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Prymnesin-1
Prymnesin-1 is a chemical with the molecular formula . It is a member of the prymnesins, a class of hemolytic phycotoxins made by the alga ''Prymnesium parvum''. It is known to be toxic to fish, causing mass fish deaths around the world, including in Texas and England, or in 2022 in the border region of Germany and Poland (Oder). Structures Prymnesin-1 is formed of a large polyether polycyclic core with several conjugate double and triple bonds, chlorine and nitrogen heteroatoms and O-linked sugar moieties including α-D-ribofuranose, α-L-arabinopyranose, and β-D-galactofuranose, unlike the single linked α-L-xylofuranose of prymnesin-2. There are three forms of prymnesin known, prymnesin 1 and 2, differing in their glycosylation, and prymnesin B1 differing in backbone. See also * Prymnesin-2 * Prymnesin-B1 Prymnesin-B1 is a chemical with the molecular formula . It is a member of the prymnesins, a class of ladder-frame polyether phycotoxins made by the alga '' Prymnesium ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prymnesin-2
Prymnesin-2 is an organic compound that is secreted by the haptophyte ''Prymnesium parvum''. It belongs to the prymnesin family and has potent hemolytic and ichthyotoxic properties. In a purified form it appears as a pale yellow solid. ''P. parvum'' is responsible for red harmful algal blooms worldwide, causing massive fish killings. When these algal blooms occur, this compound poses a threat to the local fishing industry. This is especially true for brackish water, as the compound can reach critical concentrations more easily. Structure and reactivity The structural formula of prymnesin-2 is: C96H136Cl3NO35. The compound exhibits multiple chiral centers. The molecule is amphoteric, which means that it can act both as base and an acid. This is because all 16 hydroxyls, except for one at C32, are concentrated on carbons C48-84, and there α-L-xylofuranose moiety at C77. This might lead to interaction with biomembranes, which is thought to be the basis of its toxicity. The diffe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prymnesin-2
Prymnesin-2 is an organic compound that is secreted by the haptophyte ''Prymnesium parvum''. It belongs to the prymnesin family and has potent hemolytic and ichthyotoxic properties. In a purified form it appears as a pale yellow solid. ''P. parvum'' is responsible for red harmful algal blooms worldwide, causing massive fish killings. When these algal blooms occur, this compound poses a threat to the local fishing industry. This is especially true for brackish water, as the compound can reach critical concentrations more easily. Structure and reactivity The structural formula of prymnesin-2 is: C96H136Cl3NO35. The compound exhibits multiple chiral centers. The molecule is amphoteric, which means that it can act both as base and an acid. This is because all 16 hydroxyls, except for one at C32, are concentrated on carbons C48-84, and there α-L-xylofuranose moiety at C77. This might lead to interaction with biomembranes, which is thought to be the basis of its toxicity. The diffe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prymnesins
Prymnesin may refer to: * Prymnesin-1 * Prymnesin-2 * Prymnesin-B1 Prymnesin-B1 is a chemical with the molecular formula . It is a member of the prymnesins, a class of ladder-frame polyether phycotoxins made by the alga '' Prymnesium parvum''. It is known to be toxic to fish. It is a so called "Type-B" prymnesin, ... * Prymnesin-B2 {{Short pages monitor ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Prymnesin-B1
Prymnesin-B1 is a chemical with the molecular formula . It is a member of the prymnesins, a class of ladder-frame polyether phycotoxins made by the alga ''Prymnesium parvum''. It is known to be toxic to fish. It is a so called "Type-B" prymnesin, which differ in the number of backbone cycles when compared to Type-A prymnesins like prymnesin-2. Structures Prymnesins-B1 is formed of a large polyether polycyclic core with several conjugate double and triple bonds, chlorine and nitrogen heteroatoms and a single sugar moiety consisting of α-D-galactopyranose. See also * Prymnesin-1 * Prymnesin-2 Prymnesin-2 is an organic compound that is secreted by the haptophyte ''Prymnesium parvum''. It belongs to the prymnesin family and has potent hemolytic and ichthyotoxic properties. In a purified form it appears as a pale yellow solid. ''P. parvum ... References {{reflist Phycotoxins Polyether toxins Primary alcohols Secondary alcohols Conjugated enynes Organochlorides Halohydr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ribose
