Californium is a
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
chemical element
A chemical element is a species of atoms that have a given number of protons in their nuclei, including the pure substance consisting only of that species. Unlike chemical compounds, chemical elements cannot be broken down into simpler sub ...
with the
symbol Cf and
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
98. The element was first synthesized in 1950 at
Lawrence Berkeley National Laboratory (then the University of California Radiation Laboratory), by bombarding
curium with
alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be pr ...
s (
helium-4 ion
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s). It is an
actinide
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The info ...
element, the sixth
transuranium element
The transuranium elements (also known as transuranic elements) are the chemical elements with atomic numbers greater than 92, which is the atomic number of uranium. All of these elements are unstable and decay radioactively into other elements. ...
to be
synthesized, and has the second-highest atomic mass of all elements that have been produced in amounts large enough to see with the
naked eye
Naked eye, also called bare eye or unaided eye, is the practice of engaging in visual perception unaided by a magnifying, light-collecting optical instrument, such as a telescope or microscope, or eye protection. Vision corrected to normal ...
(after
einsteinium
Einsteinium is a synthetic element with the symbol Es and atomic number 99. Einsteinium is a member of the actinide series and it is the seventh transuranium element. It was named in honor of Albert Einstein.
Einsteinium was discovered as a com ...
). The element was named after the university and the
U.S. state
In the United States, a state is a constituent political entity, of which there are 50. Bound together in a political union, each state holds governmental jurisdiction over a separate and defined geographic territory where it shares its sove ...
of
California
California is a state in the Western United States, located along the Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the most populous U.S. state and the 3rd largest by area. It is also the m ...
.
Two
crystalline forms exist for californium at normal pressure: one above and one below . A third form exists at high pressure. Californium slowly tarnishes in air at room temperature.
Californium compounds are dominated by the +3
oxidation state
In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to different atoms were fully ionic. It describes the degree of oxidation (loss of electrons) of an atom in a chemical compound. C ...
. The most stable of californium's twenty known
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s is californium-251, with a
half-life of 898 years. This short half-life means the element is not found in significant quantities in the Earth's crust.
252Cf, with a half-life of about 2.645 years, is the most common isotope used and is produced at
Oak Ridge National Laboratory in the United States and
Research Institute of Atomic Reactors in Russia.
Californium is one of the few transuranium elements with practical applications. Most of these applications exploit the property of certain
isotopes of californium to emit
neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beh ...
s. For example, californium can be used to help start up
nuclear reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
s, and it is employed as a source of neutrons when studying materials using
neutron diffraction
Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of thermal or cold neutrons to o ...
and
neutron spectroscopy. Californium can also be used in nuclear synthesis of higher mass elements;
oganesson
Oganesson is a synthetic chemical element with the symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint team of Russian and American scient ...
(element 118) was synthesized by bombarding californium-249 atoms with
calcium-48
Calcium-48 is a scarce isotope of calcium containing 20 protons and 28 neutrons. It makes up 0.187% of natural calcium by mole fraction. Although it is unusually neutron-rich for such a light nucleus, its beta decay is extremely hindered, and so ...
ions. Users of californium must take into account radiological concerns and the element's ability to disrupt the formation of
red blood cell
Red blood cells (RBCs), also referred to as red cells, red blood corpuscles (in humans or other animals not having nucleus in red blood cells), haematids, erythroid cells or erythrocytes (from Greek ''erythros'' for "red" and ''kytos'' for "holl ...
s by
bioaccumulating in skeletal tissue.
Characteristics
Physical properties
Californium is a silvery-white
actinide
The actinide () or actinoid () series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The info ...
metal with a
melting point
The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...
of and an estimated
boiling point of . The pure metal is malleable and is easily cut with a razor blade. Californium metal starts to vaporize above when exposed to a vacuum. Below californium metal is either
ferromagnetic or
ferrimagnetic
A ferrimagnetic material is a material that has populations of atoms with opposing magnetic moments, as in antiferromagnetism, but these moments are unequal in magnitude so a spontaneous magnetization remains. This can for example occur when ...
(it acts like a magnet), between 48 and 66 K it is
antiferromagnetic
In materials that exhibit antiferromagnetism, the magnetic moments of atoms or molecules, usually related to the spins of electrons, align in a regular pattern with neighboring spins (on different sublattices) pointing in opposite directions. ...
