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Spark Ionization
Spark ionization (also known as spark source ionization) is a method used to produce gas phase ions from a solid sample. The prepared solid sample is vaporized and partially ionized by an intermittent discharge or spark. This technique is primarily used in the field of mass spectrometry. When incorporated with a mass spectrometer the complete instrument is referred to as a spark ionization mass spectrometer or as a spark source mass spectrometer (SSMS). History The use of spark ionization for analysis of impurities in solids was indicated by Dempster's work in 1935. Metals were a class of material that could not be previously ionized by thermal ionization (the method formerly used for ionizing solid sample). Spark ion sources were not commercially produced until after 1954 when Hannay demonstrated its capability for analysis of trace impurities (sub-part per million detection sensitivity) in semiconducting materials. The prototype spark source instrument was the MS7 mass sp ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Rf Spark Source Schematic
RF is an abbreviation for radio frequency. Rf or RF may also mean: Arts and entertainment * ''Red Faction (series)'', a series of revolution video games * Rinforzando, , in music notation * ''RF Online'', an online RPG made by CCR Businesses * Aero K, IATA code (2020—present) * Florida West International Airways, IATA code (1984—2017) * Regions Financial Corporation, NYSE stock symbol Government and military * France (''République française'') * Russian Federation * Rhodesian Front, former political party in Rhodesia Biology and medicine * Rheumatic fever, an inflammatory disease * Release factors RF1, RF2, RF3, proteins * Reticular formation, in the brainstem * Rheumatoid factor, an antibody * Receptive field, the response characteristic of a neuron * Respiratory failure * Risk factor Other uses in science and technology * Representative fraction * Retardation factor in a chromatographic system * Radiative forcing, the change in energy flux in the atmosphere caused by cl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mass Spectrometry
Mass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a ''mass spectrum'', a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio. These spectra are used to determine the elemental or isotopic signature of a sample, the masses of particles and of molecules, and to elucidate the chemical identity or structure of molecules and other chemical compounds. In a typical MS procedure, a sample, which may be solid, liquid, or gaseous, is ionized, for example by bombarding it with a beam of electrons. This may cause some of the sample's molecules to break up into positively charged fragments or simply become positively charged without fragmenting. These ions (fragments) are then separated accordin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fresenius' Journal Of Analytical Chemistry
''Analytical and Bioanalytical Chemistry'' is a peer-reviewed scientific journal publishing research articles in the broad field of analytical and bioanalytical chemistry. Some of the subjects covered are the development of instruments for mass spectrometry, metallomics, ionics, and the analytical characterization of nano- and biomaterials. The journal was first published in 1862 under the name ''Fresenius’ Journal of Analytical Chemistry''. In 2002 the journal was renamed to ''Analytical and Bioanalytical Chemistry''. Impact factor ''Analytical and Bioanalytical Chemistry'' had a 2018 impact factor of 3.286, ranking it 18th out of 84 in the subject category " Chemistry, Analytical" and 21st out of 79 in "Biochemical Research Methods". Editors The editors of the journal are A.J Baeumner H. Cui, G. Gauglitz, G. Hopfgartner, L. Mondello, M.C. Moreno-Bondi, D.C. Muddiman, S. Szunerits, Q. Qang and S.A. Wise. Literature * Wilhelm Fresenius Wilhelm may refer to: People and f ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arthur Jeffrey Dempster
Arthur Jeffrey Dempster (August 14, 1886 – March 11, 1950) was a Canadian-American physicist best known for his work in mass spectrometry and his discovery in 1935 of the uranium isotope 235U. Early life and education Dempster was born in Toronto, Ontario, Canada. He received his bachelor's and master's degrees at the University of Toronto in 1909 and 1910, respectively. He travelled to study in Germany, and then left at the outset of World War I for the United States; there he received his Ph.D. in physics at the University of Chicago. Academic career Dempster joined the physics faculty at the University of Chicago in 1916 and remained there until his death in 1950. During World War II he worked on the secret Manhattan Project to develop the world's first nuclear weapons. From 1943 to 1946, Dempster was chief physicist of the University of Chicago's Metallurgical Laboratory or "Met Lab" which integrally related to the Manhattan Project and founded to study the materials ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Metropolitan-Vickers
Metropolitan-Vickers, Metrovick, or Metrovicks, was a British heavy electrical engineering company of the early-to-mid 20th century formerly known as British Westinghouse. Highly diversified, it was particularly well known for its industrial electrical equipment such as generators, steam turbines, switchgear, transformers, electronics and railway traction equipment. Metrovick holds a place in history as the builders of the first commercial transistor computer, the Metrovick 950, and the first British axial-flow jet engine, the Metropolitan-Vickers F.2. Its factory in Trafford Park, Manchester, was for most of the 20th century one of the biggest and most important heavy engineering facilities in Britain and the world. History Metrovick started as a way to separate the existing British Westinghouse Electrical and Manufacturing Company factories from United States control, which had proven to be a hindrance to gaining government contracts during the First World War. In 1917 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Glow Discharge
A glow discharge is a plasma formed by the passage of electric current through a gas. It is often created by applying a voltage between two electrodes in a glass tube containing a low-pressure gas. When the voltage exceeds a value called the striking voltage, the gas ionization becomes self-sustaining, and the tube glows with a colored light. The color depends on the gas used. Glow discharges are used as a source of light in devices such as neon lights, fluorescent lamps, and plasma-screen televisions. Analyzing the light produced with spectroscopy can reveal information about the atomic interactions in the gas, so glow discharges are used in plasma physics and analytical chemistry. They are also used in the surface treatment technique called sputtering. Electrical conduction in gas Conduction in a gas requires charge carriers, which can be either electrons or ions. Charge carriers come from ionizing some of the gas molecules. In terms of current flow, glow discharge falls ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inductively Coupled Plasma
