Nanopin Film
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Nanopin Film
Nanopin film is an experimental material in nanotechnology developed in 2005 with unusual superhydrophobic properties . A droplet of water makes contact with the surface of this film and forms an almost perfect sphere with a contact angle of 178 °. This happens because it is covered with nanoscale, topped-off pins or cones perpendicular to the surface. The surface is regarded as a composite material with mostly air and a small fraction constituted by the tops of the cones. When the contact angle of the cone material is sufficiently large, Cassie's law predicts large contact angle values for the composite. This particular nanopin film is produced with borosilicate glass. A solution of CoCl2•6H2O or cobalt chloride hexahydrate is heated at 60 °C for 24 hours in a chemical bath deposition to form a brucite type cobalt(II) hydroxide layer with composition :CoOH1.13Cl0.09(CO3)0.39.0.05H20 The top coating is provided by lauric acid in a separate step. A 3 square micrometer surfac ...
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Nanotechnology
Nanotechnology, also shortened to nanotech, is the use of matter on an atomic, molecular, and supramolecular scale for industrial purposes. The earliest, widespread description of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabrication of macroscale products, also now referred to as molecular nanotechnology. A more generalized description of nanotechnology was subsequently established by the National Nanotechnology Initiative, which defined nanotechnology as the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). This definition reflects the fact that quantum mechanical effects are important at this quantum-realm scale, and so the definition shifted from a particular technological goal to a research category inclusive of all types of research and technologies that deal with the special properties of matter which occur below the given size threshold. It is therefore commo ...
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Cassie's Law
Cassie's law, or the Cassie equation, describes the effective contact angle Theta, θc for a liquid on a chemically heterogeneous surface, i.e. the surface of a composite material consisting of different chemistries, that is non uniform throughout. Contact angles are important as they quantify a surface's Wetting, wettability, the nature of solid-fluid intermolecular interactions. Cassie's law is reserved for when a liquid completely covers both ''smooth'' and ''rough'' heterogeneous surfaces. More of a rule than a law, the formula found in literature for two materials is; \cos \theta_c = \sigma_1 \cos \theta_1 + \sigma_2 \cos \theta_2 where \theta_1and \theta_2 are the contact angles for components 1 with fractional surface area \sigma_1, and 2 with fractional surface area \sigma_2 in the composite material respectively. If there exist more than two materials then the equation is scaled to the general form of; \cos \theta_ =\sum_^N \sigma_k \cos \theta_k , with \sum_^N \sigma_k ...
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Lauric Acid
Lauric acid, systematically dodecanoic acid, is a saturated fatty acid with a 12-carbon atom chain, thus having many properties of medium-chain fatty acids. It is a bright white, powdery solid with a faint odor of bay oil or soap. The salts and esters of lauric acid are known as laurates. Occurrence Lauric acid, as a component of triglycerides, comprises about half of the fatty-acid content in coconut milk, coconut oil, laurel oil, and palm kernel oil (not to be confused with palm oil),David J. Anneken, Sabine Both, Ralf Christoph, Georg Fieg, Udo Steinberner, Alfred Westfechtel "Fatty Acids" in Ullmann's Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim. Otherwise, it is relatively uncommon. It is also found in human breast milk (6.2% of total fat), cow's milk (2.9%), and goat's milk (3.1%). In various plants *The palm tree '' Attalea speciosa'', a species popularly known in Brazil as ''babassu'' – 50% in ''babassu'' oil *'' Attalea cohune'', the cohun ...
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Cobalt(II) Hydroxide
Cobalt(II) hydroxide or cobaltous hydroxide is the inorganic compound with the formula , consisting of divalent cobalt cations and hydroxide anions . The pure compound, often called the "beta form" (β-) is a pink solid insoluble in water. The name is also applied to a related compound, often called "alpha" or "blue" form (α-), which incorporates other anions in its molecular structure. This compound is blue and rather unstable.Xiaohe Liu, Ran Yi, Ning Zhang, Rongrong Shi, Xingguo Li, and Guanzhou Qiu (2008): "Cobalt hydroxide nanosheets and their thermal decomposition to cobalt oxide nanorings". ''Chemistry: An Asian Journal'', volume 3, issue 4, pages 732-738. Cobalt(II) hydroxide is most used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst and in the manufacture of battery electrodes. Preparation Cobalt(II) hydroxide precipitates as a solid when an alkali metal hydroxide is added to an aqueous solution ...
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Brucite
Brucite is the mineral form of magnesium hydroxide, with the chemical formula Mg( OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal vein mineral in metamorphosed limestones and chlorite schists; and formed during serpentinization of dunites. Brucite is often found in association with serpentine, calcite, aragonite, dolomite, magnesite, hydromagnesite, artinite, talc and chrysotile. It adopts a layered CdI2-like structure with hydrogen-bonds between the layers. Discovery Brucite was first described in 1824 by François Sulpice Beudant and named for the discoverer, American mineralogist, Archibald Bruce (1777–1818). A fibrous variety of brucite is called nemalite. It occurs in fibers or laths, usually elongated along 010 but sometimes 120 crystalline directions. Occurrence A notable location in the U.S. is Wood's Chrome Mine, Cedar Hill Quarry, Lancaster County, Pennsylvania. Yellow, white and blue Brucite with a botryoidal ha ...
