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Organic Laser
Organic lasers use an organic (carbon based) material as the gain medium. The first organic laser was the liquid dye laser. These lasers use laser dye solutions as their gain media. Organic lasers are inherently tunable and when configured as optimized multiple-prism grating laser oscillators can yield efficient single-transverse mode, and single-longitudinal-mode, emission with laser linewidths as narrow as 350 MHz (approximately 0.0004 nm at a wavelength of 590 nm), in the high-power pulsed regime. Solid-state dye lasers Solid-state dye lasers are organic tunable lasers that use a variety of organic gain media, such as laser dye-doped polymers (DDP), laser dye-doped ormosil (DDO), and laser dye-doped polymer-nanoparticle (DDPN) matrices. DDO and DDPN gain media are subsets of a larger class of organic-inorganic hybrid materials used as laser matrices. Organic semiconductor laser Other types of solid-state organic lasers include the organic semiconductor ...
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AVLIS Laser
Atomic vapor laser isotope separation, or AVLIS, is a method by which specially tuned lasers are used to separate isotopes of uranium using selective ionization of hyperfine transitions. A similar technology, using molecules instead of atoms, is molecular laser isotope separation (MLIS). Natural uranium consists of a large mass of 238U and a much smaller mass of fissile 235U. Traditionally, the 235U is separated from the mass by dissolving it in acid to produce uranium hexafluoride and then using gas centrifuges to separate the isotopes. Each trip through the centrifuge "enriches" the amount of 235U and leaves behind depleted uranium. In contrast, AVLIS produces much higher enrichment in a single step without the need to mix it with acid. The technology could, in principle, also be used for isotope separation of other elements, which is uneconomic outside specialist applications with current non-laser-based technologies for most elements. As the process does not require the ...
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Ormosil
Ormosil is a shorthand phrase for ''organically modified silica'' or ''organically modified silicate''. In general, ormosils are produced by adding silane to silica-derived gel during the sol-gel process. They are engineered materials that show great promise in a wide range of applications such as: * alternative to viral vectors for gene delivery, with higher transient transfection efficiencies * suspension media and substrates for next generation solar cells (quantum dots)and photocatalytic oxidation of water * matrix material for UV-protection coating * matrix material for laser dye-doped organic-inorganic solid state dye lasers This technology has been demonstrated as a nonviral vector to successfully deliver DNA loads to specifically targeted cells in living animals. Confirmation of results demonstrated that new DNA was working and expressed genes in the animal. Sono-Ormosil Sono-Ormosils are organically modified silicates, which were prepared by using high-performance ult ...
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Organic Semiconductors
Organic semiconductors are solids whose building blocks are pi-bonded molecules or polymers made up by carbon and hydrogen atoms and – at times – heteroatoms such as nitrogen, sulfur and oxygen. They exist in the form of molecular crystals or amorphous thin films. In general, they are electrical insulators, but become semiconducting when charges are either injected from appropriate electrodes, upon doping or by photoexcitation. General properties In molecular crystals the energetic separation between the top of the valence band and the bottom conduction band, i.e. the band gap, is typically 2.5–4 eV, while in inorganic semiconductors the band gaps are typically 1–2 eV. This implies that they are, in fact, insulators rather than semiconductors in the conventional sense. They become semiconducting only when charge carriers are either injected from the electrodes or generated by intentional or unintentional doping. Charge carriers can also be generated in the cours ...
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Organic Photonics
Organic photonics includes the generation, emission, transmission, modulation, signal processing, switching, amplification, and detection/sensing of light, using organic optical materials. Fields within organic photonics include the liquid organic dye laser and solid-state organic dye lasers. Materials used in solid-state dye lasers include: * laser dye-doped PMMA * laser dye-doped ormosil * laser dye-doped polymer-nanoparticle matrices * laser dye-doped bio-based gain media Organic-inorganic nanoparticle gain media are nanocomposites developed for solid-state dye lasers and can also be utilized in biosensors, bio analytics, and nonlinear organic photonics applications. An additional class of organic materials used in the generation of laser light include organic semiconductors.C. Karnutsch, ''Low Threshold Organic Thin Film Laser Devices'' (Cuvillier, Göttingen, 2007). Conjugated polymers are widely used as optically-pumped organic semiconductors. See also *Conjugated p ...
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Nanoparticle
A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At the lowest range, metal particles smaller than 1 nm are usually called atom clusters instead. Nanoparticles are usually distinguished from microparticles (1-1000 µm), "fine particles" (sized between 100 and 2500 nm), and "coarse particles" (ranging from 2500 to 10,000 nm), because their smaller size drives very different physical or chemical properties, like colloidal properties and ultrafast optical effects or electric properties. Being more subject to the brownian motion, they usually do not sediment, like colloidal particles that conversely are usually understood to range from 1 to 1000 nm. Being much smaller than the wavelengths of visible light (400-700 nm), nano ...
