In a
scientific
Science is a systematic endeavor that builds and organizes knowledge in the form of testable explanations and predictions about the universe.
Science may be as old as the human species, and some of the earliest archeological evidence ...
sense, a chemical process is a method or means of somehow changing one or more
chemical
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., wit ...
s or
chemical compound
A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one ele ...
s. Such a chemical process can occur by itself or be caused by an outside force, and involves a
chemical reaction
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and break ...
of some sort. In an "
engineering
Engineering is the use of scientific method, scientific principles to design and build machines, structures, and other items, including bridges, tunnels, roads, vehicles, and buildings. The discipline of engineering encompasses a broad rang ...
" sense, a chemical process is a method intended to be used in
manufacturing
Manufacturing is the creation or production of goods with the help of equipment, labor, machines, tools, and chemical or biological processing or formulation. It is the essence of secondary sector of the economy. The term may refer to a ...
or on an industrial scale (see
Industrial process) to change the composition of chemical(s) or material(s), usually using technology similar or related to that used in
chemical plants or the
chemical industry
The chemical industry comprises the companies that produce industrial chemicals. Central to the modern world economy, it converts raw materials ( oil, natural gas, air, water, metals, and minerals) into more than 70,000 different products. T ...
.
Neither of these definitions are exact in the sense that one can always tell definitively what is a chemical process and what is not; they are practical definitions. There is also significant overlap in these two definition variations. Because of the inexactness of the definition, chemists and other scientists use the term "chemical process" only in a general sense or in the engineering sense. However, in the "process (engineering)" sense, the term "chemical process" is used extensively. The rest of the article will cover the engineering type of chemical processes.
Although this type of chemical process may sometimes involve only one step, often multiple steps, referred to as
unit operations, are involved. In a
plant
Plants are predominantly Photosynthesis, photosynthetic eukaryotes of the Kingdom (biology), kingdom Plantae. Historically, the plant kingdom encompassed all living things that were not animals, and included algae and fungi; however, all curr ...
, each of the unit operations commonly occur in individual vessels or sections of the plant called units. Often, one or more
chemical reaction
A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and break ...
s are involved, but other ways of changing chemical (or material) composition may be used, such as
mixing or
separation processes. The process steps may be sequential in time or sequential in space along a stream of flowing or moving material; see
Chemical plant. For a given amount of a feed (input) material or product (output) material, an expected amount of material can be determined at key steps in the process from empirical data and material balance calculations. These amounts can be scaled up or down to suit the desired capacity or operation of a particular chemical plant built for such a process. More than one chemical plant may use the same chemical process, each plant perhaps at differently scaled capacities.
Chemical processes like
distillation
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the he ...
and
crystallization go back to
alchemy
Alchemy (from Arabic: ''al-kīmiyā''; from Ancient Greek: χυμεία, ''khumeía'') is an ancient branch of natural philosophy, a philosophical and protoscientific tradition that was historically practiced in China, India, the Muslim world ...
in
Alexandria
Alexandria ( or ; ar, ٱلْإِسْكَنْدَرِيَّةُ ; grc-gre, Αλεξάνδρεια, Alexándria) is the second largest city in Egypt, and the largest city on the Mediterranean coast. Founded in by Alexander the Great, Alexandr ...
,
Egypt
Egypt ( ar, مصر , ), officially the Arab Republic of Egypt, is a transcontinental country spanning the northeast corner of Africa and southwest corner of Asia via a land bridge formed by the Sinai Peninsula. It is bordered by the Med ...
.
Such chemical processes can be illustrated generally as
block flow diagrams or in more detail as
process flow diagrams. Block flow diagrams show the units as blocks and the streams flowing between them as connecting lines with arrowheads to show direction of flow.
In addition to chemical plants for producing chemicals, chemical processes with similar technology and equipment are also used in
oil refining and other
refineries,
natural gas processing,
polymer
A polymer (; Greek ''poly-'', "many" + '' -mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...
and
pharmaceutical manufacturing,
food processing
Food processing is the transformation of agricultural products into food, or of one form of food into other forms. Food processing includes many forms of processing foods, from grinding grain to make raw flour to home cooking to complex industr ...
, and
water
Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
and
wastewater treatment.
Unit processing in chemical process
Unit processing is the basic processing in
chemical engineering
Chemical engineering is an engineering field which deals with the study of operation and design of chemical plants as well as methods of improving production. Chemical engineers develop economical commercial processes to convert raw materials in ...
. Together with
unit operations it forms the main principle of the varied chemical industries. Each genre of unit processing follows the same chemical law much as each genre of
unit operations follows the same physical law.
Chemical engineering unit processing consists of the following important processes:
*
Oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...
*
Reduction
*
Hydrogenation
Hydrogenation is a chemical reaction between molecular hydrogen (H2) and another compound or element, usually in the presence of a catalyst such as nickel, palladium or platinum. The process is commonly employed to reduce or saturate org ...
*
Dehydrogenation
*
Hydrolysis
Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.
Biological hydrolysis ...
*
Hydration
*
Dehydration
*
Halogenation
*
Nitrification
*
Sulfonation
*
Amination
*
Alkylation
Alkylation is the transfer of an alkyl group from one molecule to another. The alkyl group may be transferred as an alkyl carbocation, a free radical, a carbanion, or a carbene (or their equivalents). Alkylating agents are reagents for effectin ...
*
Dealkylation
*
Esterification
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glyceride ...
*
Polymerization
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many fo ...
*
Polycondensation
*
Catalysis
Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycl ...
Academic research institutes in process chemistry
Institute of Process Research & Development University of Leeds
See also
*
Chemical plant
*
Foam fractionation
*
Industrial process
*
Process (engineering)
{{DEFAULTSORT:Chemical Process
Secondary sector of the economy
Industrial processes