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Superhydrophobic Coating
A superhydrophobic coating is a thin surface layer that repels water. It is made from superhydrophobic ( ultrahydrophobicity) materials. Droplets hitting this kind of coating can fully rebound.Richard, Denis, Christophe Clanet, and David Quéré. "Surface phenomena: Contact time of a bouncing drop." Nature 417.6891 (2002): 811-811Yahua Liu, Lisa Moevius, Xinpeng Xu,Tiezheng Qian, Julia M Yeomans, Zuankai Wang. "Pancake bouncing on superhydrophobic surfaces." Nature Physics, 10, 515-519 (2014) Generally speaking, superhydrophobic coatings are made from composite materials where one component provides the roughness and the other provides low surface energy. Material used Superhydrophobic coatings can be made from many different materials. The following are known possible bases for the coating: * Manganese oxide polystyrene (MnO2/PS) nano-composite * Zinc oxide polystyrene (ZnO/PS) nano-composite * Precipitated calcium carbonate * Carbon nano-tube structures * Silica nano-c ...
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Ultrahydrophobicity
Ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing. Theory In 1805, Thomas Young defined the contact angle ''θ'' by analysing the forces acting on a fluid droplet resting on a smooth solid surface surrounded by a gas. :\gamma_\ =\gamma_+\gamma_\cos where :\gamma_\ = Interfacial tension between the solid and gas :\gamma_\ = Interfacial tension between the solid and liquid :\gamma_\ = Interfacial tension between the liquid and gas ''θ'' can be measured using a contact angle goniometer. Wenzel ...
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Brine
Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for brining foods) up to about 26% (a typical saturated solution, depending on temperature). Brine forms naturally due to evaporation of ground saline water but it is also generated in the mining of sodium chloride. Brine is used for food processing and cooking (pickling and brining), for de-icing of roads and other structures, and in a number of technological processes. It is also a by-product of many industrial processes, such as desalination, so it requires wastewater treatment for proper disposal or further utilization (fresh water recovery). In nature Brines are produced in multiple ways in nature. Modification of seawater via evaporation results in the concentration of salts in the residual fluid, a characteristic geologic deposit call ...
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Non-stick Surface
A non-stick surface is engineered to reduce the ability of other materials to stick to it. Non-stick cookware is a common application, where the non-stick coating allows food to brown without sticking to the pan. Non-stick is often used to refer to surfaces coated with polytetrafluoroethylene (PTFE), a well-known brand of which is Teflon. In the twenty-first century, other coatings have been marketed as non-stick, such as anodized aluminium, silica, enameled cast iron, and seasoned cookware. Types Seasoning Cast iron, carbon steel, stainless steel and cast aluminium cookware may be seasoned before cooking by applying a fat to the surface and heating it to polymerize it. This produces a dry, hard, smooth, hydrophobic coating, which is non-stick when food is cooked with a small amount of cooking oil or fat. Fluoropolymer The modern non-stick pans were made using a coating of Teflon (polytetrafluoroethylene or PTFE). PTFE was invented serendipitously by Roy Plunkett in 1938, ...
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Ultrahydrophobicity
Ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing. Theory In 1805, Thomas Young defined the contact angle ''θ'' by analysing the forces acting on a fluid droplet resting on a smooth solid surface surrounded by a gas. :\gamma_\ =\gamma_+\gamma_\cos where :\gamma_\ = Interfacial tension between the solid and gas :\gamma_\ = Interfacial tension between the solid and liquid :\gamma_\ = Interfacial tension between the liquid and gas ''θ'' can be measured using a contact angle goniometer. Wenzel ...
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Hydrophobe
In chemistry, hydrophobicity is the physical property of a molecule that is seemingly repelled from a mass of water (known as a hydrophobe). In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to be nonpolar and, thus, prefer other neutral molecules and nonpolar solvents. Because water molecules are polar, hydrophobes do not dissolve well among them. Hydrophobic molecules in water often cluster together, forming micelles. Water on hydrophobic surfaces will exhibit a high contact angle. Examples of hydrophobic molecules include the alkanes, oils, fats, and greasy substances in general. Hydrophobic materials are used for oil removal from water, the management of oil spills, and chemical separation processes to remove non-polar substances from polar compounds. Hydrophobic is often used interchangeably with lipophilic, "fat-loving". However, the two terms are not synonymous. While hydrophobic substances are usually lipophilic, there are exceptions, suc ...