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Distributed Feedback Laser
A distributed-feedback laser (DFB) is a type of laser diode, quantum-cascade laser or optical-fiber laser where the active region of the device contains a periodically structured element or diffraction grating. The structure builds a one-dimensional interference grating (Bragg scattering), and the grating provides optical feedback for the laser. This longitudinal diffraction grating has periodic changes in refractive index that cause reflection back into the cavity. The periodic change can be either in the real part of the refractive index or in the imaginary part (gain or absorption). The strongest grating operates in the first order, where the periodicity is one-half wave, and the light is reflected backwards. DFB lasers tend to be much more stable than Fabry–Perot or DBR lasers and are used frequently when clean single-mode operation is needed, especially in high-speed fiber-optic telecommunications. Semiconductor DFB lasers in the lowest loss window of optical fibers at abo ...
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OLED
An organic light-emitting diode (OLED or organic LED), also known as organic electroluminescent (organic EL) diode, is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound that emits light in response to an electric current. This organic layer is situated between two electrodes; typically, at least one of these electrodes is transparent. OLEDs are used to create digital displays in devices such as television screens, computer monitors, and portable systems such as smartphones and handheld game consoles. A major area of research is the development of white OLED devices for use in solid-state lighting applications. There are two main families of OLED: those based on small molecules and those employing polymers. Adding mobile ions to an OLED creates a light-emitting electrochemical cell (LEC) which has a slightly different mode of operation. An OLED display can be driven with a passive-matrix (PMOLED) or active-matrix (AMOLED) ...
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Conjugated Polymers
In theoretical chemistry, a conjugated system is a system of connected p-orbitals with delocalized electrons in a molecule, which in general lowers the overall energy of the molecule and increases stability. It is conventionally represented as having alternating single and multiple bonds. Lone pairs, radicals or carbenium ions may be part of the system, which may be cyclic, acyclic, linear or mixed. The term "conjugated" was coined in 1899 by the German chemist Johannes Thiele. Conjugation is the overlap of one p-orbital with another across an adjacent σ bond (in transition metals, d-orbitals can be involved). A conjugated system has a region of overlapping p-orbitals, bridging the interjacent locations that simple diagrams illustrate as not having a π bond. They allow a delocalization of π electrons across all the adjacent aligned p-orbitals. The π electrons do not belong to a single bond or atom, but rather to a group of atoms. Molecules containing conjugated syste ...
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Polymers
A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and natural polymers play essential and ubiquitous roles in everyday life. Polymers range from familiar synthetic plastics such as polystyrene to natural biopolymers such as DNA and proteins that are fundamental to biological structure and function. Polymers, both natural and synthetic, are created via polymerization of many small molecules, known as monomers. Their consequently large molecular mass, relative to small molecule compounds, produces unique physical properties including toughness, high elasticity, viscoelasticity, and a tendency to form amorphous and semicrystalline structures rather than crystals. The term "polymer" derives from the Greek word πολύς (''polus'', meaning "many, much") and μέρος (''meros'', meani ...
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Organic Compound
In chemistry, organic compounds are generally any chemical compounds that contain carbon-hydrogen or carbon-carbon bonds. Due to carbon's ability to catenate (form chains with other carbon atoms), millions of organic compounds are known. The study of the properties, reactions, and syntheses of organic compounds comprise the discipline known as organic chemistry. For historical reasons, a few classes of carbon-containing compounds (e.g., carbonate salts and cyanide salts), along with a few other exceptions (e.g., carbon dioxide, hydrogen cyanide), are not classified as organic compounds and are considered inorganic. Other than those just named, little consensus exists among chemists on precisely which carbon-containing compounds are excluded, making any rigorous definition of an organic compound elusive. Although organic compounds make up only a small percentage of Earth's crust, they are of central importance because all known life is based on organic compounds. Living t ...
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Tunable Laser
A tunable laser is a laser whose wavelength of operation can be altered in a controlled manner. While all laser gain media allow small shifts in output wavelength, only a few types of lasers allow continuous tuning over a significant wavelength range. There are many types and categories of tunable lasers. They exist in the gas, liquid, and solid state. Among the types of tunable lasers are excimer lasers, gas lasers (such as CO2 and He-Ne lasers), dye lasers (liquid and solid state), transition metal solid-state lasers, semiconductor crystal and diode lasers, and free electron lasers. Tunable lasers find applications in spectroscopy, photochemistry, atomic vapor laser isotope separation, and optical communications. Types of tunability Single line tuning Since no real laser is truly monochromatic, all lasers can emit light over some range of frequencies, known as the linewidth of the laser transition. In most lasers, this linewidth is quite narrow (for example, the  nm wave ...
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Solid-state Dye Lasers
Solid-state dye lasers (SSDL) were introduced in 1967 by Soffer and McFarland. In these solid-state lasers, the gain medium is a laser dye-doped organic matrix such as poly(methyl methacrylate) (PMMA), rather than a liquid solution of the dye. An example is rhodamine 6G-doped PMMA. These lasers are also referred to as solid-state organic lasers and solid-state dye-doped polymer lasers. Organic gain media In the 1990s, new forms of improved PMMA, such as modified PMMA, with high optical quality characteristics were introduced. Gain media research for SSDL has been rather active in the 21st century, and various new dye-doped solid-state organic matrices have been discovered. Notable among these new gain media are organic-inorganic dye-doped polymer-nanoparticle composites. An additional form of organic-inorganic dye-doped solid-state laser gain media are the ORMOSILs. High performance solid-state dye laser oscillators This improved gain medium was central to the demonstrati ...
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