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Chemical Bath Deposition
Chemical Bath Deposition, also called Chemical Solution Deposition and CBD, is a method of thin-film deposition (solids forming from a solution or gas), using an aqueous precursor solution. Chemical Bath Deposition typically forms films using heterogeneous nucleation ( deposition or adsorption of aqueous ions onto a solid substrate), to form homogeneous thin films of metal chalcogenides (mostly oxides, sulfides, and selenides) and many less common ionic compounds. Chemical Bath Deposition produces films reliably, using a simple process with little infrastructure, at low temperature ( CdS (deposition) Hydroxide-Cluster Mechanism Hydroxide-Cluster deposition occurs when hydroxide ions are present in the solution and usually results in smaller and more uniform crystals than ion-by-ion deposition. When hydroxide ions are present in the solution in quantity, metal hydroxide ions form. The hydroxide ions act as ligands to the metal cations, forming insoluble colloidal clusters w ...
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Cobalt Chloride Hexahydrate
Cobalt(II) chloride is an inorganic compound of cobalt and chlorine, with the formula . The compound forms several hydrates ·''n'', for ''n'' = 1, 2, 6, and 9. Claims of the formation of tri- and tetrahydrates have not been confirmed.M. T. Saugier, M. Noailly, R. Cohen-Adad, F. Paulik, and J. Paulik (1977): "Equilibres solide ⇄ liquide ⇆ vapeur du systeme binaire -" ''Journal of Thermal Analysis'', volume 11, issue 1, pages 87–100. Note: the lowest point of fig.6 is inconsistent with fig.7; probably should be at -27.8 C instead of 0 C. The anhydrous form is a blue crystalline solid; the dihydrate is purple and the hexahydrate is pink. Commercial samples are usually the hexahydrate, which is one of the most commonly used cobalt compounds in the lab. Properties Anhydrous At room temperature, anhydrous cobalt chloride has the cadmium chloride structure () (Rm) in which the cobalt(II) ions are octahedrally coordinated. At about 706 °C (20 degrees below the melting poi ...
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Borosilicate Glass
Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10−6 K−1 at 20 °C), making them more resistant to thermal shock than any other common glass. Such glass is subjected to less thermal stress and can withstand temperature differentials without fracturing of about . It is commonly used for the construction of reagent bottles and flasks as well as lighting, electronics, and cookware. Borosilicate glass is sold under various trade names, including Borosil, Duran, Pyrex, Glassco, Supertek, Suprax, Simax, Bellco, Marinex (Brazil), BSA 60, BSC 51 (by NIPRO), Heatex, Endural, Schott, Refmex, Kimax, Gemstone Well, and MG (India). Single ended self-starting lamps are insulated with a mica disc and contained in a borosilicate glass gas discharge tube (arc tube) and a metal cap. They include the sodium-vapor lam ...
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Composite Material
A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions. Typical engineered composite materials include: * Reinforced concrete and masonry *Composite wood such as plywood * Reinforced plastics, such as fibre-reinforced polymer or fiberglass * Ceramic matrix composites ( composite ceramic and metal matrices) *Metal matrix composites *and other advanced composite materials There are various reasons where new material can be favoured. Typical examples include materials which are less expensive, lighter, stronger or more durable when compared with ...
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Hydrophobic
In chemistry, hydrophobicity is the physical property of a molecule that is seemingly repelled from a mass of water (known as a hydrophobe). In contrast, hydrophiles are attracted to water. Hydrophobic molecules tend to be nonpolar and, thus, prefer other neutral molecules and nonpolar solvents. Because water molecules are polar, hydrophobes do not dissolve well among them. Hydrophobic molecules in water often cluster together, forming micelles. Water on hydrophobic surfaces will exhibit a high contact angle. Examples of hydrophobic molecules include the alkanes, oils, fats, and greasy substances in general. Hydrophobic materials are used for oil removal from water, the management of oil spills, and chemical separation processes to remove non-polar substances from polar compounds. Hydrophobic is often used interchangeably with lipophilic, "fat-loving". However, the two terms are not synonymous. While hydrophobic substances are usually lipophilic, there are exceptions, ...
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Perpendicular
In elementary geometry, two geometric objects are perpendicular if they intersect at a right angle (90 degrees or π/2 radians). The condition of perpendicularity may be represented graphically using the ''perpendicular symbol'', ⟂. It can be defined between two lines (or two line segments), between a line and a plane, and between two planes. Perpendicularity is one particular instance of the more general mathematical concept of '' orthogonality''; perpendicularity is the orthogonality of classical geometric objects. Thus, in advanced mathematics, the word "perpendicular" is sometimes used to describe much more complicated geometric orthogonality conditions, such as that between a surface and its '' normal vector''. Definitions A line is said to be perpendicular to another line if the two lines intersect at a right angle. Explicitly, a first line is perpendicular to a second line if (1) the two lines meet; and (2) at the point of intersection the straight angle on one sid ...
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Cone (geometry)
A cone is a three-dimensional geometric shape that tapers smoothly from a flat base (frequently, though not necessarily, circular) to a point called the apex or vertex. A cone is formed by a set of line segments, half-lines, or lines connecting a common point, the apex, to all of the points on a base that is in a plane that does not contain the apex. Depending on the author, the base may be restricted to be a circle, any one-dimensional quadratic form in the plane, any closed one-dimensional figure, or any of the above plus all the enclosed points. If the enclosed points are included in the base, the cone is a solid object; otherwise it is a two-dimensional object in three-dimensional space. In the case of a solid object, the boundary formed by these lines or partial lines is called the ''lateral surface''; if the lateral surface is unbounded, it is a conical surface. In the case of line segments, the cone does not extend beyond the base, while in the case of half- ...
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