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Orthocarbonic Acid
Orthocarbonic acid (methanetetrol) is the name given to a hypothetical compound with the chemical formula or . Its molecular structure consists of a single carbon atom bonded to four hydroxy groups. It would be therefore a fourfold alcohol. In theory it could lose four protons to give the hypothetical oxocarbon anion (orthocarbonate), and is therefore considered an oxoacid of carbon. The compound has also been given the nickname of "Hitler's Acid" due to the Ball-and-stick model of the compound resembling the Swastika symbol. Orthocarbonic acid is highly unstable. Calculations show that it decomposes spontaneously into carbonic acid and water: : H4CO4 -> H2CO3 + H2O Orthocarbonic acid is one of the group of ''ortho acids'' that have the general structure of .The term ''ortho acid'' is also used to refer to the most hydroxylated acid in a set of oxoacids. Researchers predict that orthocarbonic acid is stable at high pressure; hence it may form in the interior of the ice ...
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Tetramethoxymethane
Tetramethoxymethane is a chemical compound which is formally formed by complete methylation of the hypothetical orthocarbonic acid C(OH)4 (orthocarboxylic acid violates the Erlenmeyer Rule, Erlenmeyer rule and is unstable in free state). Preparation The obvious synthetic route from tetrachloromethane does not yield the desired product.R. H. De Wolfe, ''Carboxylic ortho acid derivatives: preparation and synthetic applications'', Organic Chemistry, Vol. 14, Academic Press, Inc. New York – London, 1970, . The original preparation of the tetramethoxymethane was therefore based on chloropicrin: Because of the unpleasant properties of the chloropicrin, other tetrasubstituted reactive methane derivatives were investigated as starting material for tetramethoxymethane. For example, trichloromethanesulfenyl chloride (also used as a chemical warfare agent and easily accessible from Carbon disulfide, carbon bisulfide and chlorine) was used: A less problematic synthesis is based on tr ...
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Swastika
The swastika (卐 or 卍) is an ancient religious and cultural symbol, predominantly in various Eurasian, as well as some African and American cultures, now also widely recognized for its appropriation by the Nazi Party and by neo-Nazis. It continues to be used as a symbol of divinity and spirituality in Indian religions, including Hinduism, Buddhism, and Jainism. It generally takes the form of a cross, the arms of which are of equal length and perpendicular to the adjacent arms, each bent midway at a right angle. The word ''swastika'' comes from sa, स्वस्तिक, svastika, meaning "conducive to well-being". In Hinduism, the right-facing symbol (clockwise) () is called ', symbolizing ("sun"), prosperity and good luck, while the left-facing symbol (counter-clockwise) () is called ''sauwastika'', symbolising night or tantric aspects of Kali. In Jain symbolism, it represents Suparshvanathathe seventh of 24 Tirthankaras ( spiritual teachers and sav ...
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Ester
In chemistry, an ester is a compound derived from an oxoacid (organic or inorganic) in which at least one hydroxyl group () is replaced by an alkoxy group (), as in the substitution reaction of a carboxylic acid and an alcohol. Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. They perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. Nitrate esters, such as nitroglycerin, are known for their explosive properties. '' Nomenclature Etymology ...
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Moiety (chemistry)
In organic chemistry, a moiety ( ) is a part of a molecule that is given a name because it is identified as a part of other molecules as well. Typically, the term is used to describe the larger and characteristic parts of organic molecules, and it should not be used to describe or name smaller functional groups of atoms that chemically react in similar ways in most molecules that contain them. Occasionally, a moiety may contain smaller moieties and functional groups. A moiety that acts as a branch extending from the backbone of a hydrocarbon molecule is called a substituent or side chain, which typically can be removed from the molecule and substituted with others. Active moiety In pharmacology, an active moiety is the part of a molecule or ion – excluding appended inactive portions – that is responsible for the physiological or pharmacological action of a drug substance. Inactive appended portions of the drug substance may include either the alcohol or acid moiety o ...
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Valence (chemistry)
In chemistry, the valence (US spelling) or valency (British spelling) of an element is the measure of its combining capacity with other atoms when it forms chemical compounds or molecules. Description The combining capacity, or affinity of an atom of a given element is determined by the number of hydrogen atoms that it combines with. In methane, carbon has a valence of 4; in ammonia, nitrogen has a valence of 3; in water, oxygen has a valence of 2; and in hydrogen chloride, chlorine has a valence of 1. Chlorine, as it has a valence of one, can be substituted for hydrogen. Phosphorus has a valence of 5 in phosphorus pentachloride, . Valence diagrams of a compound represent the connectivity of the elements, with lines drawn between two elements, sometimes called bonds, representing a saturated valency for each element. The two tables below show some examples of different compounds, their valence diagrams, and the valences for each element of the compound. Modern definition ...