Ribose is a simple sugar and carbohydrate with molecular formula C5H10O5 and the linear-form composition H−(C=O)−(CHOH)4−H. The naturally-occurring form, , is a component of the ribonucleotides from which RNA is built, and so this compound is necessary for coding, decoding, regulation and expression of genes. It has a structural analog, deoxyribose, which is a similarly essential component of DNA. is an unnatural sugar that was first prepared by Emil Fischer and Oscar Piloty in 1891. It was not until 1909 that Phoebus Levene and Walter Jacobs recognised that was a natural product, the enantiomer of Fischer and Piloty's product, and an essential component of nucleic acids. Fischer chose the name "ribose" as it is a partial rearrangement of the name of another sugar, arabinose, of which ribose is an epimer at the 2' carbon; both names also relate to gum arabic, from which arabinose was first isolated and from which they prepared . Like most sugars, ribose exists ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Primary Alcohols
A primary alcohol is an alcohol in which the hydroxy group In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy ... is bonded to a primary carbon atom. It can also be defined as a molecule containing a “–CH2OH” group. In contrast, a secondary alcohol has a formula “–CHROH” and a tertiary alcohol has a formula “–CR2OH”, where “R” indicates a carbon-containing group. Examples of primary alcohols include ethanol and n-Butanol, 1-butanol. Methanol is also generally regarded as a primary alcohol, including the 1911 edition of the Encyclopædia Britannica,. See also * Alcohol (chemistry), Alcohol (especially Nomenclature section for discussion on Secondary and Tertiary alcohols.) * Oxidation of primary alcohols to carboxylic acids References Primary alcohols, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Amines
In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group (these may respectively be called alkylamines and arylamines; amines in which both types of substituent are attached to one nitrogen atom may be called alkylarylamines). Important amines include amino acids, biogenic amines, trimethylamine, and aniline; Inorganic derivatives of ammonia are also called amines, such as monochloramine (). The substituent is called an amino group. Compounds with a nitrogen atom attached to a carbonyl group, thus having the structure , are called amides and have different chemical properties from amines. Classification of amines Amines can be classified according to the nature and number of substituents on nitrogen. Aliphatic amines contain only H and alkyl substituents. Aromatic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Organochlorides
An organochloride, organochlorine compound, chlorocarbon, or chlorinated hydrocarbon is an organic compound containing at least one covalently bonded atom of chlorine. The chloroalkane class (alkanes with one or more hydrogens substituted by chlorine) provides common examples. The wide structural variety and divergent chemical properties of organochlorides lead to a broad range of names, applications, and properties. Organochlorine compounds have wide use in many applications, though some are of profound environmental concern, with TCDD being one of the most notorious. Physical and chemical properties Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage. Natural occurrence Many organochlorine compounds have been isolate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Conjugated Enynes
Conjugation or conjugate may refer to: Linguistics *Grammatical conjugation, the modification of a verb from its basic form *Emotive conjugation or Russell's conjugation, the use of loaded language Mathematics *Complex conjugation, the change of sign of the imaginary part of a complex number * Conjugate (square roots), the change of sign of a square root in an expression *Conjugate element (field theory), a generalization of the preceding conjugations to roots of a polynomial of any degree *Conjugate transpose, the complex conjugate of the transpose of a matrix *Harmonic conjugate in complex analysis * Conjugate (graph theory), an alternative term for a line graph, i.e. a graph representing the edge adjacencies of another graph *In group theory, various notions are called conjugation: **Inner automorphism, a type of conjugation homomorphism **Conjugation in group theory, related to matrix similarity in linear algebra **Conjugation (group theory), the image of an element under t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Secondary Alcohols
In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl () functional group bound to a saturated carbon atom. The term ''alcohol'' originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula . Simple monoalcohols that are the subject of this article include primary (), secondary () and tertiary () alcohols. The suffix ''-ol'' appears in the IUPAC chemical name of all substances where the hydroxyl group is the functional group with the highest priority. When a higher priority group is present in the compound, the prefix ''hydroxy-'' is used in its IUPAC name. The suffix ''-ol'' in non-IUPAC names (such as paracetamol or cholesterol) also typically indicates that the substance is an alcohol. However, some compound ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