(an intermediate state), and above it is
paramagnetic
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, ...
(external magnetic fields can make it magnetic). It forms
alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...
s with
lanthanide metals but little is known about the resulting materials.
The element has two
crystalline forms at
standard atmospheric pressure
The standard atmosphere (symbol: atm) is a unit of pressure defined as Pa. It is sometimes used as a ''reference pressure'' or ''standard pressure''. It is approximately equal to Earth's average atmospheric pressure at sea level.
History
The s ...
: a double-
hexagonal close-packed
In geometry, close-packing of equal spheres is a dense arrangement of congruent spheres in an infinite, regular arrangement (or lattice). Carl Friedrich Gauss proved that the highest average density – that is, the greatest fraction of space occu ...
form dubbed alpha (α) and a
face-centered cubic
In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals.
There are three main varieties of ...
form designated beta (β). The α form exists below 600–800 °C with a density of 15.10 g/cm
3 and the β form exists above 600–800 °C with a density of 8.74 g/cm
3. At 48
GPa
Grading in education is the process of applying standardized measurements for varying levels of achievements in a course. Grades can be assigned as letters (usually A through F), as a range (for example, 1 to 6), as a percentage, or as a numbe ...
of pressure the β form changes into an
orthorhombic crystal system
In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
due to delocalization of the atom's
5f electrons, which frees them to bond.
The
bulk modulus of a material is a measure of its resistance to uniform pressure. Californium's bulk modulus is , which is similar to trivalent lanthanide metals but smaller than more familiar metals, such as aluminium (70 GPa).
Chemical properties and compounds
Californium exhibits oxidation states of 4, 3, or 2. It typically forms eight or nine bonds to surrounding atoms or ions. Its chemical properties are predicted to be similar to other primarily 3+ valence actinide elements and the element
dysprosium, which is the lanthanide above californium in the periodic table. Compounds in the +4 oxidation state are strong
oxidizing agent
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ). In other words, an oxi ...
s and those in the +2 state are strong
reducing agents.
The element slowly tarnishes in air at room temperature, with the rate increasing when moisture is added. Californium reacts when heated with
hydrogen
Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
,
nitrogen
Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
, or a
chalcogen
The chalcogens (ore forming) ( ) are the chemical elements in group 16 of the periodic table. This group is also known as the oxygen family. Group 16 consists of the elements oxygen (O), sulfur (S), selenium (Se), tellurium (Te), and the radioac ...
(oxygen family element); reactions with dry hydrogen and aqueous
mineral acid
A mineral acid (or inorganic acid) is an acid derived from one or more inorganic compounds, as opposed to organic acids which are acidic, organic compounds. All mineral acids form hydrogen ions and the conjugate base when dissolved in water.
Cha ...
s are rapid.
Californium is only
water-soluble as the californium(III)
cation. Attempts to
reduce or oxidize the +3 ion in solution have failed. The element forms a water-soluble
chloride
The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride sa ...
,
nitrate,
perchlorate, and
sulfate
The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
and is precipitated as a
fluoride,
oxalate
Oxalate (IUPAC: ethanedioate) is an anion with the formula C2O42−. This dianion is colorless. It occurs naturally, including in some foods. It forms a variety of salts, for example sodium oxalate (Na2C2O4), and several esters such as dimethyl ...
, or
hydroxide. Californium is the heaviest actinide to exhibit covalent properties, as is observed in the californium borate.
Isotopes
Twenty
isotope
Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s of californium are known (
mass number
The mass number (symbol ''A'', from the German word ''Atomgewicht'' tomic weight, also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approxima ...
ranging from 237 to 256
); the most stable are
251Cf with
half-life 898 years,
249Cf with half-life 351 years,
250Cf with half-life 13.08 years, and
252Cf with half-life 2.645 years.
All other isotopes have half-life shorter than a year, and most of these have half-life less than 20 minutes.
249Cf is formed from
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
of berkelium-249, and most other californium isotopes are made by subjecting berkelium to intense neutron radiation in a
nuclear reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
. Though californium-251 has the longest half-life, its production yield is only 10% due to its tendency to collect neutrons (high
neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, ...
