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Quercitron
Quercitron is a yellow natural dye obtained from the bark of the Eastern Black Oak (''Quercus velutina''), a forest tree indigenous in North America. It was formerly called Dutch pink, English pink, or Italian pink. The name is a shortened form of quercicitron, from Latin ''quercus'', oak, and ''citron'', lemon, and was invented by Edward Bancroft (1744–1821), who by act of parliament in 1785 was granted special privileges in regard to the importation and use of the substance. The dyestuff is prepared by grinding the bark in mills after it has been freed from its black epidermal layer, and sifting the product to separate the fibrous matter, the fine yellow powder which remains forming the quercitron of commerce. The ruddy-orange decoction of quercitron contains quercitannic acid, whence its use in tanning, and an active dyeing principle, quercitrin, C21H20O11. The latter substance is a glycoside, and in aqueous solution under the influence of mineral acids it yields quercet ...
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Quercitrin
Quercitrin is a glycoside formed from the flavonoid quercetin and the deoxy sugar rhamnose. Austrian chemist Heinrich Hlasiwetz (1825-1875) is remembered for his chemical analysis of quercitrin. Occurrence Quercitrin is a constituent of the dye quercitron. It can be found in Tartary buckwheat (''Fagopyrum tataricum'') and in oaks species like the North American white oak (''Quercus alba'') and English oak (''Quercus robur'').Analysis of oak tannins by liquid chromatography-electrospray ionisation mass spectrometry. Pirjo Mämmelä, Heikki Savolainen, Lasse Lindroos, Juhani Kangas and Terttu Vartiainen, Journal of Chromatography A, Volume 891, Issue 1, 1 September 2000, Pages 75-83, It is also found in ''Nymphaea odorata'' or ''Taxillus kaempferi''.The constituents of Taxillus kaempferi and the host, Pinus thunbergii. I. Catechins and flavones of Taxillus kaempferi. Konishi T, Nishio T, Kiyosawa S, Fujiwara Y and Konoshima T, Yakugaku Zasshi., February 1996, volume 116, issue 2 ...
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Quercitrin
Quercitrin is a glycoside formed from the flavonoid quercetin and the deoxy sugar rhamnose. Austrian chemist Heinrich Hlasiwetz (1825-1875) is remembered for his chemical analysis of quercitrin. Occurrence Quercitrin is a constituent of the dye quercitron. It can be found in Tartary buckwheat (''Fagopyrum tataricum'') and in oaks species like the North American white oak (''Quercus alba'') and English oak (''Quercus robur'').Analysis of oak tannins by liquid chromatography-electrospray ionisation mass spectrometry. Pirjo Mämmelä, Heikki Savolainen, Lasse Lindroos, Juhani Kangas and Terttu Vartiainen, Journal of Chromatography A, Volume 891, Issue 1, 1 September 2000, Pages 75-83, It is also found in ''Nymphaea odorata'' or ''Taxillus kaempferi''.The constituents of Taxillus kaempferi and the host, Pinus thunbergii. I. Catechins and flavones of Taxillus kaempferi. Konishi T, Nishio T, Kiyosawa S, Fujiwara Y and Konoshima T, Yakugaku Zasshi., February 1996, volume 116, issue 2 ...
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Natural Dye
Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, and wood—and other biological sources such as fungi. Archaeologists have found evidence of textile dyeing dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years.Goodwin (1982), p. 11. The essential process of dyeing changed little over time. Typically, the dye material is put in a pot of water and heated to extract the dye compounds into solution with the water. Then the textiles to be dyed are added to the pot, and held at heat until the desired color is achieved. Textile fibre may be dyed before spinning or weaving ("dyed in the wool"), after spinning ("yarn-dyed") or after weaving ("piece-dyed"). Many natural dyes require the use of substances called mordants to bind the dye to the textile fibres. Mordants (from the Latin ver ...
