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Silicate Perovskite
Silicate perovskite is either (the magnesium end-member is called bridgmanite) or ( calcium silicate known as davemaoite) when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle, between about depth. They are thought to form the main mineral phases, together with ferropericlase. Discovery The existence of silicate perovskite in the mantle was first suggested in 1962, and both and had been synthesized experimentally before 1975. By the late 1970s, it had been proposed that the seismic discontinuity at about 660 km in the mantle represented a change from spinel structure minerals with an olivine composition to silicate perovskite with ferropericlase. Natural silicate perovskite was discovered in the heavily shocked Tenham meteorite. In 2014, the Commission on New Minerals, Nomenclature and Classification (CNMNC) of the International Mineralogical Association (IMA) approved th ...
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Mindat
Mindat may refer to: Places in Burma/Myanmar *Mindat, Chin State, in Burma *Mindat Township, in Burma *Mindat District in Chin State, Burma Other uses *Mindat Min Kanaung Mintha ( my, ကနောင်မင်းသား; 31 January 1820 – 2 August 1866) was crown prince of Burma and son of King Tharrawaddy and younger brother of King Mindon of Burma. Towards the end of the Second Anglo-Burmese Wa ..., a Burmese prince * Mindat.org, an online mineralogy database {{dab, geo ...
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Iron(II) Oxide
Iron(II) oxide or ferrous oxide is the inorganic compound with the formula FeO. Its mineral form is known as wüstite. One of several iron oxides, it is a black-colored powder that is sometimes confused with rust, the latter of which consists of hydrated iron(III) oxide (ferric oxide). Iron(II) oxide also refers to a family of related non-stoichiometric compounds, which are typically iron deficient with compositions ranging from Fe0.84O to Fe0.95O. Preparation FeO can be prepared by the thermal decomposition of iron(II) oxalate. :FeC2O4 → FeO + CO2 + CO The procedure is conducted under an inert atmosphere to avoid the formation of iron(III) oxide (Fe2O3). A similar procedure can also be used for the synthesis of manganous oxide and stannous oxide. Stoichiometric FeO can be prepared by heating Fe0.95O with metallic iron at 770 °C and 36 kbar.Wells A.F. (1984) ''Structural Inorganic Chemistry'' 5th edition Oxford University Press Reactions FeO is the ...
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Eclogite
Eclogite () is a metamorphic rock containing garnet (almandine- pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, zoisite, dolomite, corundum and, rarely, diamond. The chemistry of primary and accessory minerals is used to classify three types of eclogite (A, B, and C). The broad range of eclogitic compositions has led a longstanding debate on the origin of eclogite xenoliths as subducted, altered oceanic crust. Origins Eclogites typically result from high to ultrahigh pressure metamorphism of mafic rock at low thermal gradients of < as it is subducted to the lower crust to upper mantle depths in a subduction zone.


Classification

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Harzburgite
Harzburgite, an ultramafic, igneous rock, is a variety of peridotite consisting mostly of the two minerals olivine and low-calcium (Ca) pyroxene ( enstatite); it is named for occurrences in the Harz Mountains of Germany. It commonly contains a few percent chromium-rich spinel as an accessory mineral. Garnet-bearing harzburgite is much less common, found most commonly as xenoliths in kimberlite. Harzburgite typically forms by the extraction of partial melts from the more pyroxene-rich peridotite called lherzolite. The molten magma extracted from harzburgite may then erupt on the surface as basalt. If partial melting of the harzburgite continues, all of the pyroxene may be extracted from it to form magma, leaving behind the pyroxene-poor peridotite called dunite. Harzburgite may also form by the accumulation of olivine and low-Ca pyroxene in large magma chambers of basalt deep in continental crust (layered intrusions). Occurrence Harzburgite is the most commonly found var ...
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Pyrolite
Pyrolite is a term used to characterize a model composition of the Earth's mantle. This model is based on that a pyrolite source can produce the Mid-Ocean Ridge Basalt by partial melting. It was first proposed by Ted Ringwood (1962) as being 1 part basalt and 4 parts harzburgite, but later was revised to being 1 part tholeiitic basalt and 3 parts dunite. The term is derived from the mineral names PYR-oxene and OL-ivine. However, whether pyrolite is representative of the Earth's mantle remains debated. Chemical composition and phase transition The major elements composition of pyrolite is about 44.71 weight percent (wt%) SiO2, 3.98 wt% Al2O3, 8.18 wt% FeO, 3.17 wt% CaO, 38.73 wt% MgO, 0.13 wt% Na2O. 1) A pyrolitic Upper Mantle is mainly composed of olivine (~60 volume percent (vol%)), clinopyroxene, orthopyroxene, and garnet. Pyroxene would gradually dissolved into garnet and form majoritic garnet. 2) A pyrolitic Mantle Transition Zone is mainly composed of 60 vol% olivine ...
