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Haber Process
The Haber process, also called the Haber–Bosch process, is the main industrial procedure for the ammonia production, production of ammonia. It converts atmospheric nitrogen (N2) to ammonia (NH3) by a reaction with hydrogen (H2) using finely divided iron metal as a catalyst: \ce \qquad This reaction is exothermic but disfavored in terms of entropy because four equivalents of reactant gases are converted into two equivalents of product gas. As a result, high pressures and temperatures that are not too high are needed to Le_Chatelier's_principle, drive the reaction forward. The German chemists Fritz Haber and Carl Bosch developed the process in the first decade of the 20th century, and its improved efficiency over existing methods such as the Birkeland–Eyde process, Birkeland-Eyde and Frank–Caro process, Frank-Caro processes was a major advancement in the industrial production of ammonia. The Haber process can be combined with steam reforming to produce ammonia with just ...
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Fritz Haber
Fritz Jakob Haber (; 9 December 1868 – 29 January 1934) was a German chemist who received the Nobel Prize in Chemistry in 1918 for his invention of the Haber process, a method used in industry to synthesize ammonia from nitrogen gas and hydrogen gas. This invention is important for the large-scale synthesis of fertilizers and Explosive material, explosives. It is estimated that a third of annual global food production uses ammonia from the Haber–Bosch process, and that this food supports nearly half the world's population. For this work, Haber has been called one of the most important scientists and industrial chemists in human history. Haber also, along with Max Born, proposed the Born–Haber cycle as a method for evaluating the lattice energy of an ionic solid. Haber, a known German nationalist, is also considered the "father of chemical warfare" for his years of pioneering work developing and Chlorine#Use as a weapon, weaponizing chlorine and other poisonous gases during ...
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Niter
Niter or nitre is the mineral form of potassium nitrate, KNO3. It is a soft, white, highly soluble mineral found primarily in arid climates or cave deposits. Potassium and other nitrates are of great importance for use in fertilizers and, historically, gunpowder. Much of the world's demand is now met by synthetically produced nitrates, though the natural mineral is still mined and is still of significant commercial value. Historically, the term ''niter'' was not well differentiated from natron, both of which have been very vaguely defined but generally refer to compounds of sodium or potassium joined with carbonate or nitrate ions. Characteristics Niter is a colorless to white mineral crystallizing in the orthorhombic crystal system. It is the mineral form of potassium nitrate, , and is soft (Mohs hardness 2), highly soluble in water, and easily fusible. Its crystal structure resembles that of aragonite, with potassium replacing calcium and nitrate replacing carbonate. ...
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Nitric Acid
Nitric acid is an inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into nitrogen oxide, oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water. When the solution contains more than 86% , it is referred to as ''fuming nitric acid''. Depending on the amount of nitrogen dioxide present, fuming nitric acid is further characterized as red fuming nitric acid at concentrations above 86%, or white fuming nitric acid at concentrations above 95%. Nitric acid is the primary reagent used for nitration – the addition of a nitro group, typically to an organic molecule. While some resulting nitro compounds are shock- and thermally-sensitive explosives, a few are stable enough to be used in munitions and demolition, while others are still more stable and used as synthetic dyes and medicines (e.g. metronidazole). Nitric acid is ...
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The New York Times
''The New York Times'' (''NYT'') is an American daily newspaper based in New York City. ''The New York Times'' covers domestic, national, and international news, and publishes opinion pieces, investigative reports, and reviews. As one of the longest-running newspapers in the United States, the ''Times'' serves as one of the country's Newspaper of record, newspapers of record. , ''The New York Times'' had 9.13 million total and 8.83 million online subscribers, both by significant margins the List of newspapers in the United States, highest numbers for any newspaper in the United States; the total also included 296,330 print subscribers, making the ''Times'' the second-largest newspaper by print circulation in the United States, following ''The Wall Street Journal'', also based in New York City. ''The New York Times'' is published by the New York Times Company; since 1896, the company has been chaired by the Ochs-Sulzberger family, whose current chairman and the paper's publ ...
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Blockade
A blockade is the act of actively preventing a country or region from receiving or sending out food, supplies, weapons, or communications, and sometimes people, by military force. A blockade differs from an embargo or sanction, which are legal barriers to trade rather than physical barriers. It is also distinct from a siege in that a blockade is usually directed at an entire country or region, rather than a fortress or city and the objective may not always be to conquer the area. A blockading power can seek to cut off all maritime transport from and to the blockaded country, although stopping all land transport to and from an area may also be considered a blockade. Blockades restrict the trading rights of neutrals, who must submit for inspection for contraband, which the blockading power may define narrowly or broadly, sometimes including food and medicine. In the 20th century, air power has also been used to enhance the effectiveness of blockades by halting air traffic w ...
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Saltpetre
Potassium nitrate is a chemical compound with a sharp, salty, bitter taste and the chemical formula . It is a potassium salt of nitric acid. This salt consists of potassium cations and nitrate anions , and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or ''nitre'' outside the United States). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpetre (or saltpeter in the United States). Major uses of potassium nitrate are in fertilizers, tree stump removal, rocket propellants and fireworks. It is one of the major constituents of traditional gunpowder (black powder). In processed meats, potassium nitrate reacts with hemoglobin and myoglobin generating a red color. Etymology Nitre, or potassium nitrate, because of its early and global use and production, has many names. As for nitrate, Egyptian and Hebrew words for it had the consonants ...
