Quercitrin
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Quercitrin
Quercitrin is a glycoside formed from the flavonoid quercetin and the deoxy sugar rhamnose. Austrian chemist Heinrich Hlasiwetz (1825-1875) is remembered for his chemical analysis of quercitrin. Occurrence Quercitrin is a constituent of the dye quercitron. It can be found in Tartary buckwheat (''Fagopyrum tataricum'') and in oaks species like the North American white oak (''Quercus alba'') and English oak (''Quercus robur'').Analysis of oak tannins by liquid chromatography-electrospray ionisation mass spectrometry. Pirjo Mämmelä, Heikki Savolainen, Lasse Lindroos, Juhani Kangas and Terttu Vartiainen, Journal of Chromatography A, Volume 891, Issue 1, 1 September 2000, Pages 75-83, It is also found in ''Nymphaea odorata ''Nymphaea odorata'', also known as the American white waterlily, fragrant water-lily, beaver root, fragrant white water lily, white water lily, sweet-scented white water lily, and sweet-scented water lily, is an aquatic plant belonging to the ge ...'' or ...
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Glycoside
In chemistry, a glycoside is a molecule in which a sugar is bound to another functional group via a glycosidic bond. Glycosides play numerous important roles in living organisms. Many plants store chemicals in the form of inactive glycosides. These can be activated by enzyme hydrolysis, which causes the sugar part to be broken off, making the chemical available for use. Many such plant glycosides are used as medications. Several species of ''Heliconius'' butterfly are capable of incorporating these plant compounds as a form of chemical defense against predators. In animals and humans, poisons are often bound to sugar molecules as part of their elimination from the body. In formal terms, a glycoside is any molecule in which a sugar group is bonded through its anomeric carbon to another group via a glycosidic bond. Glycosides can be linked by an O- (an '' O-glycoside''), N- (a '' glycosylamine''), S-(a '' thioglycoside''), or C- (a '' C-glycoside'') glycosidic bond. Accordin ...
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Heinrich Hlasiwetz
Heinrich Hlasiwetz (7 April 1825 – 7 October 1875) was an Austrian chemist born in Reichenberg, Bohemia. Son of a pharmacist, he studied at the University of Jena, where his instructors included Johann Wolfgang Döbereiner (1780-1849), Heinrich Wilhelm Ferdinand Wackenroder (1798-1854) and Matthias Jakob Schleiden (1804-1881). Later he studied under Josef Redtenbacher (1810–1870) in Prague. In 1848 he earned the diploma of ''Magister Pharmacia'', and during the following year received his doctorate in chemistry. In 1849 he began work as an assistant to Friedrich Rochleder (1819-1874), later becoming an associate professor of chemistry at the University of Innsbruck (1854). In 1867 he became a professor at the Vienna University of Technology, where from 1869 he represented general and analytical chemistry. During his career he largely worked with resins, tannins and protein compounds. Hlasiwetz is remembered for his chemical analysis of quercitrin, phloroglucinol, r ...
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Quercitron
Quercitron is a yellow natural dye obtained from the bark of the Eastern Black Oak (''Quercus velutina''), a forest tree indigenous in North America. It was formerly called Dutch pink, English pink, or Italian pink. The name is a shortened form of quercicitron, from Latin ''quercus'', oak, and ''citron'', lemon, and was invented by Edward Bancroft (1744–1821), who by act of parliament in 1785 was granted special privileges in regard to the importation and use of the substance. The dyestuff is prepared by grinding the bark in mills after it has been freed from its black epidermal layer, and sifting the product to separate the fibrous matter, the fine yellow powder which remains forming the quercitron of commerce. The ruddy-orange decoction of quercitron contains quercitannic acid, whence its use in tanning, and an active dyeing principle, quercitrin, C21H20O11. The latter substance is a glycoside, and in aqueous solution under the influence of mineral acids it yields querc ...
