Patrick L. Holland
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Patrick L. Holland
Patrick L. Holland (born 1971) is the Conkey P. Whitehead Professor of Chemistry at Yale University. Holland's research focuses on low-coordinate and high-spin coordination complexes of iron and cobalt, that react with small molecules such as alkenes, arenes, and N2. Early life and education Holland was born in 1971 in Pennsylvania. During his childhood, he lived in Ohio until he was 12, when his family moved to Florida. Holland attended Terry Parker High School in Jacksonville, Florida, graduating in 1989. He then attended Princeton University, graduating with his A.B. in 1993. Following graduation, Holland pursued graduate studies at the University of California, Berkeley with Prof. Robert G. Bergman and Prof. Richard A. Andersen, earning his Ph.D. in 1997. At Berkeley, Holland synthesized cyclopentadienyl nickel complexes with amido, and alkoxo ligands. He then conducted postdoctoral studies as an NIH Postdoctoral Fellow with Prof. William Tolman at the University of Mi ...
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Pennsylvania
Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, Maryland to its south, West Virginia to its southwest, Ohio to its west, Lake Erie and the Canadian province of Ontario to its northwest, New York to its north, and the Delaware River and New Jersey to its east. Pennsylvania is the fifth-most populous state in the nation with over 13 million residents as of 2020. It is the 33rd-largest state by area and ranks ninth among all states in population density. The southeastern Delaware Valley metropolitan area comprises and surrounds Philadelphia, the state's largest and nation's sixth most populous city. Another 2.37 million reside in Greater Pittsburgh in the southwest, centered around Pittsburgh, the state's second-largest and Western Pennsylvania's largest city. The state's su ...
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Aromatic Compound
Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one or more aromatic rings. The parent member of aromatic compounds is benzene. The word "aromatic" originates from the past grouping of molecules based on smell, before their general chemical properties are understood. The current definition of aromatic compounds does not have any relation with their smell. Heteroarenes are closely related, since at least one carbon atom of CH group is replaced by one of the heteroatoms oxygen, nitrogen, or sulfur. Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one nitrogen atom. Hydrocarbons without an aromatic ring are called Aliphatic compound, aliphatic. Benzene ring model Benzene, C6H6, is the least complex aromatic hydrocarbon, and it was the fir ...
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Chemical Science (journal)
''Chemical Science'' is a weekly peer-reviewed scientific journal covering all aspects of chemistry. It is the flagship journal of the Royal Society of Chemistry. It was established in July 2010 and is published by the Royal Society of Chemistry; before 2018, it was published monthly. It won the Best New Journal 2011 award from the Association of Learned and Professional Society Publishers. The editor-in-chief is Andrew Ian Cooper (University of Liverpool). In January 2015, the journal moved to an open access publishing model. Abstracting and indexing The journal is abstracted and indexed in: *Science Citation Index Expanded *Current Contents/Physical, Chemical & Earth Sciences *Chemical Abstracts Service *Directory of Open Access Journals According to the ''Journal Citation Reports'', the journal has a 2021 impact factor of 9.969. See also * ''Chemical Communications'' * ''Chemical Society Reviews ''Chemical Society Reviews'' is a biweekly peer-reviewed scientific journal pub ...
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American Association For The Advancement Of Science
The American Association for the Advancement of Science (AAAS) is an American international non-profit organization with the stated goals of promoting cooperation among scientists, defending scientific freedom, encouraging scientific responsibility, and supporting scientific education and science outreach for the betterment of all humanity. It is the world's largest general scientific society, with over 120,000 members, and is the publisher of the well-known scientific journal ''Science''. History Creation The American Association for the Advancement of Science was created on September 20, 1848, at the Academy of Natural Sciences in Philadelphia, Pennsylvania. It was a reformation of the Association of American Geologists and Naturalists. The society chose William Charles Redfield as their first president because he had proposed the most comprehensive plans for the organization. According to the first constitution which was agreed to at the September 20 meeting, the goal of ...
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National Science Foundation CAREER Awards
The National Science Foundation CAREER awards, presented by the National Science Foundation (NSF), are in support of junior faculty who exemplify the role of teacher-scholars through research and education, and the integration of these endeavors in the context of their organizations' missions. The awards, presented once each year, include a federal grant for research and education activities for five consecutive years. History The Presidential Young Investigators (PYI) program was initiated in 1983, and remained active until the NSF New Young Investigators (NYI) program replaced it in 1992. Both programs were research-oriented, and funded an average of 200 faculty members per year. Another, more selective program began in 1992, when the White House asked NSF to institute the Presidential Faculty Fellows (PFF) program. It awarded young faculty up to $100,000 per year for five years, with no matching-fund option, and put more emphasis on education and outreach. In 1994, the Faculty ...
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Sloan Research Fellowship
The Sloan Research Fellowships are awarded annually by the Alfred P. Sloan Foundation since 1955 to "provide support and recognition to early-career scientists and scholars". This program is one of the oldest of its kind in the United States. Fellowships were initially awarded in physics, chemistry, and mathematics. Awards were later added in neuroscience (1972), economics (1980), computer science (1993), computational and evolutionary molecular biology (2002), and ocean sciences or earth systems sciences (2012). Winners of these two-year fellowships are awarded $75,000, which may be spent on any expense supporting their research. From 2012 through 2020, the foundation awarded 126 research fellowship each year; in 2021, 128 were awarded, and 118 were awarded in 2022. Eligibility and selection To be eligible, a candidate must hold a Ph.D. or equivalent degree and must be a member of the faculty of a college, university, or other degree-granting institution in the United Stat ...
