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Schrieffer–Wolff Transformation
In quantum mechanics, the Schrieffer–Wolff transformation is a unitary transformation used to perturbatively diagonalize the system Hamiltonian to first order in the interaction. As such, the Schrieffer–Wolff transformation is an operator version of second-order perturbation theory. The Schrieffer–Wolff transformation is often used to project out the high energy excitations of a given quantum many-body Hamiltonian in order to obtain an effective low energy model. The Schrieffer–Wolff transformation thus provides a controlled perturbative way to study the strong coupling regime of quantum-many body Hamiltonians. Although commonly attributed to the paper in which the Kondo model was obtained from the Anderson impurity model by J.R. Schrieffer and P.A. Wolff., Joaquin Mazdak Luttinger and Walter Kohn used this method in an earlier work about non-periodic k·p perturbation theory In solid-state physics, the k·p perturbation theory is an approximated semi-empirical app ...
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Quantum Mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science. Classical physics, the collection of theories that existed before the advent of quantum mechanics, describes many aspects of nature at an ordinary (macroscopic) scale, but is not sufficient for describing them at small (atomic and subatomic) scales. Most theories in classical physics can be derived from quantum mechanics as an approximation valid at large (macroscopic) scale. Quantum mechanics differs from classical physics in that energy, momentum, angular momentum, and other quantities of a bound system are restricted to discrete values ( quantization); objects have characteristics of both particles and waves (wave–particle duality); and there are limits to ...
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Unitary Transformation
In mathematics, a unitary transformation is a transformation that preserves the inner product: the inner product of two vectors before the transformation is equal to their inner product after the transformation. Formal definition More precisely, a unitary transformation is an isomorphism between two inner product spaces (such as Hilbert spaces). In other words, a ''unitary transformation'' is a bijective function U : H \to H_2\, between two inner product spaces, H and H_2, such that \langle Ux, Uy \rangle_ = \langle x, y \rangle_ \quad \text x, y \in H. Properties A unitary transformation is an isometry, as one can see by setting x=y in this formula. Unitary operator In the case when H_1 and H_2 are the same space, a unitary transformation is an automorphism of that Hilbert space, and then it is also called a unitary operator. Antiunitary transformation A closely related notion is that of antiunitary transformation, which is a bijective function :U:H_1\to H_2\, between two co ...
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Diagonalizable Matrix
In linear algebra, a square matrix A is called diagonalizable or non-defective if it is similar to a diagonal matrix, i.e., if there exists an invertible matrix P and a diagonal matrix D such that or equivalently (Such D are not unique.) For a finite-dimensional vector space a linear map T:V\to V is called diagonalizable if there exists an ordered basis of V consisting of eigenvectors of T. These definitions are equivalent: if T has a matrix representation T = PDP^ as above, then the column vectors of P form a basis consisting of eigenvectors of and the diagonal entries of D are the corresponding eigenvalues of with respect to this eigenvector basis, A is represented by Diagonalization is the process of finding the above P and Diagonalizable matrices and maps are especially easy for computations, once their eigenvalues and eigenvectors are known. One can raise a diagonal matrix D to a power by simply raising the diagonal entries to that power, and the determi ...
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Hamiltonian (quantum Mechanics)
Hamiltonian may refer to: * Hamiltonian mechanics, a function that represents the total energy of a system * Hamiltonian (quantum mechanics), an operator corresponding to the total energy of that system ** Dyall Hamiltonian, a modified Hamiltonian with two-electron nature ** Molecular Hamiltonian, the Hamiltonian operator representing the energy of the electrons and nuclei in a molecule * Hamiltonian (control theory), a function used to solve a problem of optimal control for a dynamical system * Hamiltonian path, a path in a graph that visits each vertex exactly once * Hamiltonian group, a non-abelian group the subgroups of which are all normal * Hamiltonian economic program, the economic policies advocated by Alexander Hamilton, the first United States Secretary of the Treasury See also * Alexander Hamilton (1755 or 1757–1804), American statesman and one of the Founding Fathers of the US * Hamilton (other) Hamilton may refer to: People * Hamilton (name), a common ...
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Perturbation Theory (quantum Mechanics)
In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional "perturbing" Hamiltonian representing a weak disturbance to the system. If the disturbance is not too large, the various physical quantities associated with the perturbed system (e.g. its energy levels and eigenstates) can be expressed as "corrections" to those of the simple system. These corrections, being small compared to the size of the quantities themselves, can be calculated using approximate methods such as asymptotic series. The complicated system can therefore be studied based on knowledge of the simpler one. In effect, it is describing a complicated unsolved system using a simple, solvable system. Approximate Hamiltonians Perturbation theory is an important tool for de ...
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Projection (linear Algebra)
In linear algebra and functional analysis, a projection is a linear transformation P from a vector space to itself (an endomorphism) such that P\circ P=P. That is, whenever P is applied twice to any vector, it gives the same result as if it were applied once (i.e. P is idempotent). It leaves its image unchanged. This definition of "projection" formalizes and generalizes the idea of graphical projection. One can also consider the effect of a projection on a geometrical object by examining the effect of the projection on points in the object. Definitions A projection on a vector space V is a linear operator P : V \to V such that P^2 = P. When V has an inner product and is complete (i.e. when V is a Hilbert space) the concept of orthogonality can be used. A projection P on a Hilbert space V is called an orthogonal projection if it satisfies \langle P \mathbf x, \mathbf y \rangle = \langle \mathbf x, P \mathbf y \rangle for all \mathbf x, \mathbf y \in V. A projection on a Hilbert ...