) and its tendency to interact with other particles (high
neutron cross section
In nuclear physics, the concept of a neutron cross section is used to express the likelihood of interaction between an incident neutron and a target nucleus. The neutron cross section σ can be defined as the area in cm2 for which the number of ...
).
Californium-252 is a very strong
neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons beh ...
emitter, which makes it extremely
radioactive
Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
and harmful.
252Cf, 96.9% of the time,
alpha decay
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus) and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an atom ...
s to
curium-248; the other 3.1% of decays are
spontaneous fission
Spontaneous fission (SF) is a form of radioactive decay that is found only in very heavy chemical elements. The nuclear binding energy of the elements reaches its maximum at an atomic mass number of about 56 (e.g., iron-56); spontaneous breakdo ...
.
One
microgram
In the metric system, a microgram or microgramme is a unit of mass equal to one millionth () of a gram. The unit symbol is μg according to the International System of Units (SI); the recommended symbol in the United States and United Kingdom whe ...
(μg) of
252Cf emits 2.3 million neutrons per second, an average of 3.7 neutrons per spontaneous fission.
Most other isotopes of californium, alpha decay to curium (
atomic number
The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of an atomic nucleus. For ordinary nuclei, this is equal to the proton number (''n''p) or the number of protons found in the nucleus of every ...
96).
History
![Berkeley 60-inch cyclotron](https://upload.wikimedia.org/wikipedia/commons/a/af/Berkeley_60-inch_cyclotron.jpg)
Californium was
first made at
University of California
The University of California (UC) is a public land-grant research university system in the U.S. state of California. The system is composed of the campuses at Berkeley, Davis, Irvine, Los Angeles, Merced, Riverside, San Diego, San Francisco, ...
Radiation Laboratory
The Radiation Laboratory, commonly called the Rad Lab, was a microwave and radar research laboratory located at the Massachusetts Institute of Technology (MIT) in Cambridge, Massachusetts. It was first created in October 1940 and operated until 31 ...
,
Berkeley
Berkeley most often refers to:
*Berkeley, California, a city in the United States
**University of California, Berkeley, a public university in Berkeley, California
* George Berkeley (1685–1753), Anglo-Irish philosopher
Berkeley may also refer ...
, by physics researchers
Stanley Gerald Thompson,
Kenneth Street Jr.,
Albert Ghiorso
Albert Ghiorso (July 15, 1915 – December 26, 2010) was an American nuclear scientist and co-discoverer of a record 12 chemical elements on the periodic table. His research career spanned six decades, from the early 1940s to the late 1990s.
Biog ...
, and
Glenn T. Seaborg
Glenn Theodore Seaborg (; April 19, 1912February 25, 1999) was an American chemist whose involvement in the synthesis, discovery and investigation of ten transuranium elements earned him a share of the 1951 Nobel Prize in Chemistry. His work i ...
, about February 9, 1950. It was the sixth
transuranium element
The transuranium elements (also known as transuranic elements) are the chemical elements with atomic numbers greater than 92, which is the atomic number of uranium. All of these elements are unstable and decay radioactively into other elements. ...
to be discovered; the team announced its discovery on March 17, 1950.
To produce californium, a microgram-size target of curium-242 () was bombarded with 35 MeV
alpha particle
Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be pr ...
s () in the
cyclotron
A cyclotron is a type of particle accelerator invented by Ernest O. Lawrence in 1929–1930 at the University of California, Berkeley, and patented in 1932. Lawrence, Ernest O. ''Method and apparatus for the acceleration of ions'', filed: Janu ...
at Berkeley, which produced californium-245 () plus one
free neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave ...
().
: + → +
To identify and separate out the element,
ion exchange
Ion exchange is a reversible interchange of one kind of ion present in an insoluble solid with another of like charge present in a solution surrounding the solid with the reaction being used especially for softening or making water demineralised, ...
and adsorsion methods were undertaken.
Only about 5,000 atoms of californium were produced in this experiment, and these atoms had a half-life of 44 minutes.
