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Ammonium Nitrate
Ammonium nitrate is a chemical compound with the chemical formula . It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.Karl-Heinz Zapp "Ammonium Compounds" in ''Ullmann's Encyclopedia of Industrial Chemistry'' 2012, Wiley-VCH, Weinheim. Global production was estimated at 21.6 million tonnes in 2017. Its other major use is as a component of explosive mixtures used in mining, quarrying, and civil construction. It is the major constituent of ANFO, a popular industrial explosive which accounts for 80% of explosives used in North America; similar formulations have been used in improvised explosive devices. Many countries are phasing out its use in consumer applications due to concerns over its potential for misuse.
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Fertilizer
A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from liming materials or other non-nutrient soil amendments. Many sources of fertilizer exist, both natural and industrially produced. For most modern agricultural practices, fertilization focuses on three main macro nutrients: nitrogen (N), phosphorus (P), and potassium (K) with occasional addition of supplements like rock flour for micronutrients. Farmers apply these fertilizers in a variety of ways: through dry or pelletized or liquid application processes, using large agricultural equipment or hand-tool methods. Historically fertilization came from natural or organic sources: compost, animal manure, human manure, harvested minerals, crop rotations and byproducts of human-nature industries (i.e. fish processing waste, or bloodmeal fro ...
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Haber Process
The Haber process, also called the Haber–Bosch process, is an artificial nitrogen fixation process and is the main industrial procedure for the production of ammonia today. It is named after its inventors, the German chemists Fritz Haber and Carl Bosch, who developed it in the first decade of the 20th century. The process converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using a metal catalyst under high temperatures and pressures: : \ce \quad \Delta H^\circ = -91.8~\text Though this reaction is exothermic (i.e. it releases energy, albeit not very much), it results in a decrease in entropy, which is the central reason why it is very challenging to carry out. Before the development of the Haber process, it had been difficult to produce ammonia on an industrial scale, with early methods, such as the Birkeland–Eyde process and the Frank–Caro process, all highly inefficient. During World War I, the Haber process provided Germany with a s ...
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Halide Minerals
Halide minerals are those minerals with a dominant halide anion (, , and ). Complex halide minerals may also have polyatomic anions. Examples include the following: * Atacamite *Avogadrite (K,Cs)BF * Bararite (β) * Bischofite * Brüggenite * Calomel *Carnallite *Carnallite * Cerargyrite/Horn silver AgCl *Chlorargyrite AgCl, bromargyrite AgBr, and iodargyrite AgI * Cryolite * Cryptohalite (a) Vanadates), 09 Silicates: * ''neso-'': insular (from Greek , "island") * ''soro-'': grouped (from Greek , "heap, pile, mound") * ''cyclo-'': ringed (from Greek , "circle") * ''ino-'': chained (from Greek , "fibre", rom Ancient Greek * ''phyllo-'': sheeted (from Greek , "leaf") * ''tecto-'': of three-dimensional framework (from Greek , "of building") ;Nickel–Strunz code scheme ''NN.XY.##x'': * ''NN'': Nickel–Strunz mineral class number * ''X'': Nickel–Strunz mineral division letter * ''Y'': Nickel–Strunz mineral family letter * ''##x'': Nickel–Strunz miner ...
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Iodate
An iodate is the polyatomic anion with the formula . It is the most common form of iodine in nature, as it comprises the major iodine-containing ores. Iodate salts are often colorless. They are the salts of iodic acid. Structure Iodate is pyramidal in structure. The O–I–O angles range from 97° to 105°, somewhat smaller than the O–Cl–O angles in chlorate. Reactions Redox Iodate is one of several oxyanions of iodine, and has an oxidation number of +5. It participates in several redox reactions, such as the iodine clock reaction. Iodate show no tendency to disproportionate to periodate and iodide, in contrast to the situation for chlorate. Iodate is reduced by sulfite: :6HSO3- + 2IO3- -> 2I- + 6HSO4- Iodate oxidizes iodide: :5I- + IO3- + 3H2SO4 -> 3I2 + 3H2O + 3SO4^2- Similarly, chlorate oxidizes iodide to iodate: :I- + ClO3- -> Cl- + IO3- Iodate is also obtained by reducing a periodate with a sulfide. The byproduct of the reaction is a sulfoxide. Acid-base Iod ...
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Chile
Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east and the Pacific Ocean to the west. Chile covers an area of , with a population of 17.5 million as of 2017. It shares land borders with Peru to the north, Bolivia to the north-east, Argentina to the east, and the Drake Passage in the far south. Chile also controls the Pacific islands of Juan Fernández, Isla Salas y Gómez, Desventuradas, and Easter Island in Oceania. It also claims about of Antarctica under the Chilean Antarctic Territory. The country's capital and largest city is Santiago, and its national language is Spanish. Spain conquered and colonized the region in the mid-16th century, replacing Inca rule, but failing to conquer the independent Mapuche who inhabited what is now south-central Chile. In 1818, after ...