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Flavonoid
Flavonoids (or bioflavonoids; from the Latin word ''flavus'', meaning yellow, their color in nature) are a class of polyphenolic secondary metabolites found in plants, and thus commonly consumed in the diets of humans. Chemically, flavonoids have the general structure of a 15-carbon skeleton, which consists of two phenyl rings (A and B) and a heterocyclic ring (C, the ring containing the embedded oxygen). This carbon structure can be abbreviated C6-C3-C6. According to the IUPAC nomenclature, they can be classified into: *flavonoids or bioflavonoids * isoflavonoids, derived from 3-phenyl chromen-4-one (3-phenyl-1,4- benzopyrone) structure *neoflavonoids, derived from 4-phenyl coumarine (4-phenyl-1,2- benzopyrone) structure The three flavonoid classes above are all ketone-containing compounds and as such, anthoxanthins (flavones and flavonols). This class was the first to be termed bioflavonoids. The terms flavonoid and bioflavonoid have also been more loosely used to descri ...
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Quercetin
Quercetin is a plant flavonol from the flavonoid group of polyphenols. It is found in many fruits, vegetables, leaves, seeds, and grains; capers, red onions, and kale are common foods containing appreciable amounts of it. It has a bitter flavor and is used as an ingredient in dietary supplements, beverages, and foods. Occurrence Quercetin is a flavonoid widely distributed in nature. The name has been used since 1857, and is derived from ''quercetum'' (oak forest), after the oak genus ''Quercus''. It is a naturally occurring polar auxin transport inhibitor. Quercetin is one of the most abundant dietary flavonoids, with an average daily consumption of 25–50 milligrams. In red onions, higher concentrations of quercetin occur in the outermost rings and in the part closest to the root, the latter being the part of the plant with the highest concentration. One study found that organically grown tomatoes had 79% more quercetin than non-organically grown fruit. Quercetin is pres ...
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Deoxy Sugar
Deoxy sugars are sugars that have had a hydroxyl group replaced with a hydrogen atom. Examples include: * Deoxyribose, or 2-deoxy-D- ribose, a constituent of DNA * Fucose, or 6-deoxy-L-galactose, main component of fucoidan of brown algae, and present in N-linked glycans * Fuculose, or 6-deoxy-L- tagatose, one of the important components of avian influenza virus particles * Rhamnose, or 6-deoxy-L-mannose, present in plant glycosides In ''Escherichia coli'' bacteria, deoxyribose sugars are synthesized via two different pathways - one pathway involves aldol condensation, whereas the other pathway is conversion of a ribose sugar into a deoxyribose sugar by means of changes on the nucleotide or nucleoside level. Deoxyribose is synthesized through the reduction of ribose. Deoxyribose is derived from the same precursor as ribose being that the reduction of the sugar with the extra hydroxyl group results in the deoxy-sugar, which has its hydroxyl group replaced with a hydrogen ato ...
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Rhamnose
Rhamnose (Rha, Rham) is a naturally occurring deoxy sugar. It can be classified as either a methyl-pentose or a 6-deoxy- hexose. Rhamnose predominantly occurs in nature in its L-form as L-rhamnose (6-deoxy-L-mannose). This is unusual, since most of the naturally occurring sugars are in D-form. Exceptions are the methyl pentoses L- fucose and L-rhamnose and the pentose L-arabinose. However, examples of naturally-occurring D-rhamnose include some species of bacteria, such as ''Pseudomonas aeruginosa'' and '' Helicobacter pylori''. Rhamnose can be isolated from Buckthorn (''Rhamnus''), poison sumac, and plants in the genus '' Uncaria''. Rhamnose is also produced by microalgae belonging to class Bacillariophyceae (diatoms). Rhamnose is commonly bound to other sugars in nature. It is a common glycone component of glycosides from many plants. Rhamnose is also a component of the outer cell membrane of acid-fast bacteria in the ''Mycobacterium'' genus, which includes the organism th ...
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Fagopyrum Tataricum
''Fagopyrum tataricum'', also known as Tartary buckwheat, green buckwheat, ku qiao, Tatar buckwheat, or bitter buckwheat, is a domesticated food plant in the genus ''Fagopyrum'' in the family Polygonaceae. With another species in the same genus, common buckwheat, it is often counted as a cereal, but the buckwheats are not closely related to true cereals. Tartary buckwheat is more bitter and contains more rutin than common buckwheat. It also contains other bioactive components such as flavonoids, phenolic acids, 2-hydroxybenzylamine and quercitrin. Tartary buckwheat was domesticated in East Asia and is also cultivated in Europe and North America. While it is an unfamiliar food in the West, it is common in the Himalayan region today, as well as other regions in Southwest China such as Sichuan province. The plant has been cultivated in many parts of the world; however, when found among other crops it is considered a weed. Chemistry ''Fagopyrum tataricum'' contains aromatic ...