The discoverers named the new element after the university and the state. This was a break from the convention used for elements 95 to 97, which drew inspiration from how the elements directly above them in the periodic table were named. However, the element directly above #98 in the periodic table,
dysprosium, has a name that means "hard to get at", so the researchers decided to set aside the informal naming convention. They added that "the best we can do is to point out
hat
A hat is a head covering which is worn for various reasons, including protection against weather conditions, ceremonial reasons such as university graduation, religious reasons, safety, or as a fashion accessory. Hats which incorporate mecha ...
... searchers a century ago found it difficult to get to California".
Weighable amounts of californium were first produced by the irradiation of plutonium targets at
Materials Testing Reactor
A materials test reactor (MTR) is a high power research nuclear reactor.
Examples
Materials testing reactors include:
* The Materials Testing Reactor (MTR), an early reactor that operated in Idaho from 1952-1970.
* Dounreay Materials Testing Re ...
at
National Reactor Testing Station
Idaho National Laboratory (INL) is one of the national laboratories of the United States Department of Energy and is managed by the Battelle Energy Alliance. While the laboratory does other research, historically it has been involved with nu ...
,
eastern Idaho
Eastern Idaho is the area of Idaho lying east of the Magic Valley region. It is generally understood to include: Bannock, Bear Lake, Bingham, Bonneville, Butte, Caribou, Clark, Custer, Franklin, Fremont, Jefferson, Madison, Oneida, Power an ...
; these findings were reported in 1954. The high spontaneous fission rate of californium-252 was observed in these samples. The first experiment with californium in concentrated form occurred in 1958. The isotopes
249Cf to
252Cf were isolated that same year from a sample of
plutonium-239
Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three main ...
that had been irradiated with neutrons in a nuclear reactor for five years. Two years later, in 1960, Burris Cunningham and James Wallman of Lawrence Radiation Laboratory of the University of California created the first californium compounds—californium trichloride,
californium(III) oxychloride, and californium oxide—by treating californium with steam and hydrochloric acid.
The
High Flux Isotope Reactor
The High Flux Isotope Reactor (HFIR) is a nuclear research reactor at Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee, United States. Operating at 85 MW, HFIR is one of the highest flux reactor-based sources of neutrons for condense ...
(HFIR) at
Oak Ridge National Laboratory (ORNL) in
Oak Ridge, Tennessee, started producing small batches of californium in the 1960s. By 1995, HFIR nominally produced of californium annually. Plutonium supplied by the United Kingdom to the United States under the
1958 US–UK Mutual Defence Agreement was used for making californium.
The
Atomic Energy Commission sold
252Cf to industrial and academic customers in the early 1970s for $10 per microgram,
and an average of of
252Cf were shipped each year from 1970 to 1990. Californium metal was first prepared in 1974 by Haire and Baybarz, who reduced californium(III) oxide with lanthanum metal to obtain microgram amounts of sub-micrometer thick films.
Occurrence
Traces of californium can be found near facilities that use the element in mineral prospecting and in medical treatments. The element is fairly insoluble in water, but it adheres well to ordinary soil; and concentrations of it in the soil can be 500 times higher than in the water surrounding the soil particles.
Nuclear fallout
Nuclear fallout is the residual radioactive material propelled into the upper atmosphere following a nuclear blast, so called because it "falls out" of the sky after the explosion and the shock wave has passed. It commonly refers to the radioac ...
from atmospheric
nuclear weapons testing
Nuclear weapons tests are experiments carried out to determine nuclear weapons' effectiveness, Nuclear weapon yield, yield, and explosive capability. Testing nuclear weapons offers practical information about how the weapons function, how detona ...
prior to 1980 contributed a small amount of californium to the environment.
Californium isotopes with
mass number
The mass number (symbol ''A'', from the German word ''Atomgewicht'' tomic weight, also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approxima ...
s 249, 252, 253, and 254 have been observed in the radioactive dust collected from the air after a nuclear explosion. Californium is not a major radionuclide at
United States Department of Energy
The United States Department of Energy (DOE) is an executive department of the U.S. federal government that oversees U.S. national energy policy and manages the research and development of nuclear power and nuclear weapons in the United Stat ...
legacy sites since it was not produced in large quantities.
