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Pu-242
Plutonium-242 (242Pu or Pu-242) is one of the isotopes of plutonium, the second longest-lived, with a half-life of 375,000 years. The half-life of 242Pu is about 15 times that of 239Pu; so it is one-fifteenth as radioactive, and not one of the larger contributors to nuclear waste radioactivity. 242Pu's gamma ray emissions are also weaker than those of the other isotopes. It is not fissile (but it is fissionable by fast neutrons) and its neutron capture cross section is also low. In the nuclear fuel cycle Plutonium-242 is produced by successive neutron capture on 239Pu, 240Pu, and 241Pu. The odd-mass isotopes 239Pu and 241Pu have about a 3/4 chance of undergoing fission on capture of a thermal neutron and about a 1/4 chance of retaining the neutron and becoming the following isotope. The proportion of 242Pu is low at low burnup but increases nonlinearly. Plutonium-242 has a particularly low cross section for thermal neutron capture; and it takes three neutron absorptions to ...
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Isotopes Of Plutonium
Plutonium (94Pu) is an artificial element, except for trace quantities resulting from neutron capture by uranium, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized long before being found in nature, the first isotope synthesized being 238Pu in 1940. Twenty plutonium radioisotopes have been characterized. The most stable are plutonium-244 with a half-life of 80.8 million years, plutonium-242 with a half-life of 373,300 years, and plutonium-239 with a half-life of 24,110 years. All of the remaining radioactive isotopes have half-lives that are less than 7,000 years. This element also has eight meta states; all have half-lives of less than one second. The isotopes of plutonium range in atomic weight from 228.0387  u (228Pu) to 247.074 u (247Pu). The primary decay modes before the most stable isotope, 244Pu, are spontaneous fission and alpha emission; the primary mode after is beta emission. The pri ...
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Neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, and each has a mass of approximately one atomic mass unit, they are both referred to as nucleons. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks. The chemical properties of an atom are mostly determined by the configuration of electrons that orbit the atom's heavy nucleus. The electron configuration is determined by the charge of the nucleus, which is determined by the number of protons, or atomic number. The number of neutrons is the neutron number. Neutrons do not affect the electron configuration, but the sum of atomic and neutron numbers is the mass of the nucleus. Atoms of a chemical element t ...
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Actinides
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Since ''actinoid'' literally means ''actinium-like'' (cf. ''humanoid'' or ''android''), it has been argued for semantic reasons that actinium cannot logically be an actinoid, but IUPAC acknowledges its inclusion based on common usage. All the actinides are f-block elements, except the final one (lawrencium) which is a d-block element. Actinium has sometimes been considered d-block instead of lawrencium, but the clas ...
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Spontaneous Fission
Spontaneous fission (SF) is a form of radioactive decay that is found only in very heavy chemical elements. The nuclear binding energy of the elements reaches its maximum at an atomic mass number of about 56 (e.g., iron-56); spontaneous breakdown into smaller nuclei and a few isolated nuclear particles becomes possible at greater atomic mass numbers. History By 1908, physicists understood that alpha decay involved ejection of helium nuclei from a decaying atom. Like cluster decay, alpha decay is not typically categorized as a process of fission. The first nuclear fission process discovered was fission induced by neutrons. Because cosmic rays produce some neutrons, it was difficult to distinguish between induced and spontaneous events. Cosmic rays can be reliably shielded by a thick layer of rock or water. Spontaneous fission was identified in 1940 by Soviet physicists Georgy Flyorov and Konstantin Petrzhak by their observations of uranium in the Moscow Metro Dinamo station ...
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Uranium Series
In nuclear science, the decay chain refers to a series of radioactive decays of different radioactive decay products as a sequential series of transformations. It is also known as a "radioactive cascade". Most radioisotopes do not decay directly to a stable state, but rather undergo a series of decays until eventually a stable isotope is reached. Decay stages are referred to by their relationship to previous or subsequent stages. A ''parent isotope'' is one that undergoes decay to form a ''daughter isotope''. One example of this is uranium (atomic number 92) decaying into thorium (atomic number 90). The daughter isotope may be stable or it may decay to form a daughter isotope of its own. The daughter of a daughter isotope is sometimes called a ''granddaughter isotope''. The time it takes for a single parent atom to decay to an atom of its daughter isotope can vary widely, not only between different parent-daughter pairs, but also randomly between identical pairings of parent ...