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Post-perovskite
Post-perovskite (pPv) is a high-pressure phase of magnesium silicate (MgSiO3). It is composed of the prime oxide constituents of the Earth's rocky mantle (MgO and SiO2), and its pressure and temperature for stability imply that it is likely to occur in portions of the lowermost few hundred km of Earth's mantle. The post-perovskite phase has implications for the ''D''′′ layer, which influences the convective mixing in the mantle responsible for plate tectonics. Post-perovskite has the same crystal structure as the synthetic solid compound CaIrO3, and is often referred to as the "CaIrO3-type phase of MgSiO3" in the literature. The crystal system of post-perovskite is orthorhombic, its space group is ''Cmcm'', and its structure is a stacked SiO6-octahedral sheet along the ''b'' axis. The name "post-perovskite" derives from silicate perovskite, the stable phase of MgSiO3 throughout most of Earth's mantle, which has the perovskite structure. The prefix "post-" refers to the fact ...
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Transition Zone (Earth)
The transition zone is part of the Earth's mantle, and is located between the lower mantle and the upper mantle, between a depth of 410 and 660 km (250 to 400 mi). The Earth's mantle, including the transition zone, consists primarily of peridotite, an ultramafic igneous rock. The mantle was divided into the upper mantle, transition zone, and lower mantle as a result of sudden seismic-velocity discontinuities at depths of 410 and 660 km (250 to 400 mi). This is thought to occur as a result of rearrangement of grains in olivine (which constitutes a large portion of peridotite) at a depth of 410 km, to form a denser crystal structure as a result of the increase in pressure with increasing depth. Below a depth of 660 km, evidence suggests due to pressure changes ringwoodite minerals change into two new denser phases, bridgmanite and periclase. This can be seen using body waves from earthquakes, which are converted, reflected or refracted at the boundar ...
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Ringwoodite
Ringwoodite is a high-pressure phase of Mg2SiO4 (magnesium silicate) formed at high temperatures and pressures of the Earth's mantle between depth. It may also contain iron and hydrogen. It is polymorphous with the olivine phase forsterite (a magnesium iron silicate). Ringwoodite is notable for being able to contain hydroxide ions (oxygen and hydrogen atoms bound together) within its structure. In this case two hydroxide ions usually take the place of a magnesium ion and two oxide ions. Combined with evidence of its occurrence deep in the Earth's mantle, this suggests that there is from one to three times the world ocean's equivalent of water in the mantle transition zone from 410 to 660 km deep. This mineral was first identified in the Tenham meteorite in 1969, and is inferred to be present in large quantities in the Earth's mantle. Ringwoodite was named after the Australian earth scientist Ted Ringwood (1930–1993), who studied polymorphic phase transitions in th ...
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Earth
Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surface is made up of the ocean, dwarfing Earth's polar ice, lakes, and rivers. The remaining 29% of Earth's surface is land, consisting of continents and islands. Earth's surface layer is formed of several slowly moving tectonic plates, which interact to produce mountain ranges, volcanoes, and earthquakes. Earth's liquid outer core generates the magnetic field that shapes the magnetosphere of the Earth, deflecting destructive solar winds. The atmosphere of the Earth consists mostly of nitrogen and oxygen. Greenhouse gases in the atmosphere like carbon dioxide (CO2) trap a part of the energy from the Sun close to the surface. Water vapor is widely present in the atmosphere and forms clouds that cover most of the planet. More solar e ...
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Enstatite
Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, , has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20). Polymorphs and varieties Most natural crystals are orthorhombic ( space group P''bca'') although three polymorphs are known. The high temperature, low pressure polymorphs are protoenstatite and protoferrosilite (also orthorhombic, space group P''bcn'') while the low temperature forms, clinoenstatite and clinoferrosilite, are monoclinic (space group P2''1/c''). Weathered enstatite with a small amount of iron tak ...
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Orthorhombic Crystal System
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a rectangular base (''a'' by ''b'') and height (''c''), such that ''a'', ''b'', and ''c'' are distinct. All three bases intersect at 90° angles, so the three lattice vectors remain mutually orthogonal. Bravais lattices There are four orthorhombic Bravais lattices: primitive orthorhombic, base-centered orthorhombic, body-centered orthorhombic, and face-centered orthorhombic. For the base-centered orthorhombic lattice, the primitive cell has the shape of a right rhombic prism;See , row oC, column Primitive, where the cell parameters are given as a1 = a2, α = β = 90° it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primi ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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