Californium was once believed to be produced in
supernova
A supernova is a powerful and luminous explosion of a star. It has the plural form supernovae or supernovas, and is abbreviated SN or SNe. This transient astronomical event occurs during the last evolutionary stages of a massive star or when ...
s, as their decay matches the 60-day half-life of
254Cf.
However, subsequent studies failed to demonstrate any californium spectra,
and supernova light curves are now thought to follow the decay of
nickel-56
Naturally occurring nickel (28Ni) is composed of five stable isotopes; , , , and , with being the most abundant (68.077% natural abundance). 26 radioisotopes have been characterised with the most stable being with a half-life of 76,000 years, ...
.
The
transuranium element
The transuranium elements (also known as transuranic elements) are the chemical elements with atomic numbers greater than 92, which is the atomic number of uranium. All of these elements are unstable and decay radioactively into other elements. ...
s from
americium
Americium is a synthetic radioactive chemical element with the symbol Am and atomic number 95. It is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was na ...
to
fermium
Fermium is a synthetic element with the symbol Fm and atomic number 100. It is an actinide and the heaviest element that can be formed by neutron bombardment of lighter elements, and hence the last element that can be prepared in macroscopic qua ...
, including californium, occurred naturally in the
natural nuclear fission reactor
A natural nuclear fission reactor is a uranium deposit where self-sustaining nuclear chain reactions occur. The conditions under which a natural nuclear reactor could exist had been predicted in 1956 by Japanese American chemist Paul Kuroda. Th ...
at
Oklo
Oklo is a region near the town of Franceville, in the Haut-Ogooué province of the Central African country of Gabon. Several natural nuclear fission reactors were discovered in the uranium mines in the region in 1972.
History
Gabon was a Fren ...
, but no longer do so.
Spectral line
A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to iden ...
s of californium, along with those of several other non-primordial elements, were detected in
Przybylski's Star in 2008.
Production
Californium is produced in
nuclear reactor
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
s and
particle accelerator
A particle accelerator is a machine that uses electromagnetic fields to propel charged particles to very high speeds and energies, and to contain them in well-defined beams.
Large accelerators are used for fundamental research in particle ...
s. Californium-250 is made by bombarding berkelium-249 () with neutrons, forming berkelium-250 () via
neutron capture
Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons, ...
(n,γ) which, in turn, quickly
beta decay
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...
s (β
−) to californium-250 () in the following reaction:
:(n,γ) → + β
−
Bombardment of californium-250 with neutrons produces californium-251 and californium-252.
Prolonged irradiation of
americium
Americium is a synthetic radioactive chemical element with the symbol Am and atomic number 95. It is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was na ...
, curium, and plutonium with neutrons produces milligram amounts of californium-252 and microgram amounts of californium-249. As of 2006, curium isotopes 244 to 248 are irradiated by neutrons in special reactors to produce primarily californium-252 with lesser amounts of isotopes 249 to 255.
Microgram quantities of californium-252 are available for commercial use through the U.S.
Nuclear Regulatory Commission
The Nuclear Regulatory Commission (NRC) is an independent agency of the United States government tasked with protecting public health and safety related to nuclear energy. Established by the Energy Reorganization Act of 1974, the NRC began operat ...
. Only two sites produce californium-252: the Oak Ridge National Laboratory in the United States, and the
Research Institute of Atomic Reactors in
Dimitrovgrad, Russia
Dimitrovgrad (russian: Димитровград; ), formerly Melekess () until 1972, is a city in Ulyanovsk Oblast, Russia. It is the administrative center of Melekessky District, although it is not within the district and is an independent ci ...
. As of 2003, the two sites produce 0.25 grams and 0.025 grams of californium-252 per year, respectively.
Three californium isotopes with significant half-lives are produced, requiring a total of 15 neutron captures by
uranium-238
Uranium-238 (238U or U-238) is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it ...
without
nuclear fission
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radio ...
or alpha decay occurring during the process. Californium-253 is at the end of a production chain that starts with uranium-238, includes several
isotopes of plutonium
Plutonium (94Pu) is an artificial element, except for trace quantities resulting from neutron capture by uranium, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was synthesized long ...
,
americium
Americium is a synthetic radioactive chemical element with the symbol Am and atomic number 95. It is a transuranic member of the actinide series, in the periodic table located under the lanthanide element europium, and thus by analogy was na ...
