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Shell–Paques Process
The Shell–Paques process, also known by the trade name of Thiopaq O&G, is a gas desulfurization technology for the removal of hydrogen sulfide from natural-, refinery-, synthesis- and biogas. The process was initially named after the Shell Oil and Paques purification companies. After accession of a dedicated joint venture by the founders, Paqell B.V., the trade name for applications in the Oil & Gas industry was changed to "THIOPAQ O&G". It is based on the biocatalytical conversion of sulfide into elemental sulfur. It operates at near-ambient conditions of temperature, about 30-40 °C, and pressure which results in inherent safety. It is an alternative to, for example, the Claus process. Process chemistry Each reaction can be applied individually or sequentially as dictated by the characteristics of the stream to be treated. The process consist of three main sections: An absorber (gas washing section), a bioreactor (sulfide oxidation and regeneration of washing liquid) and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Desulfurization
Desulfurization or desulphurisation is a chemical process for the removal of sulfur from a material. This involves either the removal of sulfur from a molecule (''e.g.'' A=S → A:) or the removal of sulfur compounds from a mixture such as oil refinery streams. These processes are of great industrial and environmental importance as they provide the bulk of sulfur used in industry (Claus process and Contact process), sulfur-free compounds that could otherwise not be used in a great number of catalytic processes, and also reduce the release of harmful sulfur compounds into the environment, particularly sulfur dioxide (SO2) which leads to acid rain. Processes used for desulfurization include hydrodesulfurization, SNOX process and the wet sulfuric acid process The wet sulfuric acid process (WSA process) is a gas desulfurization process. After Danish company Haldor Topsoe introduced this technology in 1987, it has been recognized as a process for recovering sulfur from various proce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The underground mine gas term for foul-smelling hydrogen sulfide-rich gas mixtures is ''stinkdamp''. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. The British English spelling of this compound is hydrogen sulphide, a spelling no longer recommended by the Royal Society of Chemistry or the International Union of Pure and Applied Chemistry. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or it or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biogas
Biogas is a mixture of gases, primarily consisting of methane, carbon dioxide and hydrogen sulphide, produced from raw materials such as agricultural waste, manure, municipal waste, plant material, sewage, green waste and food waste. It is a renewable energy source. Biogas is produced by anaerobic digestion with anaerobic organisms or methanogen inside an anaerobic digester, biodigester or a bioreactor. Biogas is primarily methane () and carbon dioxide () and may have small amounts of hydrogen sulfide (), moisture and siloxanes. The gases methane, hydrogen, and carbon monoxide () can be combusted or oxidized with oxygen. This energy release allows biogas to be used as a fuel; it can be used in fuel cells and for any heating purpose, such as cooking. It can also be used in a gas engine to convert the energy in the gas into electricity and heat. Biogas can be compressed after removal of carbon dioxide and hydrogen sulphide, the same way as natural gas is compressed to CN ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Shell Oil
Shell plc is a British multinational oil and gas company headquartered in London, England. Shell is a public limited company with a primary listing on the London Stock Exchange (LSE) and secondary listings on Euronext Amsterdam and the New York Stock Exchange. It is one of the oil and gas "supermajors" and by revenue and profits is consistently one of the largest companies in the world. Measured by both its own emissions, and the emissions of all the fossil fuels it sells, Shell was the ninth-largest corporate producer of greenhouse gas emissions in the period 1988–2015. Shell was formed in 1907 through the merger of Royal Dutch Petroleum Company of the Netherlands and The "Shell" Transport and Trading Company of the United Kingdom. The combined company rapidly became the leading competitor of the American Standard Oil and by 1920 Shell was the largest producer of oil in the world. Shell first entered the chemicals industry in 1929. Shell was one of the " Seven Sisters" which ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds large families of inorganic and organic compounds, e.g. lead sulfide and dimethyl sulfide. Hydrogen sulfide (H2S) and bisulfide (SH−) are the conjugate acids of sulfide. Chemical properties The sulfide ion, S2−, does not exist in aqueous alkaline solutions of Na2S. Instead sulfide converts to hydrosulfide: :S2− + H2O → SH− + OH− Upon treatment with an acid, sulfide salts convert to hydrogen sulfide: :S2− + H+ → SH− :SH− + H+ → H2S Oxidation of sulfide is a complicated process. Depending on the conditions, the oxidation can produce elemental sulfur, polysulfides, polythionates, sulfite, or sulfate. Metal sulfides react with halogens, forming sulfur and metal salts. :8 MgS + 8 I2 → S8 + 8 M ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. Sulfur is the tenth most abundant element by mass in the universe and the fifth most on Earth. Though sometimes found in pure, native form, sulfur on Earth usually occurs as sulfide and sulfate minerals. Being abundant in native form, sulfur was known in ancient times, being mentioned for its uses in ancient India, ancient Greece, China, and ancient Egypt. Historically and in literature sulfur is also called brimstone, which means "burning stone". Today, almost all elemental sulfur is produced as a byproduct of removing sulfur-containing contaminants from natural gas and petroleum.. Downloahere The greatest commercial use of the element is the production o ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Claus Process