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Atacama Desert
The Atacama Desert ( es, Desierto de Atacama) is a desert plateau in South America covering a 1,600 km (990 mi) strip of land on the Pacific coast, west of the Andes Mountains. The Atacama Desert is the driest nonpolar desert in the world, and the second driest overall, just behind some very specific spots within the McMurdo Dry Valleys as well as the only hot true desert to receive less precipitation than the polar deserts, and the largest fog desert in the world. Both regions have been used as experimentation sites on Earth for Mars expedition simulations. The Atacama Desert occupies , or if the barren lower slopes of the Andes are included. Most of the desert is composed of stony terrain, salt lakes (''salares''), sand, and felsic lava that flows towards the Andes. The desert owes its extreme aridity to a constant temperature inversion due to the cool north-flowing Humboldt ocean current and to the presence of the strong Pacific anticyclone. The most arid r ...
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Nitre
Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits. Historically, the term ''niter'' was not well differentiated from natron, both of which have been very vaguely defined but generally refer to compounds of sodium or potassium joined with carbonate or nitrate ions. Characteristics Niter is a colorless to white mineral crystallizing in the orthorhombic crystal system. It is the mineral form of potassium nitrate, , and is soft (Mohs hardness 2), highly soluble in water, and easily fusible. Its crystal structure resembles that of aragonite, with potassium replacing calcium and nitrate replacing carbonate. It occurs in the soils of arid regions and as massive encrustations and efflorescent growths on cavern walls and ceilings where solutions containing alkali potassium and nitrate seep into the openings. It occasionally occurs as prismatic acicular crystal groups, and indi ...
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Gwihabaite
Gwihabaite is a rare ammonium potassium nitrate mineral (NH4,K)(NO3). It is orthorhombic in form, colorless with a vitreous luster. It has a Mohs hardness of 5 and a specific gravity of 1.77. It is deliquescent and water-soluble. The mineral is also known as ''nitrammite''. It was first described in 1996 for an occurrence in Gcwihaba Caves (Drotsky's Cavern, type locality), Maun, North-West District, Botswana. The spelling of the name was simplified, omitting the "c", which represents the "click" sound used by the San people. It occurs as incrustations and efflorescences on cave surfaces formed by bacterial action on bat guano Guano (Spanish from qu, wanu) is the accumulated excrement of seabirds or bats. As a manure, guano is a highly effective fertilizer due to the high content of nitrogen, phosphate, and potassium, all key nutrients essential for plant growt .... References {{mineral-stub Nitrate minerals Orthorhombic minerals Minerals in space group 62< ...
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Ammonium Nitrate Disasters
__FORCETOC__ When heated, ammonium nitrate decomposes non-explosively into gases of oxygen, nitrogen, and water vapor; however, it can be induced to decompose explosively by detonation into nitrous oxide and water vapor. Large stockpiles of the material can be a major fire risk due to their supporting oxidation, and may also detonate, as happened in the Texas City disaster of 1947 which led to major changes in the regulations for storage and handling. There are two major classes of incidents resulting in explosions: * In the first case, the explosion happens by the mechanism of shock to detonation transition. The initiation happens by an explosive charge going off in the mass, by the detonation of a shell thrown into the mass, or by detonation of an explosive mixture in contact with the mass. Examples are Kriewald, Morgan, Oppau, Tessenderlo, and Traskwood. * In the second case, the explosion results from a fire that spreads into the ammonium nitrate (AN) itself ( Texas C ...
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The Dallas Morning News
''The Dallas Morning News'' is a daily newspaper serving the Dallas–Fort Worth area of Texas, with an average print circulation of 65,369. It was founded on October 1, 1885 by Alfred Horatio Belo as a satellite publication of the ''Galveston Daily News'', of Galveston, Texas. Historically, and to the present day, it is the most prominent newspaper in Dallas. Today it has one of the 20 largest paid circulations in the United States. Throughout the 1990s and as recently as 2010, the paper has won nine Pulitzer Prizes for reporting and photography, George Polk Awards for education reporting and regional reporting, and an Overseas Press Club award for photography. The company has its headquarters in downtown Dallas. History ''The Dallas Morning News'' was founded in 1885 as a spin-off of the ''Galveston Daily News'' by Alfred Horatio Belo. In 1926, the Belo family sold a majority interest in the paper to its longtime publisher, George Dealey. By the 1920s, the Dallas Mo ...
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