,
curium
Curium is a transuranic, radioactive chemical element with the symbol Cm and atomic number 96. This actinide element was named after eminent scientists Marie and Pierre Curie, both known for their research on radioactivity. Curium was first inte ...
,
berkelium
Berkelium is a transuranic radioactive chemical element with the symbol Bk and atomic number 97. It is a member of the actinide and transuranium element series. It is named after the city of Berkeley, California, the location of the Lawrence Ber ...
, and the californium isotopes 249 to 253 (see diagram).
Applications
![CfShield](https://upload.wikimedia.org/wikipedia/commons/e/e7/CfShield.JPG)
Californium-252 has a number of specialized uses as a strong neutron emitter; it produces 139 million neutrons per microgram per minute.
This property makes it useful as a
startup neutron source for some nuclear reactors and as a portable (non-reactor based) neutron source for
neutron activation analysis
Neutron activation analysis (NAA) is the nuclear process used for determining the concentrations of elements in many materials. NAA allows discrete sampling of elements as it disregards the chemical form of a sample, and focuses solely on atomic ...
to detect trace amounts of elements in samples.
Neutrons from californium are used as a treatment of certain
cervical
In anatomy, cervical is an adjective that has two meanings:
# of or pertaining to any neck.
# of or pertaining to the female cervix: i.e., the ''neck'' of the uterus.
*Commonly used medical phrases involving the neck are
**cervical collar
**cerv ...
and
brain cancers
A brain tumor occurs when abnormal cells form within the brain. There are two main types of tumors: malignant tumors and benign (non-cancerous) tumors. These can be further classified as primary tumors, which start within the brain, and secondar ...
where other
radiation therapy
Radiation therapy or radiotherapy, often abbreviated RT, RTx, or XRT, is a therapy using ionizing radiation, generally provided as part of cancer treatment to control or kill malignant cells and normally delivered by a linear accelerator. Radia ...
is ineffective. It has been used in educational applications since 1969 when
Georgia Institute of Technology
The Georgia Institute of Technology, commonly referred to as Georgia Tech or, in the state of Georgia, as Tech or The Institute, is a public research university and institute of technology in Atlanta, Georgia. Established in 1885, it is part of ...
got a loan of 119 μg of
252Cf from the
Savannah River Site
The Savannah River Site (SRS) is a U.S. Department of Energy (DOE) reservation in the United States in the state of South Carolina, located on land in Aiken, Allendale, and Barnwell counties adjacent to the Savannah River, southeast of August ...
. It is also used with online elemental
coal analyzer Coal analyzers are bulk material analyzers used by coal producers, coal preparation plants, and coal-fired power plants to determine coal quality in real time.
Coal quality parameters of greatest interest include ash, moisture, sulfur, and energy ...
s and
bulk material analyzer The term bulk material analyzer is the generic noun for that device which fits around a conveyor belt and conducts real-time elemental analysis of the material on the belt. Other names often found for such a device include ''belt analyzer'', ''cros ...
s in the coal and cement industries.
Neutron penetration into materials makes californium useful in detection instruments such as
fuel rod
Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission.
Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing ...
scanners;
neutron radiography
Neutron imaging is the process of making an image with neutrons. The resulting image is based on the neutron attenuation properties of the imaged object. The resulting images have much in common with industrial X-ray images, but since the image i ...
of aircraft and weapons components to detect
corrosion
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engine ...
, bad welds, cracks and trapped moisture; and in portable metal detectors.
Neutron moisture gauge
A neutron moisture meter is a moisture meter utilizing neutron scattering. The meters are most frequently used to measure the water content in soil or rock. The technique is non-destructive, and is sensitive to moisture in the bulk of the target m ...
s use
252Cf to find water and petroleum layers in oil wells, as a portable
neutron source
A neutron source is any device that emits neutrons, irrespective of the mechanism used to produce the neutrons. Neutron sources are used in physics, engineering, medicine, nuclear weapons, petroleum exploration, biology, chemistry, and nuclear p ...
for gold and silver prospecting for on-the-spot analysis, and to detect ground water movement. The main uses of
252Cf in 1982 were, reactor start-up (48.3%), fuel rod scanning (25.3%), and activation analysis (19.4%). By 1994, most
252Cf was used in neutron radiography (77.4%), with fuel rod scanning (12.1%) and reactor start-up (6.9%) as important but secondary uses. In 2021, fast neutrons from
252Cf were used for wireless data transmission.
