Strontium Nitride
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Strontium Nitride
Strontium nitride, Sr3N2, is produced by burning strontium metal in air (resulting in a mixture with strontium oxide) or in nitrogen. Like other metal nitrides, it reacts with water to give strontium hydroxide and ammonia: :Sr3N2 + 6 H2O → 3 Sr(OH)2 + 2 NH3 See also * Beryllium nitride * Magnesium nitride * Calcium nitride * Barium nitride Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The ... References Nitrides Strontium compounds {{Inorganic-compound-stub ...
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Strontium
Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium. It occurs naturally mainly in the minerals celestine and strontianite, and is mostly mined from these. Both strontium and strontianite are named after Strontian, a village in Scotland near which the mineral was discovered in 1790 by Adair Crawford and William Cruickshank; it was identified as a new element the next year from its crimson-red flame test color. Strontium was first isolated as a metal in 1808 by Humphry Davy using the then newly discovered process of electrolysis. During the 19th century, strontium was mostly used in the production of sugar from sugar beets (see strontian p ...
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Strontium Oxide
Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a strongly basic oxide. Uses About 8% by weight of cathode ray tubes is strontium oxide, which has been the major use of strontium since 1970. Color televisions and other devices containing color cathode ray tubes sold in the United States are required by law to use strontium in the faceplate to block X-ray emission (these X-ray emitting TVs are no longer in production). Lead(II) oxide can be used in the neck and funnel, but causes discoloration when used in the faceplate. Reactions Elemental strontium is formed when strontium oxide is heated with aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other co ...
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Nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N2, a colorless and odorless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant uncombined element. Nitrogen occurs in all organisms, primarily in amino acids (and thus proteins), in the nucleic acids ( DNA and RNA) and in the energy transfer molecule adenosine triphosphate. The human body contains about 3% nitrogen by mass, the fourth most abundant element in the body after oxygen, carbon, and hydrogen. The nitrogen cycle describes the movement of the element from the air, into the biosphere and organic compounds, then back into the atmosphere. Many indus ...
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Nitride
In chemistry, a nitride is an inorganic compound of nitrogen. The "nitride" anion, N3- ion, is very elusive but compounds of nitride are numerous, although rarely naturally occuring. Some nitrides have a find applications, such as wear-resistant coatings (e.g., titanium nitride, TiN), hard ceramic materials (e.g., silicon nitride, Si3N4), and semiconductors (e.g., gallium nitride, GaN). The development of GaN-based light emitting diodes was recognized by the 2014 Nobel Prize in Physics. Metal nitrido complexes are also common. Synthesis of inorganic metal nitrides is challenging because nitrogen gas (N2) is not very reactive at low temperatures, but it becomes more reactive at higher temperatures. Therefore, a balance must be achieved between the low reactivity of nitrogen gas at low temperatures and the entropy driven formation of N2 at high temperatures. However, synthetic methods for nitrides are growing more sophisticated and the materials are of increasing technological re ...
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Strontium Hydroxide
Strontium hydroxide, Sr(OH)2, is a caustic alkali composed of one strontium ion and two hydroxide ions. It is synthesized by combining a strontium salt with a strong base. Sr(OH)2 exists in anhydrous, monohydrate, or octahydrate form. Preparation Because Sr(OH)2 is slightly soluble in cold water, its preparation can be easily carried out by the addition of a strong base such as NaOH or KOH, drop by drop to a solution of any soluble strontium salt, most commonly Sr(NO3)2 (strontium nitrate). The Sr(OH)2 will precipitate out as a fine white powder. From here, the solution is filtered, and the Sr(OH)2 is washed with cold water and dried. Applications Strontium hydroxide is used chiefly in the refining of beet sugar and as a stabilizer in plastic. It may be used as a source of strontium ions when the chlorine from strontium chloride is undesirable. Strontium hydroxide absorbs carbon dioxide from the air to form strontium carbonate Strontium carbonate (SrCO3) is the carbonat ...
