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Process Quantities
In thermodynamics, a quantity that is well defined so as to describe the path of a process through the equilibrium state space of a thermodynamic system is termed a process function, or, alternatively, a process quantity, or a path function. As an example, mechanical work and heat are process functions because they describe quantitatively the transition between equilibrium states of a thermodynamic system. Path functions depend on the path taken to reach one state from another. Different routes give different quantities. Examples of path functions include work, heat and arc length. In contrast to path functions, state functions are independent of the path taken. Thermodynamic state variables are point functions, differing from path functions. For a given state, considered as a point, there is a definite value for each state variable and state function. Infinitesimal changes in a process function are often indicated by to distinguish them from infinitesimal changes in a state ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
List Of Thermodynamic Properties
In thermodynamics, a physical property is any property that is measurable, and whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the system's state. Some constants, such as the ideal gas constant, , do not describe the state of a system, and so are not properties. On the other hand, some constants, such as (the freezing point depression constant, or cryoscopic constant), depend on the identity of a substance, and so may be considered to describe the state of a system, and therefore may be considered physical properties. "Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive or extensive). Regarding work and heat Work and heat are not thermodynamic properties, but rather '' process quantities:'' flows of energy across a system boundary. Systems do not ''con ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Equilibrium State
Thermodynamic equilibrium is an axiomatic concept of thermodynamics. It is an internal state of a single thermodynamic system, or a relation between several thermodynamic systems connected by more or less permeable or impermeable walls. In thermodynamic equilibrium, there are no net macroscopic flows of matter nor of energy within a system or between systems. In a system that is in its own state of internal thermodynamic equilibrium, no macroscopic change occurs. Systems in mutual thermodynamic equilibrium are simultaneously in mutual thermal, mechanical, chemical, and radiative equilibria. Systems can be in one kind of mutual equilibrium, while not in others. In thermodynamic equilibrium, all kinds of equilibrium hold at once and indefinitely, until disturbed by a thermodynamic operation. In a macroscopic equilibrium, perfectly or almost perfectly balanced microscopic exchanges occur; this is the physical explanation of the notion of macroscopic equilibrium. A thermodynamic sys ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic System
A thermodynamic system is a body of matter and/or radiation, confined in space by walls, with defined permeabilities, which separate it from its surroundings. The surroundings may include other thermodynamic systems, or physical systems that are not thermodynamic systems. A wall of a thermodynamic system may be purely notional, when it is described as being 'permeable' to all matter, all radiation, and all forces. A state of a thermodynamic system can be fully described in several different ways, by several different sets of thermodynamic state variables. A widely used distinction is between ''isolated'', ''closed'', and ''open'' thermodynamic systems. An isolated thermodynamic system has walls that are non-conductive of heat and perfectly reflective of all radiation, that are rigid and immovable, and that are impermeable to all forms of matter and all forces. (Some writers use the word 'closed' when here the word 'isolated' is being used.) A closed thermodynamic system is c ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mechanical Work
In physics, work is the energy transferred to or from an object via the application of force along a displacement. In its simplest form, for a constant force aligned with the direction of motion, the work equals the product of the force strength and the distance traveled. A force is said to do ''positive work'' if when applied it has a component in the direction of the displacement of the point of application. A force does ''negative work'' if it has a component opposite to the direction of the displacement at the point of application of the force. For example, when a ball is held above the ground and then dropped, the work done by the gravitational force on the ball as it falls is positive, and is equal to the weight of the ball (a force) multiplied by the distance to the ground (a displacement). If the ball is thrown upwards, the work done by its weight is negative, and is equal to the weight multiplied by the displacement in the upwards direction. When the force is consta ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat
In thermodynamics, heat is defined as the form of energy crossing the boundary of a thermodynamic system by virtue of a temperature difference across the boundary. A thermodynamic system does not ''contain'' heat. Nevertheless, the term is also often used to refer to the thermal energy contained in a system as a component of its internal energy and that is reflected in the temperature of the system. For both uses of the term, heat is a form of energy. An example of formal vs. informal usage may be obtained from the right-hand photo, in which the metal bar is "conducting heat" from its hot end to its cold end, but if the metal bar is considered a thermodynamic system, then the energy flowing within the metal bar is called internal energy, not heat. The hot metal bar is also transferring heat to its surroundings, a correct statement for both the strict and loose meanings of ''heat''. Another example of informal usage is the term '' heat content'', used despite the fact that p ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Work (thermodynamics)