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Atmospheric Pressure
Atmospheric pressure, also known as barometric pressure (after the barometer), is the pressure within the atmosphere of Earth. The standard atmosphere (symbol: atm) is a unit of pressure defined as , which is equivalent to 1013.25 millibars, 760mm Hg, 29.9212 inchesHg, or 14.696 psi.International Civil Aviation Organization. ''Manual of the ICAO Standard Atmosphere'', Doc 7488-CD, Third Edition, 1993. . The atm unit is roughly equivalent to the mean sea-level atmospheric pressure on Earth; that is, the Earth's atmospheric pressure at sea level is approximately 1 atm. In most circumstances, atmospheric pressure is closely approximated by the hydrostatic pressure caused by the weight of air above the measurement point. As elevation increases, there is less overlying atmospheric mass, so atmospheric pressure decreases with increasing elevation. Because the atmosphere is thin relative to the Earth's radius—especially the dense atmospheric layer at low altitudes—the Earth's ...
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Angstrom
The angstromEntry "angstrom" in the Oxford online dictionary. Retrieved on 2019-03-02 from https://en.oxforddictionaries.com/definition/angstrom.Entry "angstrom" in the Merriam-Webster online dictionary. Retrieved on 2019-03-02 from https://www.merriam-webster.com/dictionary/angstrom. (, ; , ) or ångström is a metric unit of length equal to m; that is, one ten-billionth ( US) of a metre, a hundred-millionth of a centimetre,Entry "angstrom" in the Oxford English Dictionary, 2nd edition (1986). Retrieved on 2021-11-22 from https://www.oed.com/oed2/00008552. 0.1 nanometre, or 100 picometres. Its symbol is Å, a letter of the Swedish alphabet. The unit is named after the Swedish physicist Anders Jonas Ångström (1814–1874). The angstrom is often used in the natural sciences and technology to express sizes of atoms, molecules, microscopic biological structures, and lengths of chemical bonds, arrangement of atoms in crystals,Arturas Vailionis (2015):Geometry of Crystals L ...
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Tetrahedral Molecular Geometry
In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are arccosine, cos−1(−) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane () as well as Group 14 hydride, its heavier analogues. Methane and other perfectly symmetrical tetrahedral molecules belong to point group Td, but most tetrahedral molecules have Tetrahedron#Isometries of irregular tetrahedra, lower symmetry. Tetrahedral molecules can be Chirality (chemistry), chiral. Tetrahedral bond angle The bond angle for a symmetric tetrahedral molecule such as CH4 may be calculated using the dot product of two Vector (mathematics and physics), vectors. As shown in the diagram, the molecule can be inscribed in a cube with the tetravalent atom (e.g. carbon) at the cube centre which is the origin of coordinates, O. The four monovalent atoms (e.g. hydrogens) are at four corners of the c ...
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Salt (chemistry)
In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is Salt, table salt, with positively charged sodium ions and negatively charged chloride ions. The component ions in a salt compound can be either inorganic compound, inorganic, such as chloride (Cl−), or organic chemistry, organic, such as acetate (). Each ion can be either monatomic ion, monatomic, such as fluoride (F−), or polyatomic ion, polyatomic, such as sulfate (). Types of salt Salts can be classified in a variety of ways. Salts that produce hydroxide ions when dissolved in water are called ''alkali salts'' and salts that produce hydrogen ions when dissolved in water are called ''acid salts''. ''Neutral salts'' are those salts that are neither acidic nor basic. Zwitterions contain an anionic and a cationic centre in the same molecule, but are not considered s ...
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Methane
Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it poses technical challenges due to its gaseous state under normal conditions for temperature and pressure. Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane. The Earth's atmospheric methane concentration has increased by about 150% since 1750, and it accounts for 20% of the total radiative forcing from all of the long-lived and globally mixed greenhouse gases. It has also been detected on other ...
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Neptune
Neptune is the eighth planet from the Sun and the farthest known planet in the Solar System. It is the fourth-largest planet in the Solar System by diameter, the third-most-massive planet, and the densest giant planet. It is 17 times the mass of Earth, and slightly more massive than its near-twin Uranus. Neptune is denser and physically smaller than Uranus because its greater mass causes more gravitational compression of its atmosphere. It is referred to as one of the solar system's two ice giant planets (the other one being Uranus). Being composed primarily of gases and liquids, it has no well-defined "solid surface". The planet orbits the Sun once every 164.8  years at an average distance of . It is named after the Roman god of the sea and has the astronomical symbol , representing Neptune's trident. Neptune is not visible to the unaided eye and is the only planet in the Solar System found by mathematical prediction rather than by empirical observation. Un ...
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Uranus
Uranus is the seventh planet from the Sun. Its name is a reference to the Greek god of the sky, Uranus ( Caelus), who, according to Greek mythology, was the great-grandfather of Ares (Mars), grandfather of Zeus (Jupiter) and father of Cronus ( Saturn). It has the third-largest planetary radius and fourth-largest planetary mass in the Solar System. Uranus is similar in composition to Neptune, and both have bulk chemical compositions which differ from that of the larger gas giants Jupiter and Saturn. For this reason, scientists often classify Uranus and Neptune as "ice giants" to distinguish them from the other giant planets. As with gas giants, ice giants also lack a well defined "solid surface." Uranus's atmosphere is similar to Jupiter's and Saturn's in its primary composition of hydrogen and helium, but it contains more " ices" such as water, ammonia, and methane, along with traces of other hydrocarbons. It has the coldest planetary atmosphere in the Solar Syst ...
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