temperatures. Hydrogenation reduces double and triple bonds in hydrocarbons. Process Hydrogenation has three components, the unsaturated substrate, the hydrogen (or hydrogen source) and, invariably, a catalyst. The reduction reaction is carried out at different temperatures and pressures depending upon the substrate and the activity of the catalyst. Related or competing reactions The same catalysts and conditions that are used for hydrogenation reactions can also lead to isomerization of the alkenes fr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cyclododecatriene
Cyclododecatrienes are cyclic trienes with the formula C12H18. Four isomers are known for 1,5,9-cyclododecatriene. The ''trans'',''trans'',''cis''-isomer is a precursor in the production of nylon-12. : Production The ''trans'',''trans'',''cis''-isomer is obtained by cyclotrimerization of butadiene catalyzed by a mixture of titanium tetrachloride and an organoaluminium co-catalyst. Production capacity in 1995 was 8000 tons. : As aforementioned, titanium catalysts predominantly produce the important ''cis'',''trans'',''trans''- isomer. The all-''trans'' isomer is, however, the product from nickel- and chromium-catalyzed trimerization reactions. The yield of cyclododecatriene through these methods is often greater than 80%. The principal side products are the dimers and oligomers of butadiene. Properties All of the isomers of 1,5,9-cyclododecatriene are colorless, possess typical terpene-like odors, and have low melting points. The all-''trans'' isomer melts at 34 °C while th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
SHOP
Shop or shopping refers to: Business and commerce * A casual word for a commercial establishment or for a place of business * Machine shop, a workshop for machining *"In the shop", referring to a car being at an automotive repair shop *A wood shop * Retail shop, possibly within a marketplace * Shopping, e.g.: ** Christmas shopping ** Comparison shopping ** Grocery shopping ** Online shopping ** Window shopping Arts, entertainment, and media * ''The Shop'', an American television talk show * "Shops", an essay by the Hong Kong writer Xi Xi * The Shop, a fictional government agency which appears in various works by Stephen King, including '' Firestarter'' and '' Golden Years'' * The Shoppe, an American country music group * The Shopping Channel, a Canadian home shopping channel * "Shop", a track from the soundtrack of the 2015 video game ''Undertale'' by Toby Fox Brands and enterprises * SHoP Architects, a New York-based architectural firm * Shop.ca, a Canadian online e- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Google Books
Google Books (previously known as Google Book Search, Google Print, and by its code-name Project Ocean) is a service from Google Inc. that searches the full text of books and magazines that Google has scanned, converted to text using optical character recognition (OCR), and stored in its digital database.The basic Google book link is found at: https://books.google.com/ . The "advanced" interface allowing more specific searches is found at: https://books.google.com/advanced_book_search Books are provided either by publishers and authors through the Google Books Partner Program, or by Google's library partners through the Library Project. Additionally, Google has partnered with a number of magazine publishers to digitize their archives. The Publisher Program was first known as Google Print when it was introduced at the Frankfurt Book Fair in October 2004. The Google Books Library Project, which scans works in the collections of library partners and adds them to the digital inve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
RWTH Aachen
RWTH Aachen University (), also known as North Rhine-Westphalia Technical University of Aachen, Rhine-Westphalia Technical University of Aachen, Technical University of Aachen, University of Aachen, or ''Rheinisch-Westfälische Technische Hochschule Aachen'', is a German public research university located in Aachen, North Rhine-Westphalia, Germany. With more than 47,000 students enrolled in 144 study programs, it is the largest technical university in Germany. In 2018, the university was ranked 31st in the world university rankings in the field of engineering and technology, and 36th world-wide in the category of natural sciences.Daten & Fakten – RWTH AACHEN UNIVERSITY – Deutsch Rwth-aachen.de (12 December 2011). Retrieved on 2013-09-18. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Wilhelm Keim
Wilhelm Keim (1 December 1934 – 30 September 2018) was a German chemist and professor of chemistry at the Technical Chemistry and former director of the ''Institute for Technical and Petrol Chemistry'' at RWTH Aachen in Germany. Wilhelm Keim was one of the key figures in the development of the ''SHOP'' – process (Shell higher olefin process). SHOP-olefines have a broad range of applications in industrial chemistry, e.g. for the modification of polyethylene as ethylene-alpha-olefine-copolymere, as source for synthetic fatty alcohols or olefine sulfonates. : He studied chemistry at the Münster and Saarbrücken University. He earned his PhD degree from Max Planck Institute for Coal Research in Mülheim an der Ruhr, having studied under Karl Ziegler. After several years in the chemical industry he became professor at the RWTH Aachen, where he was the director of the Institute for Technical and Petrol chemistry. He retired in 2001. Keim has received numerous prestigious honour ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dalton Trans
''Dalton Transactions'' is a peer-reviewed scientific journal publishing original (primary) research and review articles on all aspects of the chemistry of inorganic, bioinorganic, and organometallic compounds. It is published weekly by the Royal Society of Chemistry. The journal was named after the English chemist, John Dalton, best known for his work on modern atomic theory. Authors can elect to have accepted articles published as open access. The editor is Andrew Shore. ''Dalton Transactions'' was named a "rising star" by ''In-cites'' from Thomson Scientific in 2006. Publication history The journal was established as the ''Journal of the Chemical Society A: Inorganic, Physical, Theoretical'' in 1966. In 1972, the journal was divided into three separate journals: ''Journal of the Chemical Society, Dalton Transactions'' (covering inorganic and organometallic chemistry), '' Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases'', ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphine
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula , classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (). With traces of present, is spontaneously flammable in air ( pyrophoric), burning with a luminous flame. Phosphine is a highly toxic respiratory poison, and is immediately dangerous to life or health at 50 ppm. Phosphine has a trigonal pyramidal structure. Phosphines are compounds that include and the organophosphines, which are derived from by substituting one or more hydrogen atoms with organic groups. They have the general formula . Phosphanes are saturated phosphorus hydrides of the form , such as triphosphane. Phosphine, PH3, is the smallest of the phosphines and the smallest of the phosphanes. History Philippe Gengembre (1764–1838), a student of Lavois ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nickel
Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow to react with air under standard conditions because a passivation layer of nickel oxide forms on the surface that prevents further corrosion. Even so, pure native nickel is found in Earth's crust only in tiny amounts, usually in ultramafic rocks, and in the interiors of larger nickel–iron meteorites that were not exposed to oxygen when outside Earth's atmosphere. Meteoric nickel is found in combination with iron, a reflection of the origin of those elements as major end products of supernova nucleosynthesis. An iron–nickel mixture is thought to compose Earth's outer and inner cores. Use of nickel (as natural meteoric nickel–iron alloy) has been traced as far back as 3500 BCE. Nickel was first isolated and classified a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oligomerization
In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relative molecular mass, the structure of which essentially comprises a small plurality of units derived, actually or conceptually, from molecules of lower relative molecular mass.'' The name is composed of Greek elements '' oligo-'', "a few" and ''-mer'', "parts". An adjective form is ''oligomeric''. The oligomer concept is contrasted to that of a polymer, which is usually understood to have a large number of units, possibly thousands or millions. However, there is no sharp distinction between these two concepts. One proposed criterion is whether the molecule's properties vary significantly with the removal of one or a few of the units. An oligomer with a specific number of units is referred to by the Greek prefix denoting that number, wit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