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Eastern Black Oak
''Quercus velutina'', the black oak, is a species of oak in the red oak group (''Quercus'' sect. ''Lobatae''), native and widespread in eastern and central North America. It is sometimes called the eastern black oak. ''Quercus velutina'' was previously known as yellow oak due to the yellow pigment in its inner bark. It is a close relative of the California black oak (''Quercus kelloggii'') found in western North America. Description In the northern part of its range, black oak is a relatively small tree, reaching a height of and a diameter of , but it grows larger in the south and center of its range, where heights of up to are known. The leaves of the black oak are alternately arranged on the twig and are long with 5–7 bristle-tipped lobes separated by deep U-shaped notches. The upper surface of the leaf is a shiny deep green, the lower is yellowish-brown. There are also stellate hairs on the underside of the leaf that grow in clumps. Some key characteristics for identific ...
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Yellow
Yellow is the color between green and orange on the spectrum of light. It is evoked by light with a dominant wavelength of roughly 575585 nm. It is a primary color in subtractive color systems, used in painting or color printing. In the RGB color model, used to create colors on television and computer screens, yellow is a secondary color made by combining red and green at equal intensity. Carotenoids give the characteristic yellow color to autumn leaves, corn, canaries, daffodils, and lemons, as well as egg yolks, buttercups, and bananas. They absorb light energy and protect plants from photo damage in some cases. Sunlight has a slight yellowish hue when the Sun is near the horizon, due to atmospheric scattering of shorter wavelengths (green, blue, and violet). Because it was widely available, yellow ochre pigment was one of the first colors used in art; the Lascaux cave in France has a painting of a yellow horse 17,000 years old. Ochre and orpiment pigments were us ...
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Edward Bancroft
Edward Bartholomew Bancroft ( – September 7, 1821) was a Massachusetts-born physician and chemist who became a double agent, spying for both the United States and Great Britain while serving as secretary to the American Commission in Paris during the American Revolution. Early life Bancroft was born on January 20, 1745 in Westfield, Massachusetts. His father died of an epileptic seizure when Bancroft was two years old, and his mother remarried five years later to David Bull of Connecticut. There Bancroft studied under Silas Deane, a schoolmaster who later became an important politician and diplomat with whom he would work in Paris. At the age of sixteen, Bancroft was apprenticed to a physician in Killingworth, Connecticut, but after a few years ran away. (Bancroft returned and repaid his debt to his former master in 1766.) South America and London On July 14, 1763, after fleeing his apprenticeship, Bancroft left New England for the sugar-producing slave colonies of Dutch ...
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Quercitannic Acid
Quercitannic acid is one of the two forms of tannic acid found in oak bark and leaves. The other form is called gallotannic acid and is found in oak galls. The quercitannic acid molecule is also present in quercitron, a yellow dye obtained from the bark of the Eastern black oak (''Quercus velutina''), a forest tree indigenous in North America. It is described as a yellowish brown amorphous substance. In 1838, Jöns Jacob Berzelius wrote that quercitannate is used to dissolve morphine. In 1865 in the fifth volume of "A dictionary of chemistry", Henry Watts wrote : It exhibits with ferric salts the same reactions as gallotannic acid. It differs however from the latter in not being convertible into gallic acid, and not yielding pyrogallic acid by dry distillation. It is precipitated by sulfuric acid in red flocks. ( Stenhouse, Ann. Ch. Pharm. xlv. 16.) According to Rochleder (ibid lxiii. 202), the tannic acid of black tea is the same as that of oak-bark. In 1880, Etti gave for it ...
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Flavone
Flavone is an organic compound with the formula . A white solid, flavone is a derivative of chromone with a phenyl (Ph) substituent adjacent to the ether group. The compound is of little direct practical importance, but susbstituted derivatives, the flavones and flavonoids are a large class of nutritionally important natural products. Flavone can be prepared in the laboratory by cyclization of 2-hydroxacetophenone. Isomeric with flavone is isoflavone, where the phenyl group is adjacent to the ketone In organic chemistry, a ketone is a functional group with the structure R–C(=O)–R', where R and R' can be a variety of carbon-containing substituents. Ketones contain a carbonyl group –C(=O)– (which contains a carbon-oxygen double bo .... References {{Flavones ...
