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Profisetinidin
A profisetinidin is a type of condensed tannins formed from leuco-fisetinidin, the leucoanthocyanidin form of fisetinidin. ''Mimosa'' and quebracho tannins are, according to a comparative 13C NMR study of polyflavonoids, found to be predominantly profisetinidin/prorobinetidin-type tannins. The expected masses found in mass spectrometry in quebracho tannin are 561, 833, 1105, 1377, 1393, 1651, 1667. Quebracho also yields gallic acid Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plants. It i .... References Condensed tannins {{polyphenol-stub ...
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Condensed Tannin
Condensed tannins (proanthocyanidins, polyflavonoid tannins, catechol-type tannins, pyrocatecollic type tannins, non-hydrolyzable tannins or flavolans) are polymers formed by the condensation of flavans. They do not contain sugar residues. They are called proanthocyanidins as they yield anthocyanidins when depolymerized under oxidative conditions. Different types of condensed tannins exist, such as the procyanidins, propelargonidins, prodelphinidins, profisetinidins, proteracacinidins, proguibourtinidins or prorobinetidins. All of the above are formed from flavan-3-ols, but flavan-3,4-diols, called (leucoanthocyanidin) also form condensed tannin oligomers, e.g. leuco-fisetinidin form profisetinidin, and flavan-4-ols form condensed tannins, e.g. 3',4',5,7-flavan-4-ol form proluteolinidin (luteoforolor). One particular type of condensed tannin, found in grape, are procyanidins, which are polymers of 2 to 50 (or more) catechin units joined by carbon-carbon bonds. These are not ...
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Leuco-fisetinidin
Leucofisetinidin is a flavan-3,4-diol (leucoanthocyanidin), a type of natural phenolic substance. It is the monomer of condensed tannins called profisetinidins. Those tannins can be extracted from the heartwood of ''Acacia mearnsii'' or from the heartwoods of ''Schinopsis balansae'', ''Schinopsis quebrachocolorado'' and from commercial quebracho extract. See also * Fisetinidin Fisetinidin is an anthocyanidin. It has been obtained from the heartwood of ''Acacia mearnsii'', from the bark of '' Rhizophora apiculata'' and can also be synthesized. Fisetinidin is very similar in structure to fisetin, which itself differs in s ... References Leucoanthocyanidins {{aromatic-stub ...
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Fisetinidin
Fisetinidin is an anthocyanidin. It has been obtained from the heartwood of ''Acacia mearnsii'', from the bark of ''Rhizophora apiculata'' and can also be synthesized. Fisetinidin is very similar in structure to fisetin, which itself differs in structure from quercetin only by an additional hydroxyl group on the latter. An assay of twenty flavonoids showed fisetinidin to be the least effective in inhibition of CD38 enzyme. Tannins Fisetinidin can compose tannins. The polymers are then called profisetinidin (Porter, 1992). See also * Leuco-fisetinidin * List of compounds with carbon number 15 This is a partial list of molecules that contain 15 carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bo ... References Anthocyanidins Catechols {{Aromatic-stub}"> --> Anthocyanidins Catechols {{Aromatic-stub}--> Anthocya ...
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Quebracho Tannin
Quebracho is a common name in Spanish to describe very hard (density 0.9–1.3) wood tree species. The etymology of the name derived from ''quiebrahacha'', or ''quebrar hacha'', meaning "axe-breaker". Species There are at least three similar commercially important tree species that grow in the Gran Chaco region of South America. * the quebracho ** ''Schinopsis lorentzii'' (Syn.: ''Schinopsis marginata'' Engl., ''Schinopsis haenkeana'' Engl.); of the family Anacardiaceae; North Argentina, Paraguay and Bolivia; (the red quebracho, quebracho), ''quebracho-colorado santiagueño'', ''red quebracho santiagueño'', ''quebracho santiagueño'' (also known as ''quebracho cor(o)nillo'', ''cor(o)nillo'', ''quebracho macho'', ''quebracho negro'' or ''moro'', ''quebracho rojo'', ''quebracho bolí'', ''horco quebracho'', ''quebracho serrano'', ''quebracho montano'', ''quebracho crespo'', ''quebracho del cerro'', ''quebracho colorado de las sierras'' o ''del cerro'' and ''quebracho cordobés ...
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Mimosa
''Mimosa'' is a genus of about 590 species of herbs and shrubs, in the mimosoid clade of the legume family Fabaceae. The generic name is derived from the Greek word (''mimos''), an "actor" or "mime", and the feminine suffix -''osa'', "resembling", suggesting its 'sensitive leaves' which seem to 'mimic conscious life'. Two species in the genus are especially notable. One is ''Mimosa pudica'', commonly known as touch-me-not, which folds its leaves when touched or exposed to heat. It is native to southern Central and South America but is widely cultivated elsewhere for its curiosity value, both as a houseplant in temperate areas, and outdoors in the tropics. Outdoor cultivation has led to weedy invasion in some areas, notably Hawaii. The other is ''Mimosa tenuiflora'', which is best known for its use in shamanic ayahuasca brews due to the psychedelic drug dimethyltryptamine found in its root bark. Taxonomy The taxonomy of the genus ''Mimosa'' has gone through several periods of ...
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Gallic Acid
Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plants. It is a white solid, although samples are typically brown owing to partial oxidation. Salts and esters of gallic acid are termed "gallates". Isolation and derivatives Gallic acid is easily freed from gallotannins by acidic or alkaline hydrolysis. When heated with concentrated sulfuric acid, gallic acid converts to rufigallol. Hydrolyzable tannins break down on hydrolysis to give gallic acid and glucose or ellagic acid and glucose, known as gallotannins and ellagitannins, respectively. Biosynthesis Gallic acid is formed from 3-dehydroshikimate by the action of the enzyme shikimate dehydrogenase to produce 3,5-didehydroshikimate. This latter compound aromatizes. Reactions Oxidation and oxidative coupling Alkaline solutions of gallic a ...
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