|
Nitronium Perchlorate
Nitronium perchlorate, NO2ClO4, also known as nitryl perchlorate and nitroxyl perchlorate, is an inorganic chemical, the salt of the perchlorate anion and the nitronium cation. It forms colorless monoclinic crystals. It is hygroscopic, and is a strong oxidizing and nitrating agent. It may become hypergolic in contact with organic materials. Nitronium perchlorate was investigated as an oxidizer in solid rocket propellants. Thomas N. Scortia filed for patent on such propellant in 1963. However its reactivity and incompatibility with many materials hindered such use. Coating of nitronium perchlorate particles with ammonium nitrate, prepared in situ by passing of dry ammonia gas over the particles, was investigated and a patent was awarded. Decomposition rate of nitronium perchlorate can be altered by doping with multivalent cations. Nitronium perchlorate and ammonium perchlorate do not produce smoke when stoichiometrically burned with non-metallic fuels. Potassium perchlorate an ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitronium Tetrafluoroborate
Nitronium tetrafluoroborate is an inorganic compound with formula NO2BF4. It is a salt of nitronium cation and tetrafluoroborate anion. It is a colorless crystalline solid, which reacts with water to form the corrosive acids HF and HNO3. As such, it must be handled under water-free conditions. It is sparsely soluble in many organic solvents. Preparation Nitronium tetrafluoroborate can be prepared by adding a mixture of anhydrous hydrogen fluoride and boron trifluoride to a nitromethane solution of nitric acid or dinitrogen pentoxide. Applications Nitronium tetrafluoroborate is used as a nitration In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group into an organic compound. The term also is applied incorrectly to the different process of forming nitrate esters between alcohols and ... agent. References Tetrafluoroborates Nitronium compounds {{inorganic-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrating
In organic chemistry, nitration is a general class of chemical processes for the introduction of a nitro group into an organic compound. The term also is applied incorrectly to the different process of forming nitrate esters between alcohols and nitric acid (as occurs in the synthesis of nitroglycerin). The difference between the resulting molecular structures of nitro compounds and nitrates is that the nitrogen atom in nitro compounds is directly bonded to a non-oxygen atom (typically carbon or another nitrogen atom), whereas in nitrate esters (also called organic nitrates), the nitrogen is bonded to an oxygen atom that in turn usually is bonded to a carbon atom (nitrito group). There are many major industrial applications of nitration in the strict sense; the most important by volume are for the production of nitroaromatic compounds such as nitrobenzene. Nitration reactions are notably used for the production of explosives, for example the conversion of guanidine to nitroguanid ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyrotechnic Oxidizers
Pyrotechnics is the science and craft of creating such things as fireworks, safety matches, oxygen candles, explosive bolts and other fasteners, parts of automotive airbags, as well as gas-pressure blasting in mining, quarrying, and demolition. This trade relies upon self-contained and self-sustained exothermic chemical reactions to make heat, light, gas, smoke and/or sound. The name comes from the Greek words ''pyr'' ("fire") and ''tekhnikos'' ("made by art"). People responsible for the safe storage, handling, and functioning of pyrotechnic devices are known as pyrotechnicians. Proximate pyrotechnics Explosions, flashes, smoke, flames, fireworks and other pyrotechnic-driven effects used in the entertainment industry are referred to as proximate pyrotechnics. Proximate refers to the pyrotechnic device's location relative to an audience. In the majority of jurisdictions, special training and licensing must be obtained from local authorities to legally prepare and use proximate py ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perchlorates
A perchlorate is a chemical compound containing the perchlorate ion, . The majority of perchlorates are commercially produced salts. They are mainly used as oxidizers for pyrotechnic devices and to control static electricity in food packaging. Perchlorate contamination in food, water, and other parts of the environment has been studied in the U.S. because of harmful effects on human health. Perchlorate ions are somewhat toxic to the thyroid gland. Most perchlorates are colorless solids that are soluble in water. Four perchlorates are of primary commercial interest: ammonium perchlorate , perchloric acid , potassium perchlorate and sodium perchlorate . Perchlorate is the anion resulting from the dissociation of perchloric acid and its salts upon their dissolution in water. Many perchlorate salts are soluble in non-aqueous solutions. Production Perchlorate salts are produced industrially by the oxidation of aqueous solutions of sodium chlorate by electrolysis. This method is use ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitronium Compounds