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Rhus Cotinus
''Cotinus coggygria'', syn. ''Rhus cotinus'', the European smoketree, Eurasian smoketree, smoke tree, smoke bush, Venetian sumach, or dyer's sumach, is a Eurasian species of flowering plant in the family Anacardiaceae. Description It is a multiple-branching deciduous shrub growing to tall with an open, spreading, irregular habit, only rarely forming a small tree. The leaves are long rounded ovals, green with a waxy glaucous sheen. The autumn colour can be strikingly varied, from peach and yellow to scarlet. The flowers are numerous, produced in large inflorescences long; each flower in diameter, with five pale yellow petals. Most of the flowers in each inflorescence abort, elongating into yellowish-pink to pinkish-purple feathery plumes (when viewed en masse these have a wispy 'smoke-like' appearance, hence the common name "smoke tree") which surround the small () drupaceous fruit that develop. Fossil record Macrofossils of ''C. coggygria'' from the early Pliocene epoch have ...
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Rose Petal
A rose is either a woody perennial flowering plant of the genus ''Rosa'' (), in the family Rosaceae (), or the flower it bears. There are over three hundred species and tens of thousands of cultivars. They form a group of plants that can be erect shrubs, climbing, or trailing, with stems that are often armed with sharp prickles. Their flowers vary in size and shape and are usually large and showy, in colours ranging from white through yellows and reds. Most species are native to Asia, with smaller numbers native to Europe, North America, and northwestern Africa. Species, cultivars and hybrids are all widely grown for their beauty and often are fragrant. Roses have acquired cultural significance in many societies. Rose plants range in size from compact, miniature roses, to climbers that can reach seven meters in height. Different species hybridize easily, and this has been used in the development of the wide range of garden roses. Etymology The name ''rose'' comes from Lati ...
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Arthur George Perkin
Arthur George Perkin DSc FRS FRSE (1861–1937) was an English chemist and Professor of Colour Chemistry and Dyeing at the University of Leeds. Life Perkin was the second son of Sir William Henry Perkin FRS, who founded the aniline dye industry, and was born on 13 December 1861 at Sudbury, close to his father's dyeworks at Greenford. His mother was Jemima Harriet Lissett (d.1862). His brother was William Henry Perkin, Jr., FRS, Professor of Chemistry at Manchester and Oxford universities. He was educated at the City of London School (1872–1878). He then studied Chemistry variously at the Royal College of Chemistry in London, Anderson's College in Glasgow, and Leeds University. In 1893 he was elected a Fellow of the Royal Society of Edinburgh. His proposers were Alexander Crum Brown, Sir Francis Grant Ogilvie, Alexander Buchan and his father, William Henry Perkin. He died in Headingley on 30 May 1937 and is buried with his wife in Adel Churchyard, in Leeds. Family Per ...
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Stanisław Kostanecki
Stanisław Kostanecki (born 16 April 1860 in Myszaków, now in Poland then Kingdom of Prussia – 15 November 1910 in Würzburg) was a Polish organic chemist, professor who pioneered in vegetable dye chemistry e.g. curcumin. Known for Kostanecki acylation name reactions. In 1896, he developed the theory of dyes and studied the natural vegetable dyes. Among his many students were famous scientists Kazimierz Funk Kazimierz Funk (; February 23, 1884 – November 19, 1967), commonly anglicized as Casimir Funk, was a Polish-American biochemist generally credited with being among the first to formulate (in 1912) the concept of vitamins, which he called "vita ... and Wiktor Lampe. 1860 births 1910 deaths Polish organic chemists {{Chemist-stub ...
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