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Alpha Decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus) and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. It has a charge of and a mass of . For example, uranium-238 decays to form thorium-234. While alpha particles have a charge , this is not usually shown because a nuclear equation describes a nuclear reaction without considering the electrons – a convention that does not imply that the nuclei necessarily occur in neutral atoms. Alpha decay typically occurs in the heaviest nuclides. Theoretically, it can occur only in nuclei somewhat heavier than nickel (element 28), where the overall binding energy per nucleon is no longer a maximum and the nuclides are therefore unstable toward spontaneou ...
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Uranium-238
Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is ''fertile'', meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control. Around 99.284% of natural uranium's mass is uranium-238, which has a half-life of 1.41 seconds (4.468 years, or 4.468 billion years). Due to its natural abundance and half-life relative to other radioactive elements, 238U produces ~40% of the radioactive heat produced within th ...
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Fast Reactor
A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons (carrying energies above 1 MeV or greater, on average), as opposed to slow thermal neutrons used in thermal-neutron reactors. Such a fast reactor needs no neutron moderator, but requires fuel that is relatively rich in fissile material when compared to that required for a thermal-neutron reactor. Around 20 land based fast reactors have been built, accumulating over 400 reactor years of operation globally. The largest of this was the Superphénix Sodium cooled fast reactor in France that was designed to deliver 1,242 MWe. Fast reactors have been intensely studied since the 1950s, as they provide certain decisive advantages over the existing fleet of water cooled and water moderated reactors. These are: * More neutrons are produced when a fission occurs, resulting from the absorption of a fast neutron, t ...
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Thermal Reactor
A thermal-neutron reactor is a nuclear reactor that uses slow or thermal neutrons. ("Thermal" does not mean hot in an absolute sense, but means in thermal equilibrium with the medium it is interacting with, the reactor's fuel, moderator and structure, which is much lower energy than the fast neutrons initially produced by fission.) Most nuclear power plant reactors are thermal reactors and use a neutron moderator to slow neutrons until they approach the average kinetic energy of the surrounding particles, that is, to reduce the speed of the neutrons to low-velocity, thermal neutrons. Neutrons are uncharged, this allows them to penetrate deep in the target and close to the nuclei,Squires, G.L. (2012, March 29). Introduction of the Theory of Thermal Neutron Scattering. https://books.google.com/books?hl=en&lr=&id=KUVD8KJt7_0C&oi=fnd&pg=PR9&dq=thermal-neutron+reactor&ots=1tn_4dppSF&sig=QDWkMU5-iW8_4GCXjItypUchKBQ#v=onepage&q=thermal-neutron%20reactor&f=false thus scattering neutrons by ...
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Californium
Californium is a radioactive chemical element with the symbol Cf and atomic number 98. The element was first synthesized in 1950 at Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory), by bombarding curium with alpha particles ( helium-4 ions). It is an actinide element, the sixth transuranium element to be synthesized, and has the second-highest atomic mass of all elements that have been produced in amounts large enough to see with the naked eye (after einsteinium). The element was named after the university and the U.S. state of California. Two crystalline forms exist for californium at normal pressure: one above and one below . A third form exists at high pressure. Californium slowly tarnishes in air at room temperature. Californium compounds are dominated by the +3 oxidation state. The most stable of californium's twenty known isotopes is californium-251, with a half-life of 898 years. This short half-life means the element is ...
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Actinide
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide. The 1985 IUPAC ''Red Book'' recommends that ''actinoid'' be used rather than ''actinide'', since the suffix ''-ide'' normally indicates a negative ion. However, owing to widespread current use, ''actinide'' is still allowed. Since ''actinoid'' literally means ''actinium-like'' (cf. ''humanoid'' or ''android''), it has been argued for semantic reasons that actinium cannot logically be an actinoid, but IUPAC acknowledges its inclusion based on common usage. All the actinides are f-block elements, except the final one (lawrencium) which is a d-block element. Actinium has sometimes been considered d-block instead of lawrencium, but the class ...
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Nuclear Fission
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radioactive decay. Nuclear fission of heavy elements was discovered on Monday 19 December 1938, by German chemist Otto Hahn and his assistant Fritz Strassmann in cooperation with Austrian-Swedish physicist Lise Meitner. Hahn understood that a "burst" of the atomic nuclei had occurred. Meitner explained it theoretically in January 1939 along with her nephew Otto Robert Frisch. Frisch named the process by analogy with biological fission of living cells. For heavy nuclides, it is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments (heating the bulk material where fission takes place). Like nuclear fusion, for fission to produce energy, the total binding energy ...
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