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Alexander Von Humboldt Foundation
The Alexander von Humboldt Foundation (german: Alexander von Humboldt-Stiftung) is a foundation established by the government of the Federal Republic of Germany and funded by the Federal Foreign Office, the Federal Ministry of Education and Research, the Federal Ministry for Economic Cooperation and Development as well as other national and international partners; it promotes international academic cooperation between excellent scientists and scholars from Germany and from abroad. Description Every year, the Foundation grants more than 700 competitive research fellowships and awards, primarily going to academics from natural sciences (mathematics included) and the humanities. It allows scientists and scholars from all over the world to come to Germany to work on a research project they have chosen themselves together with a host and collaborative partner. Additionally it funds German scholars' via the Feodor Lynen Fellowships to go anywhere in the world to work on a research proj ...
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Blavatnik Awards For Young Scientists
Blavatnik Awards for Young Scientists was established in 2007 through a partnership between the Blavatnik Family Foundation, headed by Leonard Blavatnik (Russian: Леонид Валентинович Блаватник), chairman of Access Industries, and the New York Academy of Sciences, headed by president Nicholas Dirks. These cash grant awards are given annually to selected faculty and postdoctoral researchers age 42 years and younger who work in the life and physical sciences and engineering at institutions in New York, New Jersey, and Connecticut. The first Blavatnik Awards were given in New York City on Monday, November 12, 2007. On June 3, 2013, the Blavatnik Family Foundation and the New York Academy of Sciences announced the expansion of the faculty competition to include young scientists from institutions throughout the United States. In April 2017, the Blavatnik Awards program was expanded to the United Kingdom (UK) and Israel. By the end of 2022, the Blavatnik Awards ...
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Copper Protein
Copper proteins are proteins that contain one or more copper ions as prosthetic groups. Copper proteins are found in all forms of air-breathing life. These proteins are usually associated with electron-transfer with or without the involvement of oxygen (O2). Some organisms even use copper proteins to carry oxygen instead of iron proteins. A prominent copper proteins in humans is in cytochrome c oxidase (cco). The enzyme cco mediates the controlled combustion that produces ATP. Classes The metal centers in the copper proteins can be classified into several types: *Type I copper centres (T1Cu) are characterized by a single copper atom coordinated by two histidine residues and a cysteine residue in a trigonal planar structure, and a variable axial ligand. In class I T1Cu proteins (e.g. amicyanin, plastocyanin and pseudoazurin) the axial ligand is the sulfur of methionine, whereas aminoacids other than methionine (e.g. glutamine) give rise to class II T1Cu copper proteins ...
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William B
William is a male given name of Germanic origin.Hanks, Hardcastle and Hodges, ''Oxford Dictionary of First Names'', Oxford University Press, 2nd edition, , p. 276. It became very popular in the English language after the Norman conquest of England in 1066,All Things William"Meaning & Origin of the Name"/ref> and remained so throughout the Middle Ages and into the modern era. It is sometimes abbreviated "Wm." Shortened familiar versions in English include Will, Wills, Willy, Willie, Bill, and Billy. A common Irish form is Liam. Scottish diminutives include Wull, Willie or Wullie (as in Oor Wullie or the play ''Douglas''). Female forms are Willa, Willemina, Wilma and Wilhelmina. Etymology William is related to the given name ''Wilhelm'' (cf. Proto-Germanic ᚹᛁᛚᛃᚨᚺᛖᛚᛗᚨᛉ, ''*Wiljahelmaz'' > German ''Wilhelm'' and Old Norse ᚢᛁᛚᛋᛅᚼᛅᛚᛘᛅᛋ, ''Vilhjálmr''). By regular sound changes, the native, inherited English form of the name should b ...
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Alkoxide
In chemistry, an alkoxide is the conjugate base of an alcohol and therefore consists of an organic group bonded to a negatively charged oxygen atom. They are written as , where R is the organic substituent. Alkoxides are strong bases and, when R is not bulky, good nucleophiles and good ligands. Alkoxides, although generally not stable in protic solvents such as water, occur widely as intermediates in various reactions, including the Williamson ether synthesis. Transition metal alkoxides are widely used for coatings and as catalysts. Enolates are unsaturated alkoxides derived by deprotonation of a bond adjacent to a ketone or aldehyde. The nucleophilic center for simple alkoxides is located on the oxygen, whereas the nucleophilic site on enolates is delocalized onto both carbon and oxygen sites. Ynolates are also unsaturated alkoxides derived from acetylenic alcohols. Phenoxides are close relatives of the alkoxides, in which the alkyl group is replaced by a derivative of be ...
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Metal Amides
Metal amides (systematic name metal azanides) are a class of coordination compounds composed of a metal center with amide ligands of the form NR2−. Amide ligands have two electron pairs available for bonding. In principle, they can be terminal or bridging. In these two examples, the dimethylamido ligands are both bridging and terminal: File:Tris(dimethylamino)aluminium dimer.png, Tris(dimethylamino)aluminium dimer File:Tris(dimethylamino)gallium dimer.png, Tris(dimethylamino)gallium dimer File:Ti(NMe2)4.png, Tetrakis(dimethylamino)titanium File:Ta(NMe2)5.png, Pentakis(dimethylamido)tantalum In practice, bulky amide ligands have a lesser tendency to bridge. Amide ligands may participate in metal-ligand π-bonding giving a complex with the metal center being co-planar with the nitrogen and substituents. Metal bis(trimethylsilyl)amides form a significant subcategory of metal amide compounds. These compounds tend to be discrete and soluble in organic solvents. Alkali metal amid ...
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