An inductively coupled plasma (ICP) or transformer coupled plasma (TCP) is a type of plasma source in which the energy is supplied by electric currents which are produced by electromagnetic induction, that is, by time-varying magnetic fields. Operation There are three types of ICP geometries: planar (Fig. 3 (a)), cylindrical (Fig. 3 (b)), and half-toroidal (Fig. 3 (c)). In planar geometry, the electrode is a length of flat metal wound like a spiral (or coil). In cylindrical geometry, it is like a helical spring. In half-toroidal geometry, it is toroidal solenoid cut along its main diameter to two equal halves. When a time-varying electric current is passed through the coil, it creates a time-varying magnetic field around it, with flux \Phi=\pi r^2 H=\pi r^2 H_0 \cos \omega t, where ''r'' is the distance to the center of coil (and of the quartz tube). According to the Faraday–Lenz's law of induction, this creates azimuthal electromotive force in the rarefied gas: U ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrode
An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit (e.g. a semiconductor, an electrolyte, a vacuum or air). Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery. The electrophore, invented by Johan Wilcke, was an early version of an electrode used to study static electricity. Anode and cathode in electrochemical cells Electrodes are an essential part of any battery. The first electrochemical battery made was devised by Alessandro Volta and was aptly named the Voltaic cell. This battery consisted of a stack of copper and zinc electrodes separated by brine-soaked paper disks. Due to fluctuation in the voltage provided by the voltaic cell it wasn't very practical. The first practical battery was invented in 1839 and named the Daniell cell after John Frederic Daniell. Still making use of the zinc–copper electrode combination. Since then many more batteries have be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electric Spark
An electric spark is an abrupt electrical discharge that occurs when a sufficiently high electric field creates an ionized, electrically conductive channel through a normally-insulating medium, often air or other gases or gas mixtures. Michael Faraday described this phenomenon as "the beautiful flash of light attending the discharge of common electricity". The rapid transition from a non-conducting to a conductive state produces a brief emission of light and a sharp crack or snapping sound. A spark is created when the applied electric field exceeds the dielectric breakdown strength of the intervening medium. For air, the breakdown strength is about 30 kV/cm at sea level. Experimentally, this figure tends to differ depending upon humidity, atmospheric pressure, shape of electrodes (needle and ground-plane, hemispherical etc.) and the corresponding spacing between them and even the type of waveform, whether sinusoidal or cosine-rectangular. At the beginning stages, free electrons ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spark Gap
A spark gap consists of an arrangement of two conducting electrodes separated by a gap usually filled with a gas such as air, designed to allow an electric spark to pass between the conductors. When the potential difference between the conductors exceeds the breakdown voltage of the gas within the gap, a spark forms, ionizing the gas and drastically reducing its electrical resistance. An electric current then flows until the path of ionized gas is broken or the current reduces below a minimum value called the "holding current". This usually happens when the voltage drops, but in some cases occurs when the heated gas rises, stretching out and then breaking the filament of ionized gas. Usually, the action of ionizing the gas is violent and disruptive, often leading to sound (ranging from a ''snap'' for a spark plug to thunder for a lightning discharge), light and heat. Spark gaps were used historically in early electrical equipment, such as spark gap radio transmitters, electr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sector Instrument
A sector instrument is a general term for a class of mass spectrometer that uses a static electric (E) or magnetic (B) sector or some combination of the two (separately in space) as a mass analyzer. Popular combinations of these sectors have been the EB, BE (of so-called reverse geometry), three-sector BEB and four-sector EBEB (electric-magnetic-electric-magnetic) instruments. Most modern sector instruments are double-focusing instruments (first developed by Francis William Aston, Arthur Jeffrey Dempster, Kenneth Bainbridge and Josef Mattauch in 1936) in that they focus the ion beams both in direction and velocity. Theory The behavior of ions in a homogeneous, linear, static electric or magnetic field (separately) as is found in a sector instrument is simple. The physics are described by a single equation called the Lorentz force law. This equation is the fundamental equation of all mass spectrometric techniques and applies in non-linear, non-homogeneous cases too and is an impor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Photosensitive
Photosensitivity is the amount to which an object reacts upon receiving photons, especially visible light. In medicine, the term is principally used for abnormal reactions of the skin, and two types are distinguished, photoallergy and phototoxicity. The photosensitive ganglion cells in the mammalian eye are a separate class of light-detecting cells from the photoreceptor cells that function in vision. Skin reactions Human medicine Sensitivity of the skin to a light source can take various forms. People with particular skin types are more sensitive to sunburn. Particular medications make the skin more sensitive to sunlight; these include most of the tetracycline antibiotics, heart drugs amiodarone, and Sulfonamide (medicine), sulfonamides. Some dietary supplements, such as St. John's Wort, include photosensitivity as a possible side effect. Particular conditions lead to increased light sensitivity. Patients with systemic lupus erythematosus experience skin symptoms after sunligh ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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