The Claus process is the most significant gas desulfurizing process, recovering elemental sulfur from gaseous hydrogen sulfide. First patented in 1883 by the chemist Carl Friedrich Claus, the Claus process has become the industry standard. The multi-step Claus process recovers sulfur from the gaseous hydrogen sulfide found in raw natural gas and from the by-product gases containing hydrogen sulfide derived from refining crude oil and other industrial processes. The by-product gases mainly originate from physical and chemical gas treatment units (Selexol, Rectisol, Purisol and amine scrubbers) in refineries, natural gas processing plants and gasification or synthesis gas plants. These by-product gases may also contain hydrogen cyanide, hydrocarbons, sulfur dioxide or ammonia. Gases with an H2S content of over 25% are suitable for the recovery of sulfur in straight-through Claus plants while alternate configurations such as a split-flow set up or feed and air preheating c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sour Gas
Sour gas is natural gas or any other gas containing significant amounts of hydrogen sulfide (H2S). Natural gas is usually considered sour if there are more than 5.7 milligrams of H2S per cubic meter of natural gas, which is equivalent to approximately 4 ppm by volume under standard temperature and pressure.NaturalGas.org website page ''Processing Natural Gas'' However, this threshold varies by country, state, or even agency or application. For instance, the considers a sour gas pipeline one that carries gas over 100 ppm by volume of H2S. However, the |
Sodium Hydrogensulfide
Sodium hydrosulfide is the chemical compound with the formula NaHS. This compound is the product of the half-neutralization of hydrogen sulfide () with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar purposes. Solid NaSH is colorless. The solid has an odor of owing to hydrolysis by atmospheric moisture. In contrast with sodium sulfide (), which is insoluble in organic solvents, NaSH, being a 1:1 electrolyte, is more soluble. Structure and properties Crystalline NaHS undergoes two phase transitions. At temperatures above 360 K, NaSH adopts the NaCl structure, which implies that the behaves as a spherical anion owing to its rapid rotation, leading to equal occupancy of eight equivalent positions. Below 360 K, a rhombohedral structure forms, and the sweeps out a discoidal shape. Below 114 K, the structure becomes monoclinic. The analogous rubidium and potassium compounds behave similarly. NaSH has a relatively low melting poi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Halothiobacillus
''Halothiobacillus'' is a genus in the ''Gammaproteobacteria''. Both species are obligate aerobic bacteria; they require oxygen to grow. They are also halotolerant; they live in environments with high concentrations of salt or other solutes, but don't require them in order to grow. The type species of this genus, ''Halothiobacillus neapolitanus'' used to be members of the genus ''Thiobacillus'', before they were reclassified in 2000.Kelly, D.P., and Wood, A.P. "Reclassification of some species of ''Thiobacillus'' to the newly designated genera ''Acidithiobacillus'' gen. nov., ''Halothiobacillus'' gen. nov. and ''Thermithiobacillus'' gen. nov." Int. J. Syst. Evol. Microbiol. (2000) 50:489-500. A further two former ''Thiobacillus'' spp. were also reclassified as '' Halothiobacillus halophilus'' and '' Halothiobacillus hydrothermalis'', both of which were obligate halophiles rather than being halotolerant and showed comparatively low 16S rRNA gene identity to ''Halothiobacillus ne ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfidic Caustic
Sulfidation (British spelling also sulphidation) is a process of installing sulfide ions in a material or molecule. The process is widely used to convert oxides to sulfides but is also related to corrosion and surface modification. Inorganic, materials, and organic chemistry Sulfidation is relevant to the formation of sulfide minerals. A large scale application of sulfidation is the conversion of molybdenum oxides to the corresponding sulfides. This conversion is a step in the preparation of catalysts for hydrodesulfurization wherein alumina impregnated with molybdate salts are converted to molybdenum disulfide by the action of hydrogen sulfide. In organosulfur chemistry, sulfiding is often called thiation. The preparation of thioamides from amides involves thiation. A typical reagent is phosphorus pentasulfide (P4S10). The idealized equation for this conversion is: :RC(O)NH2 + 1/4 P4S10 → RC(S)NH2 + 1/4 P4S6O4 This conversion where an oxygen atom in the amide fu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