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Beryllium Nitride
Beryllium nitride, Be3N2, is a nitride of beryllium. It can be prepared from the elements at high temperature (1100–1500 °C);Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier unlike beryllium azide or BeN6, it decomposes in vacuum into beryllium and nitrogen. It is readily hydrolysed forming beryllium hydroxide and ammonia. It has two polymorphic forms cubic α-Be3N2 with a defect anti-fluorite structure, and hexagonal β-Be3N2. It reacts with silicon nitride, Si3N4 in a stream of ammonia at 1800–1900 °C to form BeSiN2. Preparation Beryllium nitride is prepared by heating beryllium metal powder with dry nitrogen in an oxygen-free atmosphere in temperatures between 700 and 1400 °C. : 3Be + N2 → Be3N2 Uses It is used in refractory ceramicsHugh O. Pierson, 1996, Handbook of Refractory Carbides and Nitrides: Properties, Characteristics, Processing, and Applications, William Andrew Inc., as well as in nuclear reactors and to produ ...
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Magnesium Nitride
Magnesium nitride, which possesses the chemical formula Mg3N2, is an inorganic compound of magnesium and nitrogen. At room temperature and pressure it is a greenish yellow powder. Preparation * By passing dry nitrogen over heated magnesium: ::\begin\\ \ce\\ \end * or ammonia: ::\begin\\ \ce\\ \end History When isolating argon, William Ramsay passed dry air over copper to remove oxygen and over magnesium to remove the nitrogen, forming magnesium nitride. Chemistry Magnesium nitride reacts with water to produce magnesium hydroxide and ammonia gas, as do many metal nitrides. :Mg3N2(s) + 6 H2O(l) → 3 Mg(OH)2(aq) + 2 NH3(g) In fact, when magnesium is burned in air, some magnesium nitride is formed in addition to the principal product, magnesium oxide. Thermal decomposition of magnesium nitride gives magnesium and nitrogen gas (at 700-1500 °C). At high pressures, the stability and formation of new nitrogen-rich nitrides (N/Mg ratio equal or greater to one) were sugge ...
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Calcium Nitride
Calcium nitride is the inorganic compound with the chemical formula Ca3 N2. It exists in various forms (isomorphs), α-calcium nitride being more commonly encountered. Structure α-Calcium nitride adopts an anti-bixbyite structure, similar to Mn2O3, except that the positions of the ions are reversed: calcium (Ca2+) take the oxide (O2−) positions and nitride ions (N3−) the manganese (Mn3+). In this structure, Ca2+ occupies tetrahedral sites, and the nitride centres occupy two different types of octahedral sites. Synthesis and reactions Calcium nitride is formed along with the oxide, CaO, when calcium burns in air. It can be produced by direct reaction of the elements: :3 Ca + N2 → Ca3N2 It reacts with water or even the moisture in air to give ammonia and calcium hydroxide: :Ca3N2 + 6 H2O → 3 Ca(OH)2 + 2 NH3 Like sodium oxide Sodium oxide is a chemical compound with the formula Na2 O. It is used in ceramics and glasses. It is a white solid but the c ...
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Barium Nitride
Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. The most common minerals of barium are baryte (barium sulfate, BaSO4) and witherite (barium carbonate, BaCO3). The name ''barium'' originates from the alchemical derivative "baryta", from Greek (), meaning 'heavy'. ''Baric'' is the adjectival form of barium. Barium was identified as a new element in 1774, but not reduced to a metal until 1808 with the advent of electrolysis. Barium has few industrial applications. Historically, it was used as a getter for vacuum tubes and in oxide form as the emissive coating on indirectly heated cathodes. It is a component of YBCO (high-temperature superconductors) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure. Barium compounds are ...
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Nitrides
In chemistry, a nitride is an inorganic compound of nitrogen. The "nitride" anion, N3- ion, is very elusive but compounds of nitride are numerous, although rarely naturally occuring. Some nitrides have a find applications, such as wear-resistant coatings (e.g., titanium nitride, TiN), hard ceramic materials (e.g., silicon nitride, Si3N4), and semiconductors (e.g., gallium nitride, GaN). The development of GaN-based light emitting diodes was recognized by the 2014 Nobel Prize in Physics. Metal nitrido complexes are also common. Synthesis of inorganic metal nitrides is challenging because nitrogen gas (N2) is not very reactive at low temperatures, but it becomes more reactive at higher temperatures. Therefore, a balance must be achieved between the low reactivity of nitrogen gas at low temperatures and the entropy driven formation of N2 at high temperatures. However, synthetic methods for nitrides are growing more sophisticated and the materials are of increasing technological re ...
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