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Biomimetics
Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from grc, βίος (''bios''), life, and μίμησις ('' mīmēsis''), imitation, from μιμεῖσθαι (''mīmeisthai''), to imitate, from μῖμος (''mimos''), actor. A closely related field is bionics. Living organisms have evolved well-adapted structures and materials over geological time through natural selection. Biomimetics has given rise to new technologies inspired by biological solutions at macro and nanoscales. Humans have looked at nature for answers to problems throughout their existence. Nature has solved engineering problems such as self-healing abilities, environmental exposure tolerance and resistance, hydrophobicity, self-assembly, and harnessing solar energy. History One of the early examples of biomimicry was the study of birds to enable human flight. Alth ...
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Plant Cuticle
A plant cuticle is a protecting film covering the outermost skin layer (epidermis) of leaves, young shoots and other aerial plant organs (aerial here meaning all plant parts not embedded in soil or other substrate) that have no ''periderm''. The film consists of lipid and hydrocarbon polymers impregnated with wax, and is synthesized exclusively by the epidermal cells. Kolattukudy, PE (1996) Biosynthetic pathways of cutin and waxes, and their sensitivity to environmental stresses. In: Plant Cuticles. Ed. by G. Kerstiens, BIOS Scientific publishers Ltd., Oxford, pp 83-108 Description The plant cuticle is a layer of lipid polymers impregnated with waxes that is present on the outer surfaces of the primary organs of all vascular land plants. It is also present in the sporophyte generation of hornworts, and in both sporophyte and gametophyte generations of mosses The plant cuticle forms a coherent outer covering of the plant that can be isolated intact by treating plant tissue with ...
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Lotus Effect
The lotus effect refers to self-cleaning properties that are a result of ultrahydrophobicity as exhibited by the leaves of ''Nelumbo'', the lotus flower. Dirt particles are picked up by water droplets due to the micro- and nanoscopic architecture on the surface, which minimizes the droplet's adhesion to that surface. Ultrahydrophobicity and self-cleaning properties are also found in other plants, such as ''Tropaeolum'' (nasturtium), ''Opuntia'' (prickly pear), ''Alchemilla'', cane, and also on the wings of certain insects. The phenomenon of ultrahydrophobicity was first studied by Dettre and Johnson in 1964 using rough hydrophobic surfaces. Their work developed a theoretical model based on experiments with glass beads coated with paraffin or Polytetrafluoroethylene, PTFE fluorotelomer, telomer. The self-cleaning property of ultrahydrophobic micro-nanotechnology, nanostructured surfaces was studied by Wilhelm Barthlott and Ehler in 1977, who described such self-cleaning and ultr ...
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Polytetrafluoroethylene
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from DuPont, which originally discovered the compound in 1938. Polytetrafluoroethylene is a fluorocarbon solid, as it is a high-molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. Where used as a lubricant, PTFE ...
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International Maritime Organization
The International Maritime Organization (IMO, French: ''Organisation maritime internationale'') is a specialised agency of the United Nations responsible for regulating shipping. The IMO was established following agreement at a UN conference held in Geneva in 1948 and the IMO came into existence ten years later, meeting for the first time in 1959. Headquartered in London, United Kingdom, IMO currently has 175 Member States and three Associate Members. The IMO's primary purpose is to develop and maintain a comprehensive regulatory framework for shipping and its remit today includes maritime safety, environmental concerns, legal matters, technical co-operation, maritime security and the efficiency of shipping. IMO is governed by an assembly of members which meets every two years. Its finance and organization is administered by a council of 40 members elected from the assembly. The work of IMO is conducted through five committees and these are supported by technical subcommitte ...
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Windshields
The windshield (North American English) or windscreen (Commonwealth English) of an aircraft, car, bus, motorbike, truck, train, boat or streetcar is the front window, which provides visibility while protecting occupants from the elements. Modern windshields are generally made of laminated safety glass, a type of treated glass, which consists of, typically, two curved sheets of glass with a plastic layer laminated between them for safety, and bonded into the window frame. Motorcycle windshields are often made of high-impact polycarbonate or acrylic plastic. Usage Windshields protect the vehicle's occupants from wind and flying debris such as dust, insects, and rocks, and provide an aerodynamically formed window towards the front. UV coating may be applied to screen out harmful ultraviolet radiation. However, this is usually unnecessary since most auto windshields are made from laminated safety glass. The majority of UV-B is absorbed by the glass itself, and any remainin ...
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