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Stern–Volmer Relationship
The Stern–Volmer relationship, named after Otto Stern and Max Volmer, allows the kinetics of a photophysical ''intermolecular'' deactivation process to be explored. Processes such as fluorescence and phosphorescence are examples of ''intramolecular'' deactivation (quenching) processes. An ''intermolecular'' deactivation is where the presence of another chemical species can accelerate the decay rate of a chemical in its excited state. In general, this process can be represented by a simple equation: : \mathrm^* + \mathrm \rightarrow \mathrm + \mathrm or : \mathrm^* + \mathrm \rightarrow \mathrm + \mathrm^* where A is one chemical species, Q is another (known as a quencher) and * designates an excited state. The kinetics of this process follows the Stern–Volmer relationship: : \frac = 1+k_q\tau_0\cdot mathrm Where I_f^0 is the intensity, or rate of fluorescence, without a quencher, I_f is the intensity, or rate of fluorescence, with a quencher, k_q is the quencher rate coeff ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Otto Stern
:''Otto Stern was also the pen name of German women's rights activist Louise Otto-Peters (1819–1895)''. Otto Stern (; 17 February 1888 – 17 August 1969) was a German-American physicist and Nobel laureate in physics. He was the second most nominated person for a Nobel Prize with 82 nominations in the years 1925–1945 (most times nominated is Arnold Sommerfeld with 84 nominations), ultimately winning in 1943. Biography Stern was born into a Jewish family in Sohrau (now Żory) in the Province of Silesia, the German Empire's Kingdom of Prussia. His father was Oskar Stern (1850-1919), a mill owner, who had been living in Breslau (now Wrocław) since 1892. His mother Eugenia née Rosenthal (1863-1907) was from Rawitsch (now Rawicz) in the Prussian Province of Posen. Otto Stern had a brother, Kurt, who became a noted botanist in Frankfurt, and three sisters. He studied in Freiburg im Breisgau, Munich and Breslau. Stern completed his studies at the University of Breslau in 1912 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Max Volmer
Max Volmer (; 3 May 1885 – 3 June 1965) was a German physical chemist, who made important contributions in electrochemistry, in particular on electrode kinetics. He co-developed the Butler–Volmer equation. Volmer held the chair and directorship of the Physical Chemistry and Electrochemistry Institute of the Technische Hochschule Berlin, in Berlin-Charlottenburg. After World War II, he went to the Soviet Union, where he headed a design bureau for the production of heavy water. Upon his return to East Germany ten years later, he became a professor at the Humboldt University of Berlin and was president of the East German Academy of Sciences. Education From 1905 to 1908, Volmer studied chemistry at the Philipps University of Marburg. After that, he went to the University of Leipzig, where he was awarded a doctorate in 1910, based on his work on photochemical reactions in high vacuums. He became an assistant lecturer at Leipzig in 1912, and after completion of his Habilit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluorescence
Fluorescence is the emission of light by a substance that has absorbed light or other electromagnetic radiation. It is a form of luminescence. In most cases, the emitted light has a longer wavelength, and therefore a lower photon energy, than the absorbed radiation. A perceptible example of fluorescence occurs when the absorbed radiation is in the ultraviolet region of the electromagnetic spectrum (invisible to the human eye), while the emitted light is in the visible region; this gives the fluorescent substance a distinct color that can only be seen when the substance has been exposed to UV light. Fluorescent materials cease to glow nearly immediately when the radiation source stops, unlike phosphorescent materials, which continue to emit light for some time after. Fluorescence has many practical applications, including mineralogy, gemology, medicine, chemical sensors (fluorescence spectroscopy), fluorescent labelling, dyes, biological detectors, cosmic-ray detection, vacu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Phosphorescence
Phosphorescence is a type of photoluminescence related to fluorescence. When exposed to light (radiation) of a shorter wavelength, a phosphorescent substance will glow, absorbing the light and reemitting it at a longer wavelength. Unlike fluorescence, a phosphorescent material does not immediately reemit the radiation it absorbs. Instead, a phosphorescent material absorbs some of the radiation energy and reemits it for a much longer time after the radiation source is removed. In a general sense, there is no distinct boundary between the emission times of fluorescence and phosphorescence (i.e.: if a substance glows under a black light it is generally considered fluorescent, and if it glows in the dark it is often simply called phosphorescent). In a modern, scientific sense, the phenomena can usually be classified by the three different mechanisms that produce the light, and the typical timescales during which those mechanisms emit light. Whereas fluorescent materials stop emit ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quenching (fluorescence)