In thermodynamics, work is one of the principal processes by which a thermodynamic system can interact with its surroundings and exchange energy. An exchange of energy is facilitated by a mechanism through which the system can spontaneously exert macroscopic forces on its surroundings, or vice versa. In the surroundings, this mechanical work can lift a weight, for example. The externally measured forces and external effects may be electromagnetic,Guggenheim, E.A. (1985). ''Thermodynamics. An Advanced Treatment for Chemists and Physicists'', seventh edition, North Holland, Amsterdam, .Jackson, J.D. (1975). ''Classical Electrodynamics'', second edition, John Wiley and Sons, New York, .Konopinski, E.J. (1981). ''Electromagnetic Fields and Relativistic Particles'', McGraw-Hill, New York, . gravitational,North, G.R., Erukhimova, T.L. (2009). ''Atmospheric Thermodynamics. Elementary Physics and Chemistry'', Cambridge University Press, Cambridge (UK), . or mechanical (such as pressure-v ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arc Length
ARC may refer to: Business * Aircraft Radio Corporation, a major avionics manufacturer from the 1920s to the '50s * Airlines Reporting Corporation, an airline-owned company that provides ticket distribution, reporting, and settlement services * Airport Regions Conference, a European organization of major airports * Amalgamated Roadstone Corporation, a British stone quarrying company * American Record Company (1904–1908, re-activated 1979), one of two United States record labels by this name * American Record Corporation (1929–1938), a United States record label also known as American Record Company * ARC (American Recording Company) (1978-present), a vanity label for Earth, Wind & Fire * ARC Document Solutions, a company based in California, formerly American Reprographics Company * Amey Roadstone Construction, a former British construction company * Aqaba Railway Corporation, a freight railway in Jordan * ARC/Architectural Resources Cambridge, Inc., Cambridge, Massachusett ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Function
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system (e.g. gas, liquid, solid, crystal, or emulsion), not the path which the system has taken to reach that state. A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example. In this law, one state variable (e.g., pressure, volume, temperature, or the amount of substance in a gaseous equilibrium system) is a function of other state variables so is regarded as a state function. A state fu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
State Function
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system (e.g. gas, liquid, solid, crystal, or emulsion), not the path which the system has taken to reach that state. A state function describes equilibrium states of a system, thus also describing the type of system. A state variable is typically a state function so the determination of other state variable values at an equilibrium state also determines the value of the state variable as the state function at that state. The ideal gas law is a good example. In this law, one state variable (e.g., pressure, volume, temperature, or the amount of substance in a gaseous equilibrium system) is a function of other state variables so is regarded as a state function. A state fu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Exact Differential
In multivariate calculus, a differential or differential form is said to be exact or perfect (''exact differential''), as contrasted with an inexact differential, if it is equal to the general differential dQ for some differentiable function Q in an orthogonal coordinate system. An exact differential is sometimes also called a ''total differential'', or a ''full differential'', or, in the study of differential geometry, it is termed an exact form. The integral of an exact differential over any integral path is path-independent, and this fact is used to identify state functions in thermodynamics. Overview Definition Even if we work in three dimensions here, the definitions of exact differentials for other dimensions are structurally similar to the three dimensional definition. In three dimensions, a form of the type :A(x,y,z) \,dx + B(x,y,z) \,dy + C(x,y,z) \,dz is called a differential form. This form is called ''exact'' on an open domain D \subset \mathbb^3 in spac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inexact Differential
An inexact differential or imperfect differential is a differential whose integral is path dependent. It is most often used in thermodynamics to express changes in path dependent quantities such as heat and work, but is defined more generally within mathematics as a type of differential form. In contrast, an integral of an exact differential is always path independent since the integral acts to invert the differential operator. Consequently, a quantity with an inexact differential cannot be expressed as a function of only the variables within the differential. I.e., its value cannot be inferred just by looking at the initial and final states of a given system. Inexact differentials are primarily used in calculations involving heat and work because they are path functions, not state functions. Definition An inexact differential \delta u is a differential for which the integral over some two paths with the same end points is different. Specifically, there exist integrable paths ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Holonomic Constraints
In classical mechanics, holonomic constraints are relations between the position variables (and possibly time) that can be expressed in the following form: :f(u_1, u_2, u_3,\ldots, u_n, t) = 0 where \ are the ''n'' generalized coordinates that describe the system. For example, the motion of a particle constrained to lie on the surface of a sphere is subject to a holonomic constraint, but if the particle is able to fall off the sphere under the influence of gravity, the constraint becomes non-holonomic. For the first case, the holonomic constraint may be given by the equation :r^2-a^2=0 where r is the distance from the centre of a sphere of radius a, whereas the second non-holonomic case may be given by :r^2 - a^2 \geq 0 Velocity-dependent constraints (also called semi-holonomic constraints) such as :f(u_1,u_2,\ldots,u_n,\dot_1,\dot_2,\ldots,\dot_n,t)=0 are not usually holonomic. Holonomic system In classical mechanics a system may be defined as holonomic if all constraints ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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