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Sodium Nitrate
Sodium nitrate is the chemical compound with the chemical formula, formula . This alkali metal nitrate salt (chemistry), salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile) to distinguish it from ordinary saltpeter, potassium nitrate. The mineral form is also known as nitratine, nitratite or soda niter. Sodium nitrate is a white deliquescent solid very soluble in water. It is a readily available source of the nitrate anion (NO3−), which is useful in several reactions carried out on industrial scales for the production of fertilizers, pyrotechnics, smoke bombs and other explosives, glass and pottery vitreous enamel, enamels, food preservatives (esp. meats), and rocket propellant, solid rocket propellant. It has been mined extensively for these purposes. History The first shipment of saltpeter to Europe arrived in England from Peru in 1820 or 1825, right after that country's independence from Spain, but did not find any buyers and was ...
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Allies Of World War I
The Allies or the Entente (, ) was an international military coalition of countries led by the French Republic, the United Kingdom, the Russian Empire, the United States, the Kingdom of Italy, and the Empire of Japan against the Central Powers of the German Empire, Austria-Hungary, the Ottoman Empire, and the Kingdom of Bulgaria in World War I (1914–1918). By the end of the first decade of the 20th century, the major European powers were divided between the Triple Entente and the Triple Alliance. The Triple Entente was made up of the United Kingdom, France, and Russia. The Triple Alliance was originally composed of Germany, Austria–Hungary, and Italy, but Italy remained neutral in 1914. As the war progressed, each coalition added new members. Japan joined the Entente in 1914 and, despite proclaiming its neutrality at the beginning of the war, Italy also joined the Entente in 1915. The term "Allies" became more widely used than "Entente", although the United Kingdom, Fran ...
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Munitions
Ammunition, also known as ammo, is the material fired, scattered, dropped, or detonated from any weapon or weapon system. The term includes both expendable weapons (e.g., bombs, missiles, grenades, land mines), and the component parts of other weapons that create the effect on a target (e.g., bullets and warheads). The purpose of ammunition is to project a force against a selected target to have an effect (usually, but not always, lethal). An example of ammunition is the firearm cartridge, which includes all components required to deliver the weapon effect in a single package. Until the 20th century, black powder was the most common propellant used but has now been replaced in nearly all cases by modern compounds. Ammunition comes in a great range of sizes and types and is often designed to work only in specific weapons systems. However, there are internationally recognized standards for certain ammunition types (e.g., 5.56×45mm NATO) that enable their use across diff ...
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World War I
World War I or the First World War (28 July 1914 – 11 November 1918), also known as the Great War, was a World war, global conflict between two coalitions: the Allies of World War I, Allies (or Entente) and the Central Powers. Fighting took place mainly in European theatre of World War I, Europe and the Middle Eastern theatre of World War I, Middle East, as well as in parts of African theatre of World War I, Africa and the Asian and Pacific theatre of World War I, Asia-Pacific, and in Europe was characterised by trench warfare; the widespread use of Artillery of World War I, artillery, machine guns, and Chemical weapons in World War I, chemical weapons (gas); and the introductions of Tanks in World War I, tanks and Aviation in World War I, aircraft. World War I was one of the List of wars by death toll, deadliest conflicts in history, resulting in an estimated World War I casualties, 10 million military dead and more than 20 million wounded, plus some 10 million civilian de ...
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Ludwigshafen
Ludwigshafen, officially Ludwigshafen am Rhein (; meaning "Ludwig I of Bavaria, Ludwig's Port upon the Rhine"; Palatine German dialects, Palatine German: ''Ludwichshafe''), is a List of cities and towns in Germany, city in the German state of Rhineland-Palatinate, on the river Rhine (Upper Rhine), opposite Mannheim. With Mannheim, Heidelberg, and the surrounding region, it forms the Rhine Neckar Area. Known primarily as an industrial city, Ludwigshafen is home to BASF, the world's List of largest chemical producers, largest chemical producer, and other companies. Among its cultural facilities are the Staatsphilharmonie Rheinland-Pfalz. It is the birthplace and death place of the former Chancellor of Germany Helmut Kohl. In 2012, Ludwigshafen was classified as a global city with 'Globalization and World Cities Research Network#Sufficiency, Sufficiency' status by the Globalization and World Cities Research Network (GaWC). History Early history In ancient history, antiquity, Cel ...
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BASF
BASF SE (), an initialism of its original name , is a European Multinational corporation, multinational company and the List of largest chemical producers, largest chemical producer in the world. Its headquarters are located in Ludwigshafen, Germany. BASF comprises subsidiary, subsidiaries and joint ventures in more than 80 countries, operating six integrated production sites and 390 other production sites across Europe, Asia, Australia, the Americas and Africa. BASF has customers in over 190 countries and supplies products to a wide variety of industries. Despite its size and global presence, BASF has received relatively little public attention since it abandoned the manufacture and sale of BASF-branded consumer electronics products in the 1990s. The company began as a dye manufacturer in 1865. Fritz Haber worked with Carl Bosch, one of its employees, to invent the Haber-Bosch, Haber-Bosch process by 1912, after which the company grew rapidly. In 1925, the company merged with ...
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