251Cf has a very small calculated
critical mass
In nuclear engineering, a critical mass is the smallest amount of fissile material needed for a sustained nuclear chain reaction. The critical mass of a fissionable material depends upon its nuclear properties (specifically, its nuclear fissi ...
of about , high lethality, and a relatively short period of toxic environmental irradiation. The low critical mass of californium led to some exaggerated claims about possible uses for the element.
In October 2006, researchers announced that three atoms of
oganesson
Oganesson is a synthetic chemical element with the symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint team of Russian and American scient ...
(element 118) had been identified at
Joint Institute for Nuclear Research
The Joint Institute for Nuclear Research (JINR, russian: Объединённый институт ядерных исследований, ОИЯИ), in Dubna, Moscow Oblast (110 km north of Moscow), Russia, is an international research c ...
in
Dubna
Dubna ( rus, Дубна́, p=dʊbˈna) is a town in Moscow Oblast, Russia. It has a status of ''naukograd'' (i.e. town of science), being home to the Joint Institute for Nuclear Research, an international nuclear physics research center and one o ...
,
Russia
Russia (, , ), or the Russian Federation, is a List of transcontinental countries, transcontinental country spanning Eastern Europe and North Asia, Northern Asia. It is the List of countries and dependencies by area, largest country in the ...
, from bombarding
249Cf with
calcium-48
Calcium-48 is a scarce isotope of calcium containing 20 protons and 28 neutrons. It makes up 0.187% of natural calcium by mole fraction. Although it is unusually neutron-rich for such a light nucleus, its beta decay is extremely hindered, and so ...
, making it the heaviest element ever made. The target contained about 10 mg of
249Cf deposited on a titanium foil of 32 cm
2 area. Californium has also been used to produce other transuranium elements; for example, element 103 (later named
lawrencium
Lawrencium is a synthetic chemical element with the symbol Lr (formerly Lw) and atomic number 103. It is named in honor of Ernest Lawrence, inventor of the cyclotron, a device that was used to discover many artificial radioactive elements. A radio ...
) was first synthesized in 1961 by bombarding californium with
boron
Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
nuclei.
Precautions
Californium that
bioaccumulates in skeletal tissue releases radiation that disrupts the body's ability to form
red blood cell
Red blood cells (RBCs), also referred to as red cells, red blood corpuscles (in humans or other animals not having nucleus in red blood cells), haematids, erythroid cells or erythrocytes (from Greek ''erythros'' for "red" and ''kytos'' for "holl ...
s. The element plays no natural biological role in any organism due to its intense radioactivity and low concentration in the environment.
Californium can enter the body from ingesting contaminated food or drinks or by breathing air with suspended particles of the element. Once in the body, only 0.05% of the californium will reach the bloodstream. About 65% of that californium will be deposited in the skeleton, 25% in the liver, and the rest in other organs, or excreted, mainly in urine. Half of the californium deposited in the skeleton and liver are gone in 50 and 20 years, respectively. Californium in the skeleton adheres to bone surfaces before slowly migrating throughout the bone.
The element is most dangerous if taken into the body. In addition, californium-249 and californium-251 can cause tissue damage externally, through
gamma ray
A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically ...
emission.
Ionizing radiation
Ionizing radiation (or ionising radiation), including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel ...
emitted by californium on bone and in the liver can cause cancer.
Notes
References
Bibliography
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External links
Californiumat ''
The Periodic Table of Videos
''Periodic Videos'' (also known as ''The Periodic Table of Videos'') is a video project and YouTube channel on chemistry. It consists of a series of videos about chemical elements and the periodic table, with additional videos on other topics i ...
'' (University of Nottingham)
NuclearWeaponArchive.org – CaliforniumHazardous Substances Databank – Californium, Radioactive
{{Commons category-inline
Chemical elements
Chemical elements with double hexagonal close-packed structure
Actinides
Synthetic elements
Neutron sources