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Effective Field Theory
In physics, an effective field theory is a type of approximation, or effective theory, for an underlying physical theory, such as a quantum field theory or a statistical mechanics model. An effective field theory includes the appropriate degrees of freedom to describe physical phenomena occurring at a chosen length scale or energy scale, while ignoring substructure and degrees of freedom at shorter distances (or, equivalently, at higher energies). Intuitively, one averages over the behavior of the underlying theory at shorter length scales to derive what is hoped to be a simplified model at longer length scales. Effective field theories typically work best when there is a large separation between length scale of interest and the length scale of the underlying dynamics. Effective field theories have found use in particle physics, statistical mechanics, condensed matter physics, general relativity, and hydrodynamics. They simplify calculations, and allow treatment of dissipation and ...
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Kondo Model
The Kondo model (sometimes referred to as the s-d model) is a model for a single localized quantum impurity coupled to a large reservoir of delocalized and noninteracting electrons. The quantum impurity is represented by a spin-1/2 particle, and is coupled to a continuous band of noninteracting electrons by an antiferromagnetic exchange coupling J. The Kondo model is used as a model for metals containing magnetic impurities, as well as quantum dot systems. Kondo Hamiltonian The Kondo Hamiltonian is given by :H = \sum_ \epsilon_ c^_c_ - J \mathbf\cdot \mathbf where \mathbf is the spin-1/2 operator representing the impurity, and :\mathbf = \sum_ c^_ \mathbf_c_ is the local spin-density of the noninteracting band at the impurity site ( \mathbf are the Pauli matrices). In the Kondo problem, J 0). The Kondo model is intimately related to the Anderson impurity model, as can be shown by Schrieffer–Wolff transformation. See also *Anderson impurity model *Kondo effect In physic ...
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Anderson Impurity Model
The Anderson impurity model, named after Philip Warren Anderson, is a Hamiltonian that is used to describe magnetic impurities embedded in metals. It is often applied to the description of Kondo effect-type problems, such as heavy fermion systems and Kondo insulators. In its simplest form, the model contains a term describing the kinetic energy of the conduction electrons, a two-level term with an on-site Coulomb repulsion that models the impurity energy levels, and a hybridization term that couples conduction and impurity orbitals. For a single impurity, the Hamiltonian takes the form :H = \sum_\epsilon_k c^_c_ + \sum_\epsilon_ d^_d_ + Ud^_d_d^_d_ + \sum_V_k(d^_c_ + c^_d_), where the c operator is the annihilation operator of a conduction electron, and d is the annihilation operator for the impurity, k is the conduction electron wavevector, and \sigma labels the spin. The on–site Coulomb repulsion is U, and V gives the hybridization. Regimes The model yields several reg ...
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John Robert Schrieffer
John Robert Schrieffer (; May 31, 1931 – July 27, 2019) was an American physicist who, with John Bardeen and Leon Cooper, was a recipient of the 1972 Nobel Prize in Physics for developing the BCS theory, the first successful quantum theory of superconductivity. Life and career Schrieffer was born in Oak Park, Illinois, the son of Louise (Anderson) and John Henry Schrieffer. His family moved in 1940 to Manhasset, New York, and then in 1947 to Eustis, Florida, where his father, a former pharmaceutical salesman, began a career in the citrus industry. In his Florida days, Schrieffer enjoyed playing with homemade rockets and ham radio, a hobby that sparked an interest in electrical engineering. After graduating from Eustis High School in 1949, Schrieffer was admitted to the Massachusetts Institute of Technology, where for two years he majored in electrical engineering before switching to physics in his junior year. He completed a bachelor's thesis on multiplets in heavy at ...
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Joaquin Mazdak Luttinger
Joaquin (Quin) Mazdak Luttinger (December 2, 1923 – April 6, 1997) was an American physicist well known for his contributions to the theory of interacting electrons in one-dimensional metals (the electrons in these metals are said to be in a Luttinger-liquid state) and the Fermi-liquid theory. He received his BS and PhD in physics from MIT in 1947. His brother was the physical chemist Lionel Luttinger (1920–2009) and his nephew is the mathematician Karl Murad Luttinger (born 1961). See also * Negative mass * Schrieffer–Wolff transformation * Wiener sausage * Fermi liquid * Many-body problem * Anomalous magnetic moment * Effective mass theory * k·p perturbation theory Notes Some publications (Note: For a complete list, seJ. Stat. Phys. 103, 641 (2001)) * W. Kohn, and J. M. Luttinger, ''Quantum Theory of Electrical Transport Phenomena'', Physical Review, Vol. 108, pp. 590–611 (1957)APS* W. Kohn, and J. M. Luttinger, ''Quantum Theory of Electrical Transport ...
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Walter Kohn
Walter Kohn (; March 9, 1923 – April 19, 2016) was an Austrian-American theoretical physicist and theoretical chemist. He was awarded, with John Pople, the Nobel Prize in Chemistry in 1998. The award recognized their contributions to the understandings of the electronic properties of materials. In particular, Kohn played the leading role in the development of density functional theory, which made it possible to calculate quantum mechanical electronic structure by equations involving the electronic density (rather than the many-body wavefunction). This computational simplification led to more accurate calculations on complex systems as well as many new insights, and it has become an essential tool for materials science, condensed-phase physics, and the chemical physics of atoms and molecules. Early years in Canada Kohn arrived in England as part of the Kindertransport rescue operation immediately after the annexation of Austria by Hitler. He was from a Jewish family, and has wr ...
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