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Quercus Alba
An oak is a tree or shrub in the genus ''Quercus'' (; Latin "oak tree") of the beech family, Fagaceae. There are approximately 500 extant species of oaks. The common name "oak" also appears in the names of species in related genera, notably '' Lithocarpus'' (stone oaks), as well as in those of unrelated species such as '' Grevillea robusta'' (silky oaks) and the Casuarinaceae (she-oaks). The genus ''Quercus'' is native to the Northern Hemisphere, and includes deciduous and evergreen species extending from cool temperate to tropical latitudes in the Americas, Asia, Europe, and North Africa. North America has the largest number of oak species, with approximately 160 species in Mexico of which 109 are endemic and about 90 in the United States. The second greatest area of oak diversity is China, with approximately 100 species. Description Oaks have spirally arranged leaves, with lobate margins in many species; some have serrated leaves or entire leaves with smooth ma ...
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Quercus Robur
''Quercus robur'', commonly known as common oak, pedunculate oak, European oak or English oak, is a species of flowering plant in the beech and oak family, Fagaceae. It is a large tree, native to most of Europe west of the Caucasus. It is widely cultivated in temperate regions elsewhere and has escaped into the wild in scattered parts of China and North America. Description ''Quercus robur'' is a large deciduous tree, with circumference of grand oaks from to an exceptional . The Majesty Oak with a circumference of is the thickest tree in Great Britain. The Brureika (Bridal Oak) in Norway with a circumference of (2018) and the Kaive Oak in Latvia with a circumference of are among the thickest trees in Northern Europe. The largest historical oak was known as the Imperial Oak from Bosnia and Herzegovina. This specimen was recorded at 17.5 m in circumference at breast height and estimated at over 150 m³ in total volume. It collapsed in 1998. The species has lobed and nea ...
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Nymphaea Odorata
''Nymphaea odorata'', also known as the American white waterlily, fragrant water-lily, beaver root, fragrant white water lily, white water lily, sweet-scented white water lily, and sweet-scented water lily, is an aquatic plant belonging to the genus '' Nymphaea''. It can commonly be found in shallow lakes, ponds, and permanent slow moving waters throughout North America where it ranges from Central America to northern Canada. It is also reported from Brazil and Guyana. Description This plant is rooted from a branched rhizomes which gives rise to long petioles which terminate in smooth floating leaves. Since the leaves are subject to tearing by water and waves, they are round with a waxy upper coating that is water-repellent. The flowers also float. They are radially symmetric with prominent yellow stamens and many white petals. The flowers open each day and close again each night and are very fragrant. Once the flowers are pollinated, the developing fruit is pulled back un ...
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Taxillus Kaempferi
''Taxillus kaempferi'' () is a parasitic plant A parasitic plant is a plant that derives some or all of its nutritional requirements from another living plant. They make up about 1% of angiosperms and are found in almost every biome. All parasitic plants develop a specialized organ called th ... species in the genus '' Taxillus'' found in China (Anhui, Fujian, W Hubei, S Jiangxi, Sichuan, S Zhejiang), Bhutan and Japan. Its host is '' Pinus thunbergii''.The constituents of Taxillus kaempferi and the host, Pinus thunbergii. I. Catechins and flavones of Taxillus kaempferi. Konishi T, Nishio T, Kiyosawa S, Fujiwara Y and Konoshima T, Yakugaku Zasshi., February 1996, volume 116, issue 2, pages 148-157 (article in Japanese) The flavonol avicularin can be produced from ''T. kaempferi''.Avicularin, a plant flavonoid, suppresses lipid accumulation through repression of C/EBPα-activated GLUT4-mediated glucose uptake in 3T3-L1 cells. Fujimori K and Shibano M, J Agric Food Chem., 29 May ...
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