The nitronium ion, , is a cation. It is an onium ion because its nitrogen atom has +1 charge, similar to ammonium ion . It is created by the removal of an electron from the paramagnetic nitrogen dioxide molecule , or the protonation of nitric acid (with removal of ). It is stable enough to exist in normal conditions, but it is generally reactive and used extensively as an electrophile in the nitration of other substances. The ion is generated ''in situ'' for this purpose by mixing concentrated sulfuric acid and concentrated nitric acid according to the chemical equilibrium, equilibrium: : Structure The nitronium ion is isoelectronicity, isoelectronic with carbon dioxide and nitrous oxide, and has the same linear structure and bond angle of 180°. For this reason it has a similar vibrational spectrum to carbon dioxide. Historically, the nitronium ion was detected by Raman spectroscopy, because its symmetric stretch is Raman-active but infrared-inactive. The Raman-active symmet ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Detonation
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidant in a composition somewhat below conventional flammabil ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonia
Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous waste, particularly among aquatic organisms, and it contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to 45% of the world's food and fertilizers. Around 70% of ammonia is used to make fertilisers in various forms and composition, such as urea and Diammonium phosphate. Ammonia in pure form is also applied directly into the soil. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceutical products and is used in many commercial cleaning products. It is mainly collected by downward displacement of both air and water. Although common in nature—both terrestrially and in the outer planets of the Solar System—and in wide use, ammonia is both caust ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Nitrate
Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.Karl-Heinz Zapp "Ammonium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'' 2012, Wiley-VCH, Weinheim. Global production was estimated at 21.6 million tonnes in 2017. Its other major use is as a component of explosive mixtures used in mining, quarrying, and civil construction. It is the major constituent of ANFO, a popular industrial explosive which accounts for 80% of explosives used in North America; similar formulations have been used in improvised explosive devices. Many countries are phasing out its use in consumer applications due to concerns over its potential for misuse. [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thomas N
Thomas may refer to: People * List of people with given name Thomas * Thomas (name) * Thomas (surname) * Saint Thomas (other) * Thomas Aquinas (1225–1274) Italian Dominican friar, philosopher, and Doctor of the Church * Thomas the Apostle * Thomas (bishop of the East Angles) (fl. 640s–650s), medieval Bishop of the East Angles * Thomas (Archdeacon of Barnstaple) (fl. 1203), Archdeacon of Barnstaple * Thomas, Count of Perche (1195–1217), Count of Perche * Thomas (bishop of Finland) (1248), first known Bishop of Finland * Thomas, Earl of Mar (1330–1377), 14th-century Earl, Aberdeen, Scotland Geography Places in the United States * Thomas, Illinois * Thomas, Indiana * Thomas, Oklahoma * Thomas, Oregon * Thomas, South Dakota * Thomas, Virginia * Thomas, Washington * Thomas, West Virginia * Thomas County (other) * Thomas Township (other) Elsewhere * Thomas Glacier (Greenland) Arts, entertainment, and media * ''Thomas'' (Burton novel) 1969 novel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid Rocket Propellant
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines. Overview Rockets create thrust by expelling mass rear-ward, at high velocity. The thrust produced can be calculated by multiplying the mass flow rate of the propellants by their exhaust velocity relative to the rocket (specific impulse). A rocket can be thought of as being accelerated by the pressure of the combusting gases against the combustion chamber and nozzle, not by "pushing" against the air behind or below it. Rocket engines perform best in outer space because of the lack of air pressure on the outside of the engine. In space it is also possible to fit a longer nozzle without suffering from flow separation. Most chemical propellants release energy through redox chemistry, m ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxidizer
An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ). In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide and the halogens. In one sense, an oxidizing agent is a chemical species that undergoes a chemical reaction in which it gains one or more electrons. In that sense, it is one component in an oxidation–reduction (redox) reaction. In the second sense, an oxidizing agent is a chemical species that transfers electronegative atoms, usually oxygen, to a substrate. Combust ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hypergolic
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other. The two propellant components usually consist of a fuel and an oxidizer. The main advantages of hypergolic propellants are that they can be stored as liquids at room temperature and that engines which are powered by them are easy to ignite reliably and repeatedly. Common hypergolic propellants are difficult to handle due to their extreme toxicity and/or corrosiveness. In contemporary usage, the terms "hypergol" and "hypergolic propellant" usually mean the most common such propellant combination: dinitrogen tetroxide plus hydrazine and/or its relatives monomethylhydrazine (MMH) and unsymmetrical dimethylhydrazine (UDMH). History In 1935, Hellmuth Walter discovered that hydrazine hydrate was hypergolic with high-test peroxide of 80-83%. He was probably the first to discover this phenomenon, and set to work devel ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
-3D-balls.png "Click for more on -> Ammonia")