Quenching refers to any process which decreases the fluorescence intensity of a given substance. A variety of processes can result in quenching, such as excited state reactions, energy transfer, complex-formation and collisional quenching. As a consequence, quenching is often heavily dependent on pressure and temperature. Molecular oxygen, iodide ions and acrylamide are common chemical quenchers. The chloride ion is a well known quencher for quinine fluorescence. Quenching poses a problem for non-instant spectroscopic methods, such as laser-induced fluorescence. Quenching is made use of in optode sensors; for instance the quenching effect of oxygen on certain ruthenium complexes allows the measurement of oxygen saturation in solution. Quenching is the basis for Förster resonance energy transfer (FRET) assays. Quenching and dequenching upon interaction with a specific molecular biological target is the basis for activatable optical contrast agents for molecular imaging. Many dyes ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Eugene A
Eugene may refer to: People and fictional characters * Eugene (given name), including a list of people and fictional characters with the given name * Eugene (actress) (born 1981), Kim Yoo-jin, South Korean actress and former member of the singing group S.E.S. * Eugene (wrestler), professional wrestler Nick Dinsmore * Franklin Eugene (producer), American film producer * Gene Eugene, stage name of Canadian born actor, record producer, engineer, composer and musician Gene Andrusco (1961–2000) * Wendell Eugene (1923–2017), American jazz musician Places Canada * Mount Eugene, in Nunavut; the highest mountain of the United States Range on Ellesmere Island United States * Eugene, Oregon, a city ** Eugene, OR Metropolitan Statistical Area ** Eugene (Amtrak station) * Eugene Apartments, NRHP-listed apartment complex in Portland, Oregon * Eugene, Indiana, an unincorporated town * Eugene, Missouri, an unincorporated town Business * Eugene Green Energy Standard, an int ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Kelvin
The kelvin, symbol K, is the primary unit of temperature in the International System of Units (SI), used alongside its prefixed forms and the degree Celsius. It is named after the Belfast-born and University of Glasgow-based engineer and physicist William Thomson, 1st Baron Kelvin (1824–1907). The Kelvin scale is an absolute thermodynamic temperature scale, meaning it uses absolute zero as its null (zero) point. Historically, the Kelvin scale was developed by shifting the starting point of the much-older Celsius scale down from the melting point of water to absolute zero, and its increments still closely approximate the historic definition of a degree Celsius, but since 2019 the scale has been defined by fixing the Boltzmann constant to be exactly . Hence, one kelvin is equal to a change in the thermodynamic temperature that results in a change of thermal energy by . The temperature in degree Celsius is now defined as the temperature in kelvins minus 273.15, meaning t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stokes–Einstein Relation
In physics (specifically, the kinetic theory of gases), the Einstein relation is a previously unexpected connection revealed independently by William Sutherland in 1904, Albert Einstein in 1905, and by Marian Smoluchowski in 1906 in their works on Brownian motion. The more general form of the equation is D = \mu \, k_\text T, where * is the diffusion coefficient; * is the "mobility", or the ratio of the particle's terminal drift velocity to an applied force, ; * is the Boltzmann constant; * is the absolute temperature. This equation is an early example of a fluctuation-dissipation relation. Two frequently used important special forms of the relation are: * Einstein–Smoluchowski equation, for diffusion of charged particles: D = \frac * Stokes–Einstein equation, for diffusion of spherical particles through a liquid with low Reynolds number: D = \frac Here * is the electrical charge of a particle; * is the electrical mobility of the charged particle; * is the dyna ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Optode
An optode or optrode is an optical sensor device that optically measures a specific substance usually with the aid of a chemical transducer. Construction An optode requires three components to function: a chemical that responds to an analyte, a polymer to immobilise the chemical transducer and instrumentation (optical fibre, light source, detector and other electronics). Optodes usually have the polymer matrix coated onto the tip of an optical fibre, but in the case of evanescent wave optodes the polymer is coated on a section of fibre that has been unsheathed. Operation Optodes can apply various optical measurement schemes such as reflection, absorption, evanescent wave, luminescence (fluorescence and phosphorescences), chemiluminescence, surface plasmon resonance. By far the most popular methodology is luminescence. Luminescence in solution obeys the linear Stern–Volmer relationship. Fluorescence of a molecule is quenched by specific analytes, e.g., ruthenium complexes are qu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
